The invention proposes a treatment method for the discoloration of the surface of pure silver products. The pure silver products with discolored surfaces are soaked in a solution prepared with a cleaning agent. After 1-2 hours, the silverware is taken out, cleaned, dried, and soaked in a protective agent. After 30‑50 minutes in the prepared solution, take out the silverware, wash it, and blow it dry. The cleaning agent is prepared from the following raw materials in parts by weight: 10-20 parts of concentrated ammonia water, 3-5 parts of sodium cyanide, 20-30 parts of glucose, 12-17 parts of inorganic alkali and 20-50 parts of polyol; The protective agent has the following structure: the process of the present invention is simple, and the processing time is very short; the normal temperature operation does not cause physical damage to the surface, and the loss of silver is almost zero; the cleaning agent and the protective agent can be stored at room temperature, ready to use, Repeated use, subsequent cleaning is simple, thorough, and low-cost, which is cost-effective compared with other methods.