The invention discloses a medium-voltage working electrolyte of an aluminum electrolytic capacitor. The electrolyte comprises constituents based on ratio by mass: 36.5-78% of main solvent, 3-20% of auxiliary solvent, 8-15% of main solute, 6-17% of auxiliary solute, 0.05-0.3% of waterproof mixture, 2-7% of voltage-resistant promoter, 1.5-3% of formation special modifier and 0.6-1.5% of hydrogen elimination agent, wherein the main solvent is ethylene glycol. A mixed solvent system is employed, high-temperature characteristic is ensured, and low-temperature characteristic is also compatible; theboiling point (245 DEG C) of diethylene glycol is high, the condensation point (-44 DEG C) of Gamma-butyrolactone is low, an appropriate amount of voltage resistant promoter is added, U<flash>=alg Rho+b (V), Rho is resistivity (ohm. cm) of the electrolyte, a and b are relevant constants of the electrolyte, thus, the electrical conductivity of the medium-voltage electrolyte is high to cause that the flash voltage is low, and enough voltage resistant capability can be ensured under the condition of high electrical conductivity by the introduction of the voltage resistant promoter; and moreover,with the addition of a corrosion resistant agent, the corrosion probability during long-term working is reduced, and the lifetime of a product is ensured.