The invention relates to a
temperature difference power generation device with a laminated structure and a preparation method of the
temperature difference power generation device, and the temperaturedifference power generation device structurally comprises a thermoelectric material layer, an insulating bonding layer, a top
electrode, a bottom
electrode, a top insulating layer, a bottom insulating layer and an insulating and heat-insulating packaging layer which are arranged in a laminated manner, the
temperature difference power generation device has a long thermoelectric arm length, is beneficial to increasing the temperature difference, and can be used for a thermoelectric power generation environment with natural air heat dissipation. No gap exists between an N-type thermoelectric material and a P-type thermoelectric material, the proportion of the
thermoelectric materials in unit area is large, the structural
internal resistance and
thermal resistance of the thermoelectric powergeneration module are effectively reduced, and the power generation efficiency is improved; the problems of
moisture corrosion and the like can be eliminated by adopting simple edge packaging; the conductive connection between the N-type thermoelectric material and the P-type thermoelectric material adopts a simple spraying or
sputtering process, and the insulating bonding layer connected with theelectrode is relatively thin, so that the
thermal resistance of a
heat transfer surface can be greatly reduced. The
heat transfer surface of the temperature difference power generation device can beprocessed into any shape and is effectively attached to a curved
surface heat source, and the
maximum temperature difference power generation efficiency is obtained.