81 results about "Porphyrin molecule" patented technology
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Porphyrin Definition. A porphyrin is a large ring molecule consisting of 4 pyrroles, which are smaller rings made from 4 carbons and 1 nitrogen. These pyrrole molecules are connected together through a series of single and double bonds which forms the molecule into a large ring.
The invention discloses a quantum dot rate fluorescence probe for zincion detection and a detection method of the quantum dot rate fluorescence probe. The quantum dot rate fluorescence probe for zincion detection is prepared from CdSe / ZnS quantum dots for emitting green fluorescence, and CdSe / CdZnS / ZnS quantum dots for emitting yellow fluorescence and porphyrin molecules in an electrostatic assembly manner; the molarconcentration ratio of the two quantum dots to porphyrin is 1 to 10; the outer layers of the two quantum dots are wrapped by positively charged silicon dioxide shell layers; and the porphyrin molecules are negatively charged sulfur-based porphyrin molecules. By virtue of a rate fluorescence detection method, the quantum dot rate fluorescence probe adopts a simple process, is low in price, good in repeatability, suitable for the environment, drinking water and body liquid, and has a good application prospect.
The invention discloses a peroxide mimic enzyme and preparation and applications thereof, and relates to a horse radishperoxidase bio-mimetic technology, namely a technology of orderly fixing natural enzyme prothetic groups that are porphyrin molecules on the surface of a mass-produced carbon nitridenanosheet in an axial coordination manner so as to produce a mimic enzyme with a structure approaching a natural enzyme protein structure. The various catalytic kinetics indexes of the mimic enzyme are equivalent with that of a natural enzyme. On this basis, a general peroxide mimic enzyme CoII-Hemin@g-C3N4 nanometer biological probe is designed, and a high-sensitivity high-specificity biosensor used for detection of the H7N9 avian influenza virus is constructed, wherein the biosensor has characteristics of stable electrogenerated chemiluminescence output signals and a low detection lower limit. The mimic enzyme can be used in the aspects of biomedicine, clinical diagnosis, environment monitoring, judicial expertise, and the like.
The invention discloses a method for preparing a phenylamino porphyrin self-assembled nanomaterial by adopting a co-solvent method. The method comprises the following steps: 1) preparing CTAB, SDS, MTAB or P123 aqueous solution; 2) preparing a DMF solution of phenylamino porphyrin; and 3) adding the solution in the step 2) into the solution in the step 1), stirring for 40-50h at 25 DEG C, and performing centrifugal separation, to obtain a solid, namely the phenylamino porphyrin self-assembled nanomaterial. The method has the advantages of the original methods, the yield problem can be solved as a great amount of phenylamino porphyrin is dissolved in the DMF solution; by taking micelle as a confinement template, the self assembling can be conducted under the assistance of an emulsifying agent by changing the soluble state of phenylamino porphyrin molecules into a non-soluble state through the weak phase interaction between molecules, finally the porphyrin molecule assembled body with controllable shapes can be obtained, and the assembled material has an important role in the fields of photocatalysis, nanodevices and the like.
The invention discloses a micro-nano reactor based on phthalocyanine bridging methylationcyclodextrin, and in particular relates to a supermolecule tubular micro-nano reactor for catalyzing cross coupling reaction generated by arylhalide and an organic boric agent. The micro-nano reactor has such a building mode that porphyrins molecules are enveloped into a cavity of methylationcyclodextrin; a hydrophilic clathrate is adopted to construct a hydrophilic surface of the reactor and is exposed to a water phase; hydrophobic alkyl chains are crossed with each other to form a hydrophobic interlayer of the micro reactor. According to the preparation method, the micro-nano reactor is obtained by supermolecules self-assembly of a phthalocyanine axial bridging methylationcyclodextrin host compound and an amphipathy porphyrin guest compound. The palladium-loaded micro-nano reactor prepared by the method has the advantages that the synthesis route is simple, the reaction conditions are mild, the aftertreatment is simple and convenient, and the yield is very high; the micro-nano reactor is suitable for amplification synthesis and actual production application. The coupling reaction yield is high, and the use of a toxic organic solvent is avoided; the micro-nano reactor serving as a catalyst for the coupling reaction has a wide application prospect.
The invention relates to the field of intelligent food packaging, and particularly relates to a metalloporphyrin / agarose freshness indicating label and a preparation method thereof. According to the freshness indicating label, agarose gel is used as a base material, the agarose gel comprises a metalloporphyrin color developing agent and a plasticizer which are uniformly dispersed in the agarose gel, the acid-base detection sensitivity of porphyrin molecules is high, and in combination with the good film-forming performance of the agarose gel, the prepared metalloporphyrin / agarose freshness indicating label can simply, rapidly and conveniently indicate the decay condition of meat products, and meanwhile the preparation method is simple, novel, low in cost, good in response performance, andhas wide application prospects.