The invention discloses a fluorescent color changing eutectic material under ultra-
high pressure conditions and a preparation method thereof, and belongs to the field of
molecular solid-state light-emitting materials. A plurality of multi-fluoro-substituted organic small molecules are selected as co-
assembly units, and a novel multi-component molecular co-
crystal compound is prepared by using a
solvent-assisted
grinding method, a
solvent evaporation method, an ultrasonic synthesis method and the like. Cyano substituted p-
phenylene vinyl type molecules and the co-assembled small molecules mutually recognize each other through multiple
hydrogen bonds, Pi- Pi force and other non-covalent forces to form a structure-ordered supramolecular structure, changing self-stacking
molecular configuration and spatial arrangement of original cyano-substituted
phenylene vinyl type molecules so as to achieve a certain
modulation effect on photophysical properties. The novel fluorescent color changing eutectic material prepared by the method can produce different fluorescent discoloration behaviors under the ultra-
high pressure conditions, is the first fluorescent discoloration
eutectic system underthe ultra-
high pressure conditions, and has application prospects in the fields of new optical sensors and
pressure sensitive materials and the like.