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32results about How to "Continuous degradation" patented technology

Iron carbon and bentonite sodium alginate gel catalyst and preparation method and application thereof

The invention discloses an iron carbon and bentonite sodium alginate gel catalyst and a preparation method and application thereof. The catalyst is made by crosslinking bentonite, active carbon, sodium alginate, deionized water and iron powder through calcium chloride, wherein bentonite and sodium alginate are taken as an embedding medium and calcium chloride is taken as a cross-linking agent. The catalyst together with persulfate is put in wastewater containing organic pollutants. The catalyst contacts persulfate to generate a large amount of sulfate free radicals with strong oxidability, so that the organic pollutants are oxidized and degraded.
Owner:HUAQIAO UNIVERSITY

Ferric-carbon complex as well as preparation and application thereof

The invention discloses a preparation method for a ferric-carbon complex which comprises the following steps that grinding mediums with volume accounting for 70%-80% of the volume of a cavity are arranged in the cavity of a wet-grinding sand mill, wherein the grinding mediums are iron balls with the diameter of 0.15 mm or zirconia with the particle size of 0.9-1.1 mm; active carbon powder and micron order iron powder are mixed according to the mass ratio of 1:(5-10), then a lubrication solvent is added, and grinding is carried out for 1-4 hours at a grinding speed of 2000-4000 rpm; the mixed liquor after grinding is subjected to solid-liquid separation, and solid particles are cleaned with ethyl alcohol, and are vacuum dried to obtain the ferric-carbon complex. The ferric-carbon complex prepared in the invention can be used for in-situ remediation of contamination with chlorinated organics and heavy metal contained in underground water.
Owner:ZHEJIANG UNIV OF TECH

Preparation method of magnetic oxygen deficient cobalt ferrite bimetal oxide composite catalyst

The invention discloses a preparation method of a magnetic oxygen deficient cobalt ferrite bimetal oxide composite catalyst. In the preparation method provided by the invention, an oxygen vacancy is introduced into CoFe2O4(CFO) with a hydrogen reduction method to prepare oxygen deficient CoFe2O4(HCFO), so that the electron transfer capacity of the catalyst is improved, and the amount of catalyticsites is increased; the catalytic activity of the catalyst is strengthened through the synergistic effect of the oxygen vacancy and transition metal; and the oxygen deficient CoFe2O4(HCFO) can effectively activate persulfate to produce a great quantity of free radicals to degrade organic matters which are difficult to degrade in water. The prepared magnetic oxygen deficient cobalt ferrite bimetaloxide composite catalyst has very strong magnetism, can realize recovery utilization of the catalyst and reduces secondary pollution.
Owner:HUAQIAO UNIVERSITY

Remediation device for organic contaminated soil

The invention discloses a remediation device for organic contaminated soil, which is provided with a water spraying pipe, a water pumping pipe and a backfilling pipe for directly conveying an oxidizing agent and a mud-water mixture and backfilling soil correspondingly, sulfate radicals are generated through the reaction of persulfate and filler, pollutants are degraded when the contaminated soil is sprayed and impacted, and the mud-water mixture falling by impact is pumped into a processor main body, and under the combined action of a ultrasonic generation device and a ultrasonic vibration column and continuous supply of small ozone bubbles, organic pollutants are degraded in an accelerated manner, and soil particles are settled in the accelerated manner and enter the backfilling pipe. According to the device, the treatment process of solid pollution is fluidized, the polluted soil is continuously, effectively and deeply remedied, a large amount of oxidizing agents do not need to be injected into the ground, waste of the oxidizing agents and pollution to the soil and underground water are greatly reduced, the defects of traditional in-situ remediation are overcome, heavy engineering machinery for ex-situ remediation does not need to be used for excavating the soil, and the operation is simple, economical and effective.
Owner:GUANGDONG UNIV OF TECH +1

Integrated water treatment system for treating both water for seawater recirculating aquaculture and tail water

