The invention discloses a dense black-spot-free iron-based powdery metallurgical self-lubricating CNG engine valve seat ring. The dense black-spot-free iron-based powdery metallurgical self-lubricating CNG engine valve seat ring is prepared from, by weight, 6.4-6.6 parts of chrome, 4.4-4.6 parts of cobalt, 0.7-1.2 parts of nickel, 0.3-0.5 part of neodymium, 2.3-2.6 parts of boron, 3.6-4.3 parts of polymerization iron powder, 16-18 parts of copper, 1.3-1.5 parts of nano molybdenum disulfide, 0.7-0.8 part of calcium fluoride, 1.2-1.4 parts of silicon carbide, 0.2-0.3 part of zinc chloride, 0.5-0.8 part of triethyl silane, 1-2 parts of glass fiber, 2-3 parts of high carbon ferro-chrome alloy powder and 62-65 parts of iron. The surface of the modified nano molybdenum disulfide is coated with a layer of copper film to serve as a solid lubricant which is added to a substrate material, meanwhile the silicon carbide, neodymium, boron and other ingredients are further added, metal particle phase change is changed by adopting sintering, infiltration and heat treatment processes, and the prepared product is uniform in texture, dense, stable and free of black spot and other defects.