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High-temperature-resistant environmentally-friendly insulating coating material for electrical steels, and preparation method thereof

An insulating coating and high temperature resistant technology, applied in anti-corrosion coatings, fire-retardant coatings, coatings, etc., can solve the problems of easy cracking of coatings, low coating hardness, poor tolerance, etc., achieve excellent thermal stability, strong chemical The effect of stability and improvement of tolerance

Inactive Publication Date: 2019-01-22
CHANGZHOU VOCATIONAL INST OF ENG
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0009] In view of the problems existing in the above-mentioned prior art, the object of the present invention is to provide a kind of high-temperature-resistant environment-friendly insulating coating for electrical steel and its preparation method, to solve the problem that the existing chrome-free insulating coating usually has certain pollution to the environment, and The coating has low hardness and is easy to scratch. It also solves the problems that the existing coating materials have poor resistance to high-temperature annealing, and the coating is prone to cracking, powder falling, and detachment, and improves the mechanical properties of the coating material. increase density

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] A high-temperature-resistant and environment-friendly insulating coating for electrical steel, the components are: 180kg of aluminum dihydrogen phosphate, 32kg of boric acid, 18kg of ethylene glycol antimony, 65kg of wax emulsion with 40% solid content, and polytetrafluoroethylene The resin emulsion also includes 5kg of silicone waterproofing agent and 700kg of deionized water.

[0024] A method for preparing a high-temperature-resistant environment-friendly insulating coating for electrical steel, comprising the following steps:

[0025] (1) In the stirring state, add 700kg of water, 32kg of boric acid, 180kg of aluminum dihydrogen phosphate and 18kg of ethylene glycol antimony into the reactor according to the metering ratio, mix and stir for 30min to dissolve evenly;

[0026] (2) After cooling down to room temperature, drop into 65kg polytetrafluoroethylene resin emulsion according to the metering ratio in the reactor, and then stir for 5min;

[0027] (3) In the sta...

Embodiment 2

[0031] A high-temperature-resistant and environmentally-friendly insulating coating for electrical steel. The components and their quality of raw materials are: 210kg of aluminum dihydrogen phosphate, 27kg of boric acid, 15kg of ethylene glycol antimony, 48kg of wax emulsion with a solid content of 60%. Tetrafluoroethylene resin emulsion also includes 3kg of silicone water repellent and 388kg of deionized water.

[0032] A method for preparing a high-temperature-resistant environment-friendly insulating coating for electrical steel, comprising the following steps:

[0033] (1) In the stirring state, add 688kg of water, 27kg of boric acid, 210kg of aluminum dihydrogen phosphate and 15kg of ethylene glycol antimony into the reactor according to the metering ratio, mix and stir for 30 minutes to dissolve evenly;

[0034] (2) After cooling down to room temperature, drop into 48kg polytetrafluoroethylene resin emulsion according to the metering ratio in the reactor, and then stir f...

Embodiment 3

[0039] A high-temperature-resistant and environment-friendly insulating coating for electrical steel. The components and the quality of the raw materials are: 180kg of aluminum dihydrogen phosphate, 40kg of boric acid, 22kg of ethylene glycol antimony, 25kg of wax emulsion with a solid content of 60%. Tetrafluoroethylene resin emulsion also includes 8kg of silicone water repellent and 725kg of deionized water.

[0040] A method for preparing a high-temperature-resistant environment-friendly insulating coating for electrical steel, comprising the following steps:

[0041] (1) In the stirring state, add 725kg of water, 40kg of boric acid, 180kg of aluminum dihydrogen phosphate and 22kg of ethylene glycol antimony into the reactor according to the metering ratio, mix and stir for 30 minutes, and dissolve evenly;

[0042] (2) After cooling down to room temperature, drop into 25kg polytetrafluoroethylene resin emulsion according to the metering ratio in the reactor, and then stir f...

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PUM

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Abstract

The invention relates to a high-temperature-resistant environmentally-friendly insulating coating material for electrical steels, and a preparation method thereof, wherein the raw materials comprise,by mass, 15-25% of aluminum dihydrogen phosphate, 0.5-4% of boric acid, 0.5-5% of ethylene glycol antimony, 1-10% of wax emulsion, 0.1-3% of an organosilicon waterproof agent, and the balance of deionized water. The preparation method comprises: (1) sequentially adding water, boric acid, aluminum dihydrogen phosphate and ethylene glycol antimony to a reaction kettle, mixing, stirring, and dissolving uniformly; (2) after cooling to a room temperature, pouring wax emulsion into the reaction kettle according to a metering ratio, and stirring; and (3) pouring an organosilicon waterproof agent intothe reaction kettle according to a metering ratio under stirring, stirring, screening with a 1000 mesh sieve mesh, and discharging the material. According to the present invention, the coating material has advantages of good insulation performance, good corrosion resistance, and good tolerance to high temperature annealing and welding process, and cannot produce cracking, powder falling, sheddingand other failure phenomena at a high temperature.

Description

technical field [0001] The invention relates to a coating, in particular to a high-temperature-resistant and environment-friendly insulating coating for electrical steel and a preparation method thereof. Background technique [0002] Silicon steel insulating coatings can be divided into three categories: organic coatings, inorganic coatings and organic-inorganic composite (semi-inorganic) coatings. Organic coatings rely on polymers to provide insulation, and their interlayer resistance is high. They are mainly used in large and medium-sized equipment such as power plant generators. Organic coatings generally have good adhesion and punching and shearing properties, but their hardness is low, thermal stability is poor, thermal shrinkage deformation is large, pores are prone to occur during welding, and they cannot withstand stress relief annealing. The main components of inorganic coatings are generally metal salts and metal oxides, which have the advantages of high surface h...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D127/18C09D5/25C09D7/61C09D7/63C09D7/65C09D5/08
CPCC08K2003/327C08L2201/08C09D5/00C09D5/08C09D5/18C09D7/61C09D7/63C09D7/65C09D127/18C08L83/04C08K3/32C08K3/38C08K5/057
Inventor 孙致平张翠英孙德松
Owner CHANGZHOU VOCATIONAL INST OF ENG
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