PendingCN110255809AReduce concentration effectContinuous Phosphorus and Nitrogen RemovalSludge treatmentWater/sewage treatment by irradiationSludgeWater quality
The invention provides an integrated water treatment system for treating both water for seawater recirculating aquaculture and tail water. The integrated water treatment system comprises a sewage collection tank, a physical filtering device, an air floating pool, an electrode-suspended filler coupled biofilter treating unit, and an ozone-ultraviolet combined pathogenic microorganism killing unit which are connected in sequence, wherein the sewage collection tank, the physical filtering device, the air floating pool, the electrode-suspended filler coupled biofilter treating unit, the ozone-ultraviolet combined pathogenic microorganism killing pool are all connected with a sludge concentration-dehydration device, and the ozone-ultraviolet combined pathogenic microorganism killing pool is also connected with a culture pond. The integrated water treatment system of the invention has the characteristics of high water treatment efficiency and continuous maintenance of the high water quality of an aquaculture system, and the water circulation utilization rate of the system can reach 95% to 98%; and the integrated water treatment system can fully meet the demand for healthy culturing of cultured objects, has a tail water treatment function, and allows the tail water to be discharged after reaching the standard.
Owner:JIMEI UNIV

Preparation method and application of magnetic nano iron-manganese double metal oxide composite catalyst

The invention discloses a preparation method and application of a magnetic nano iron-manganese double metal oxide composite catalyst. The magnetic nano iron-manganese double metal oxide composite catalyst combines Fe3O4 and alpha-MnO2 to overcome the difficulty of recycling and reduce secondary pollution, higher catalytic activity can be achieved through the synergistic effect of the Fe3O4 and thealpha-MnO2, and PS can be effectively activated to generate a large amount of free radicals to degrade organic matters in water. The magnetic nano iron-manganese double metal oxide composite catalystprepared by the method has a saturation magnetization of 39.89 emu / g, and can be quickly separated from water by an external magnetic field.
Owner:HUAQIAO UNIVERSITY

High-efficiency nitrogen and phosphorus removal system for treating aquaculture tail water

PendingCN110240257AReduce concentration effectContinuous Phosphorus and Nitrogen RemovalWater treatment parameter controlTreatment by combined electrochemical biological processesSludgeBiological filter
The invention provides a high-efficiency nitrogen and phosphorus removal system for treating aquaculture tail water. The system comprises a tail water treatment biological filter, suspended filler, a direct current (DC) anodic-cathodic array combination, an electric stirring device and a carbon source replenishment device, wherein the suspended filler is arranged in the tail water treatment biological filter; the DC anodic-cathodic array combination is arranged at the upper part of the tail water treatment biological filter; the electric stirring device is arranged at the lower part of the tail water treatment biological filter; a sludge bucket is arranged at the bottom of the tail water treatment biological filter; the electric stirring device is arranged above the sludge bucket; the carbon source replenishment device is connected with the tail water treatment biological filter by means of a pipeline; the volume ratio of the suspended filler to water body in the tail water treatment biological filter is equal to 20-50%; the density of the suspended filler is 0.92-0.98g / cm<3>. The high-efficiency nitrogen and phosphorus removal system for treating the aquaculture tail water has the advantages of being high in nitrogen and phosphorus removal treatment efficiency and small in land occupancy area, does not need an air pump for oxygenation, is energy-saving, low in cost, free from secondary pollution, simple and convenient in management, and the like.
Owner:JIMEI UNIV

Porous magnesium oxychloride cement-based photocatalytic functional material and preparation method thereof

The invention discloses a porous magnesium oxychloride cement-based photocatalytic functional material and a preparation method thereof. The porous magnesium oxychloride cement-based photocatalytic functional material disclosed by the invention is prepared from 100 parts of light-burned magnesia with the activity content of 60%-65%, 60-200 parts of magnesium chloride water solution with the mass concentration of 22%-31%, 0-30 parts of admixture, 0.2-5 parts of foaming agent, 1-20 parts of photocatalyst and 0.1-1 part of phosphoric acid with the mass concentration of 85%. The porous magnesium oxychloride cement-based photocatalytic functional material disclosed by the invention can significantly improve the capability of degrading harmful pollutants in atmosphere of the porous magnesium oxychloride cement-based photocatalytic functional material by utilizing the characteristics of porous magnesium oxychloride cement and combining with a secondary load, and has the comprehensive capability in the aspects of heat preservation, heat insulation and environmental purification.
Owner:WUHAN UNIV OF TECH

