The invention belongs to the field of preparation of ionic
hydrogen bond organic framework materials, and particularly discloses an ionic
hydrogen bond organic framework material with
proton conduction performance, the
chemical formula of the ionic
hydrogen bond organic framework material is {TPE-SO3H. 2 (DBD). 2 (DMF). 4 (H2O)} n, n is a positive integer, TPE-SO3H is 1, 1, 2, 2-tetrasulfonic acidphenyl
ethylene, DBD is (C5NH4NH2) 22+, and DMF is N, N '-
dimethylformamide. The
structural unit belongs to a triclinic
system, the
space group is P-1, the molecular formula is C52H62N10O18S4, the
cell parameters are as follows: alpha = 102.789 degrees, beta = 99.968 degrees and gamma = 112.169 degrees, each repetitive unit comprises four water molecules and two DMF molecules, two DBD molecules and one TPE-SO3H molecule, and amino groups on the DBD molecules and
sulfonate groups on the TPE-SO3H molecule form a one-dimensional
hydrogen bond network with water molecules. The material has good
thermal stability, and has good performance for
proton transportation. The invention discloses the preparation method of the material, the synthetic raw materials are easy to obtain, and the preparation process is simple. The ionic
hydrogen bond organic framework material disclosed by the invention can be used as a
proton conducting material and has a very good application prospect.