The invention relates to efficient coagulant special for emulsified oil waste water and a preparation method of the efficient coagulant. The efficient coagulant comprises, by weight percentage, 8-18% of ferrous sulfate, 16-37% of aluminum sulfate, 1-6% of sodium chlorate, 2-19% of manganese salt, 20-30% of acid, 16-28% of sodium silicate solution and 1-3% of sodium hydroxide. The preparation method of the efficient coagulant includes: using the sodium silicate and acid as raw materials to prepare activated silicate, and dissolving the aluminum sulfate, ferrous sulfate, manganese salt and the like in the acid to have polymerization reaction with the activated silicate so as to finally produce the efficient coagulant special for emulsified oil waste water. The efficient coagulant used for treating the emulsified oil waste water of different concentration is applicable to the treatment of other waste water, low in use amount and high in oil removing efficiency as compared with like products, stable in treatment effect, simple in preparation process, safe, free of pollution, and the like.