Boron-doped ferro-manganese magnetic biochar material as well as preparation method and application thereof

The invention discloses a boron-doped ferro-manganese magnetic biochar material as well as a preparation method and application thereof. The preparation method of the boron-doped iron-manganese magnetic biochar material comprises the following steps: S1, providing biomass raw materials, namely FeCl3. 6H2O, MnCl2. 4H2O, H3BO4 and ultrapure water; s2, preparing the biomass raw material into powder; s3, dispersing the powdered biomass raw material in ultrapure water, then adding the FeCl3. 6H2O, the MnCl2. 4H2O and the H3BO4, and stirring to obtain a mixed solution; and S4, drying the mixed solution overnight, and then carrying out pyrolysis treatment to obtain a pyrolysis product. The ratio of the addition amount of the FeCl3. 6H2O to the addition amount of the MnCl2. 4H2O to the addition amount of the H3BO4 is 16.22 to 5.94 to 1. According to the preparation method disclosed by the invention, B atoms, Fe compounds and Mn compounds are doped into biomass raw materials, so that the boron-doped ferro-manganese magnetic biochar material is prepared. The prepared boron-doped iron-manganese magnetic biochar material has a good removal effect on pollutants, is high in applicability, has extremely high stability and reusability, and is an environment-friendly catalyst.
Owner:HEFEI UNIV OF TECH

Preparation method and application of ferromanganese layered bimetal hydroxide catalyst

The invention discloses a preparation method and application of a ferromanganese layered bimetal hydroxide catalyst. According to the invention, the ferromanganese layered bimetal hydroxide catalyst is prepared through a co-precipitation method, wherein the electron transfer capacity of the catalyst is enhanced through the synergistic effect of ferromanganese bimetal, catalytic sites are increased, and the adsorption capacity of the catalyst is improved through exchange of interlayer anions and target pollutants. The ferromanganese layered bimetal hydroxide composite catalyst prepared by the method can effectively activate persulfate to generate a large number of free radicals and efficiently degrade refractory organic matters in water.
Owner:HUAQIAO UNIVERSITY

NAS immobilized carrier microorganism generator and technology for treating sewage by NAS solidified carrier microbial generator

The invention discloses an NAS immobilized carrier microorganism generator and a technology for treating sewage by using the NAS immobilized carrier microorganism generator. The NAS immobilized carrier microorganism generator comprises a barrel-shaped shell, a cover body arranged at the upper end of the shell, and a first aeration pipe which penetrates through the cover body and is fixedly connected to the inner bottom of the shell, and a through hole penetrating through the shell is arranged; a microorganism immobilized carrier is filled between the inner wall of the shell and the outer wallof the first aeration pipe, wherein the microorganism immobilized carrier is a 1-5 cm porous ceramic material prepared by mixing and firing clay and diatomaceous earth in the mass ratio of 50: 1; microorganisms extracted from nature and transfer enzymes are combined in a carrier in a dormant manner by adsorption, covalent bonding and embedding. The technology can be used for replacing a link of culturing the microorganisms by utilizing activated sludge when the sewage is treated by an activated sludge method, high-concentration microbial flora can be continuously supplied to the sewage for a long time without addition, no activated sludge is not generated in the sewage treatment process, and the effect of zero emission of the sludge is achieved; and the technology can also be applied to microorganism treatment of polluted water bodies of lakes and rivers and other polluted water bodies.
Owner:云南科善环保科技有限公司

A device for remediating organically polluted soil

The invention discloses a repairing device for organic polluted soil, which is provided with a water spraying pipe, a water pumping pipe and a backfilling pipe to directly transport the oxidant, the mud-water mixture and the backfilling soil respectively, and utilizes persulfate to react with fillers to generate sulfate radicals, thereby reducing pollution When the soil is sprayed and impacted, the pollutants are degraded, and the mud-water mixture that falls under the impact is pumped into the main body of the processor. Under the joint action of the ultrasonic generating device and the ultrasonic vibration column and the continuous supply of small ozone bubbles, the organic pollutants are accelerated. Degradation, the soil Particles settle at an accelerated rate into the backfill tube. The device of the present invention fluidizes the treatment process of solid pollution, carries out continuous and effective deep restoration of polluted soil, does not need to inject a large amount of oxidant into the ground, greatly reduces the waste of oxidant and the pollution of soil and groundwater, and overcomes the traditional in-situ The disadvantages of repairing are that there is no need to use major engineering machinery for ex-situ repairing to excavate the soil, and the operation is simple, economical and effective.
Owner:GUANGDONG UNIV OF TECH +1

