The invention discloses a method for separating a
methanol-containing
organic solvent binary
azeotrope. The method comprises the following steps: S1, rectifying a
methanol-containing
organic solvent solution by using a first rectification
tower, and repeatedly heating and rectifying the solution to remove impurities and concentrate in order to obtain an
methanol-containing azeotropic
organic solvent A1; S2, heating the methanol-containing azeotropic organic
solvent A1, performing repeated cycle purification by using
pervaporation modules 3, heating the purified organic
solvent A1 to a certaintemperature, separating a methanol
vapor liquid A2 containing an extremely small amount of other organic solvents through a penetration side port under a vacuum condition under the action of
pervaporation membranes, and cooling the methanol
vapor liquid A2 by using a condenser to obtain a methanol solution A3 containing the extremely small amount of other organic solvents; and S3, rectifying the methanol solution A3 by using a second rectification
tower to respectively obtain methanol and an
azeotrope containing an extremely small amount of methanol. The method has the advantages of effectiveness in separation and
recovery of the methanol-containing organic
solvent binary
azeotrope by using the modules and the rectification towers, low
energy consumption, simplicity in operation of the whole
system, simple process, solving of the difficulty in the separation of the methanol-containing azeotrope in the
chemical industry, and saving of 30-60% of energy.