The invention provides a hyperbranched
polymer, a hyperbranched polycarboxylic acid-series super
plasticizer and a preparation method thereof. The preparation method comprises the following steps of: undergoing an
addition reaction and an ammonolysis reaction on alkenyl amine, polymethylmethacrylate,
ethylene diamine and 2-
acrylamide-2-
sodium methylacrylsulfonate serving as raw materials to obtain a hyperbranched
polymer with a structure shown as a formula (I), (II), (III) or (IV); undergoing a
polymerization reaction on the hyperbranched
polymer, an esterification
monomer and a crosslinking agent; and preparing a hyperbranched polycarboxylic acid-series super
plasticizer with a two-step process. The preparation method provided by the invention has the advantages of simple process, easiness for controlling a preparing process and operating, readily-available raw materials, low production cost and suitability for industrial production. Due to the adoption of the hyperbranched polycarboxylic acid-series super
plasticizer, the comprehensive performance of concrete is improved. As proved by an experiment result, the hyperbranched polycarboxylic acid super plasticizer provided by the invention has high
slump loss resistance, high water-reducing rate and high
compressive strength.