The invention discloses a preparation method of a
sulfur dioxide and
epoxide copolymer. According to the method, a novel
polysulfone material is prepared through copolymerization of
sulfur dioxide and
epoxide under the catalytic action of SalenMX,
epoxide and SalenMX are sequentially added to a high-pressure reaction kettle,
sulfur dioxide is introduced and has a reaction at the temperature of 50-100 DEG C for 8-48 h, then, a product, namely, the
sulfur dioxide and epoxide
copolymer is obtained, the product is dissolved with
chloroform, a
hydrochloric acid and
methanol mixed solution is used for
precipitation, amber precipitates are filtered and repeatedly washed with
methanol for 2-4 times, the washed product is transferred to a
vacuum drying box and dried in vacuum at the
room temperature for 8-24 h, and the
sulfur dioxide and epoxide
copolymer with higher stereoregularity can be obtained. The preparation method is simple, few catalysts are used, the
reaction temperature is mild, the yield is high, the structure regularity of the product is good, the cost is low, and industrial production is easy to realize.