The invention relates to a preparation method of an
ultraviolet fluorescent-green
plastic film by taking rare-earth
phosphate glass as a photochromic agent and application thereof in anti-counterfeiting aspects. Aiming at the problems of doped rare-earth
fluorescent polymer materials, such as large polarity difference between an inorganic rare-earth fluorescent agent and a
polymer material, rare-earth fluorescent
concentration quenching,
fluorescence stability and the like, the
ultraviolet fluorescent-green
plastic film has the characteristics that the
phosphate glass is used as the substrate, Tb<3+>
ion is used as a fluorescent activator, and Ce<3+>
ion is used as a sensitizing agent, so that the fluorescent
concentration quenching phenomenon is overcome, and the Eu addition amount and the
fluorescence efficiency are increased through the synergistic effect of the
phosphate glass matrix, Tb<3+> and Ce<3+> in the formula; glass fragments are pressed by using a melting method and an
ice water mixture cooled glass tablet press, and then, the
phosphate glass:Tb<3+>, Ce<3+> fluorescent
powder with the
granularity of being less than 300 nm is prepared through high-pressure
grinding of an air-current mill; a surface modifier is added, fluorescent
powder and
polymer master-batch are molten and blended, and the
plastic film obtained by being blown is white and transparent in the sun and emits beautiful
green light under
irradiation of
ultraviolet light; and the plastic film has special transmission spectrum and can be used as an anti-counterfeiting packaging film, an anti-counterfeiting
label printing substrate and an anti-counterfeiting safety line substrate.