The invention discloses a high-permeability selective acid-resistant
nanofiltration membrane material as well as a preparation method and application thereof. The
nanofiltration membrane material comprises a dense separation layer which is formed by assembling an amine and a
quaternary ammonium salt polycation
electrolyte and a polyanion
electrolyte material with
sulfonic acid groups or
sulfuric acid groups layer by layer; the concentration of the polycation is 0.1-20 g / L, and the polycation is dissolved in a
salt solution of 0.05-5 mol / L; the used polyanion
electrolyte polymer material is a
polymer material with
sulfonic acid groups or
sulfuric acid groups, the concentration of polyanion is 0.1-20g / L, and the polyanion is dissolved in a 0.05-5mol / L
salt solution; the dense separation layer of the
nanofiltration membrane is formed by layer-by-layer
assembly, and has better
permeation selectivity and excellent acid-resistant stability than a commercial nanofiltration membrane. The
retention rate of the membrane to multivalent cations is greater than 90%, the permeability of the membrane to
phosphoric acid is greater than 80%, and the permeability of
phosphoric acid is one
order of magnitude layer than that of that of a commercial membrane. The high-permeability selective acid-resistant nanofiltration membrane material is used in
phosphoric acid refining and recycling processes, inorganic compounds in phosphoric acid-containing feed liquid are removed through pretreatment, then substances such as large particles and colloids are removed through
ultrafiltration, stable operation of a nanofiltration membrane process is achieved, high-purity phosphoric acid of different grades is obtained, and the high-permeability selective acid-resistant nanofiltration membrane material has wide application in the aspects of phosphoric acid refining and phosphoric acid recycling.