The invention discloses a vulcanized rubber for shoes capable of realizing high effective and fast vulcanization and a preparation method and a vulcanization process thereof. The vulcanized rubber isprepared from natural rubber, styrene-butadiene rubber, butadiene rubber, accelerator B, accelerator BM, accelerator DS, nanometer zinc oxide, rubber softening oil, sulphur, stearic acid, aging resister CD, carbon black N330, pine tar oil, solid coumarone, reclaimed rubber and pot clay. Compared with the prior art, the vulcanized rubber of the invention has suitable starting time of vulcanization,faster velocity of vulcanization and higher thermal oxidative aging property, the vulcanization efficiency is increased, and the heat-conducting property, processing safety and storage property of the rubber are increased in the vulcanization process; the provided vulcanization process can effectively shorten the vulcanization time, improve the vulcanization quality and increase the vulcanizationefficiency to 2-3 times of the original one.