The present invention relates to an electrochemical measurement device, in particular to an electrolytic cell device based on the on-line electrochemical measurement of the transmission line, including an electrolytic cell, a fixing clip, etc., wherein the electrolytic cell includes an electrolyte container with an upward opening, a square The connecting part of the partition and the workpiece, the square partition is located between the electrolyte container and the connecting part of the workpiece, and its periphery protrudes to form a square ring-shaped boss; the connecting part of the workpiece is a columnar member, which is opened along the central axis of the connecting part of the workpiece It has a cylindrical through hole, and the cylindrical through hole passes through the workpiece connection part and the square partition and communicates with the inner cavity of the electrolyte container. The advantage of using this device is that it does not need to destroy the workpiece of the transmission line, avoids adverse effects on the transmission line, ensures the safe operation of the transmission line, and fully realizes the on-line electrochemical measurement of the workpiece of the transmission line. The purpose of quickly measuring the corrosion rate of metal components of power grid equipment can be realized.