Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Preparation method of titanium dioxide/polysiloxane photocatalytic composite film

A technology of titanium dioxide and polysiloxane, which is applied in the field of preparing titanium dioxide/polysiloxane photocatalytic composite film, which can solve the problems of poor photocatalysis and ultraviolet shielding ability, poor mechanical properties of the coating, and no three-dimensional crosslinking structure. , to achieve excellent organic/inorganic amphotericity, obvious UV shielding effect, and excellent photocatalytic function

Active Publication Date: 2014-01-01
ZHEJIANG SCI-TECH UNIV
View PDF5 Cites 12 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the titanium sol particles produced under this system are mainly amorphous, and their photocatalytic and UV shielding capabilities are poor.
[0005] In addition, the Chinese invention patent application with publication number CN101928517A discloses a method of physically blending anatase titanium sol and polysiloxane solution to prepare nanometer self-cleaning coatings. The process described in this method does not involve the reaction between silicone oil molecules , and there is no three-dimensional cross-linking structure, so the mechanical properties of the coating itself are not good, so it can only be used for coating

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Preparation method of titanium dioxide/polysiloxane photocatalytic composite film
  • Preparation method of titanium dioxide/polysiloxane photocatalytic composite film
  • Preparation method of titanium dioxide/polysiloxane photocatalytic composite film

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1~16

[0047] Under stirring, a certain amount of vinyl-terminated silicone oil viPDMS, hydrogen-containing silicone oil PMHS, titanium sol and reinforcing agent silicon dioxide (SiO 2 , powder) into the film-forming solvent, the film-forming solvent and the dispersion medium in the titanium sol are selected from toluene, and mixed uniformly (the total weight of vinyl silicone oil viPDMS and hydrogen-containing silicone oil PMHS is 100g, which is used as a benchmark for the quality of other materials) . The Karstedt platinum catalyst was added dropwise to initiate the hydrosilylation reaction between silicone oils, and poured into a polytetrafluoroethylene mold. At a dry room temperature of 25°C, a film is gradually formed with the volatilization of the solvent and the progress of the hydrosilylation reaction, and a three-dimensional cross-linked structure is built. After 24 hours, a titanium sol particle uniformly dispersed in the polysiloxane matrix is ​​obtained. oxygen

[0048]...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
particle diameteraaaaaaaaaa
thicknessaaaaaaaaaa
thicknessaaaaaaaaaa
Login to View More

Abstract

The invention discloses a preparation method of a titanium dioxide / polysiloxane photocatalytic composite film, which comprises the following steps: adding vinyl-terminated silicone oil, hydrogen-containing silicone oil and titanium sol into a film-forming solvent, uniformly mixing, adding a reinforcing agent silicon dioxide, uniformly mixing, adding a platinum catalyst to initiate silicon hydrogen addition reaction, pouring into a mold, and gradually forming the film along with the solvent volatilization and silicon hydrogen addition reaction, thereby obtaining the titanium dioxide / polysiloxane photocatalytic composite film. The method is simple in technique and easy to implement; the crosslinking level of the stereoscopic network structure of the composite film is controllable, and silicon dioxide granules can be uniformly and stably dispersed in the composite film in the form of primary particles and can be easily enriched and embedded in the surface layer of the composite film; and the composite film has the advantages of favorable mechanical strength and obvious ultraviolet shielding effect, has excellent photocatalytic functions of resisting bacteria, degrading organic substances and the like, and can be used in the fields of textiles, paints, buildings, cosmetics, sanitation, medicine and the like.

Description

technical field [0001] The invention relates to an organic / inorganic composite film in the field of polymer chemical industry and its preparation method, in particular to a method of uniformly distributing titanium sol particles in a silicone oil solution, and preparing titanium dioxide / polysiloxane through crosslinking of silicone oil molecules and solvent volatilization A method for photocatalytic composite membranes. Background technique [0002] Anatase Nano TiO 2 Non-toxic and tasteless, strong stability, good UV shielding and visible light transmission, excellent photocatalytic ability, it can be used in textiles, coatings, construction, cosmetics, hygiene, medicine and other fields under the action of adhesive adhesion, which can endow Continuous and stable UV shielding, bactericidal and antibacterial, degrading dirt, self-cleaning and other effects for the target object. However, in recent years, more and more studies have shown that anatase TiO 2 The high-energy ...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Applications(China)
IPC IPC(8): C08J5/18C08L87/00C08L83/10C08K3/22C08K3/36C08G81/00B01J31/38
Inventor 戚栋明曹俊陈智杰吴明华
Owner ZHEJIANG SCI-TECH UNIV
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products