The invention relates to a self-supported
titanium nitride /
graphene combined
electrode and a preparation method of the self-supported
titanium nitride /
graphene combined
electrode. The preparation method comprises the steps that (1)
titanium foil is soaked with acid liquid, ultrasonic
processing is conducted on the
titanium foil, the
titanium foil is taken out, washed by deionized water, and soaked with a
hydrogen peroxide solution, the temperature of the solution is increased to 60DEG C-95DEG C from the
room temperature under the normal pressure through heating, the temperature is kept for 10-60 minutes, and the
titanium foil is taken out and dried after an reaction ends; (2) the titanium foil is placed into a tubular
atmosphere furnace,
ammonia is fed into the tubular
atmosphere furnace to conduct
nitrogen treatment on the titanium foil, and
titanium nitride is formed on the surface of the titanium foil; (3) a layer of
graphene is formed on the surface of the
titanium nitride in a deposition mode through a dipping-pull method or a
drop casting method, and the graphene and the
titanium nitride are placed into a
drying oven at the temperature
ranging from 60DEG C to 100DEG C to be dried, so that the self-supported titanium
nitride / graphene combined
electrode is obtained. Compared with the prior art, a graphene / titanium nitride three-dimensional network is directly formed on the surface of flexible
metal foil so that the self-supported electrode can be formed. The combined electrode is low in cost, high in
porosity ratio and good in catalytic activity and electrical
conductivity, and has the broad application prospect.