The invention provides a method for improving
methane purity in a
sludge anaerobic digestion generated
biogas. The method comprises the following steps: concentrating organic
sludge till a
solid content is 20-40g / L; adding an additive, and controlling a pH value to 4.0-6.0, and carrying out a hydrolytic acidification reaction at 35-39 DEG C; adjusting the pH value of the
sludge after hydrolytic acidification to 6.0-6.5, carrying out an
anaerobic digestion reaction, and collecting a
biogas. By adopting the method,
calcium nitrite is adopted as the additive, so that sludge
lysis and
hydrolysis acidification can be improved, the anaerobic acid generation velocity of the sludge is greatly increased, furthermore, the sludge
anaerobic digestion efficiency is improved; due to the addition of thecalcium
nitrite, a function of blocking carbon is also achieved, the concentration of
carbon dioxide in the
biogas is also reduced, and the purity of
methane is improved; as the pH value is adjusted twice, both acidic
hydrolysis of the sludge under the action of the
calcium nitrite is improved, and growth of
hydrogen type methanogens in an anaerobic
methanogenesis period is facilitated, the potential that the
carbon dioxide is in reaction with
hydrogen to generate the
methane is improved, and the purity of the methane in the biogas is further improved.