Organic wastewater treatment device and system by utilizing solid adsorbent and low-temperature plasma desorption

The invention belongs to the technical field of organic wastewater treatment, and particularly relates to an organic wastewater treatment device and system by utilizing solid adsorbent and low-temperature plasma desorption. The organic wastewater treatment device is composed of multi-tube parallel coaxial reaction chambers, a metal ground electrode electromagnetic shielding housing, an anode connecting ring, an insulation bracket and the like. The organic wastewater treatment system comprises the organic wastewater treatment device, a high-voltage nanosecond pulse power supply, an air pump, a water pump, an oxygen cylinder, a water storage tank, a gas phase detector and a water quality detector. According to the organic wastewater treatment device and the organic wastewater treatment system, in the condition that other chemical medicines are not introduced, a high-voltage nanosecond pulse technique and low-temperature plasma formed by dielectric barrier discharge are used as technical cores, the adsorption characteristics of the solid adsorbent on organic pollutants in wastewater and the electrical characteristic of easy gas discharge of an interior porous structure are utilized, electric energy is used as unique operating cost, and degradation treatment on the organic wastewater is greenly and efficiently performed. A plurality of reaction chambers are alternately used, so that the industrial actual demand of continuous treatment of the organic wastewater is achieved.
Owner:FUDAN UNIV

Preparation method and application of iron-copper composite catalyst

The invention discloses a preparation method and application of an iron-copper composite catalyst. The preparation method includes the following steps that 1, ferrous sulfate is dissolved in a mixed solution of ethyl alcohol and deionized water, urea is added, and the mixture is stirred to be dissolved; 2, the material obtained in the step 1 is subjected to magnetic stirring and refluxing in an oil bath, the material is centrifugally washed after being naturally cooled, precipitate is obtained, and the precipitate is dried; 3, the material obtained in the step 2 is calcined, and a first component is obtained after natural cooling is completed; 4, copper nitrate is completely dissolved in a mixed solution of ethyl alcohol and ethylene glycol; 5, the first component is added into the material obtained in the step 4, the first component is completely dispersed through ultrasonic treatment, then the mixture reacts for 3-7 h at the temperature of 115-165 DEG C, the mixture is centrifugally washed after being naturally cooled, and precipitate is obtained; 6, the precipitate obtained in the step 5 is dried under the vacuum condition, and the iron-copper composite catalyst is obtained. The adding amount of the prepared iron-copper composite catalyst and the adding amount of persulfate are both small, therefore, cost is reduced, and the catalyst can be separated and reused after being precipitated.
Owner:HUAQIAO UNIVERSITY

Tail-end purification device for overflow pollution of urban inundation drain outlet

The invention discloses a tail end purification device for urban flooding sewage draining exit overflow pollution, a sewage draining exit is arranged on a river channel revetment retaining wall, and the purification device comprises an in-situ purification module which is arranged on the outlet side of the sewage draining exit in a semi-surrounding manner, is tightly connected with the river channel revetment retaining wall and is used for rapidly degrading soluble pollutants in sewage; the filtering and purifying module is arranged on the outer side of the in-situ purifying module in a semi-surrounding manner, is tightly connected with a river channel revetment retaining wall and is used for effectively adsorbing suspended pollutants in sewage; the ecological wetland module is arranged on the outer side of the filtering and purifying module in a semi-surrounding manner, is tightly connected with a river channel revetment retaining wall and is used for further purifying the sewage; the energy dissipation module is arranged on the outer side of the ecological wetland module in a semi-surrounding mode and tightly connected with the river channel revetment retaining wall, and the elevation of the energy dissipation module is higher than the normal water level. The purification device is efficient and convenient, combined sewage can be rapidly purified after being discharged from the water outlet, and the water quality safety of a receiving water body is guaranteed.
Owner:CHANGJIANG SURVEY PLANNING DESIGN & RES
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