The invention discloses a high temperature-resistant and anti-aging two-side coated polyester aluminized film, which is prepared by double-side coating of a polyester substrate. Specifically, one side is coated with a PMMA composite coating, and the other side is coated with a polyurethane composite coating, wherein the polyurethane composite coating is prepared from the following raw materials by weight part: 40-50 of a waterborne polyurethane emulsion, 3-5 of a polytetrafluoroethylene emulsion, 2-4 of rosin, 2-4 of acrylic acid, 2-4 of dimethyl silicone oil, 0.1-0.2 of turkey red oil, 2-4 of nano alumina, 1-2 of nano titanium dioxide, 0.2-0.4 of propyl gallate, and 40-50 of water. The aluminized film provided by the invention not only can effectively prevent adhesion phenomenon, has good barrier properties, high peel strength, good acid and alkali resistance, increases the compounding fastness on the back of the aluminized film, and has good use performance, but also has good high temperature resistance, anti-aging properties, long service life and high practical value.