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38results about How to "Narrow residence time distribution" patented technology

Reaction device for preparing low-carbon olefin by employing methyl alcohol and/or dimethyl ether

The invention relates to a reaction device for preparing low-carbon olefin by employing methyl alcohol and / or dimethyl ether, in particular to a reaction device for preparing low-carbon olefin by employing methyl alcohol and / or dimethyl ether. The reaction device mainly comprises a dense-phase fluidized bed reactor (2), a cyclone separator (3), a stripper (5), a lift pipe (7), a dense-phase fluidized bed regenerator (10), a cyclone separator (11), a stripper (13) and a lift pipe (15), wherein the dense-phase fluidized bed reactor (2) is partitioned into n (n is greater than or equal to 2) secondary reaction zones by material flow controllers (17); and the dense-phase fluidized bed regenerator (10) is partitioned into m (m is greater than or equal to 2) secondary regeneration zones by the material flow controllers (17). By virtue of the reaction device, the problems in the prior art that carbon deposit distribution of a catalyst is uneven and low-carbon olefin selectivity is relatively low are solved.
Owner:中科催化新技术(大连)股份有限公司

Process and apparatus for removing volatile substances from highly viscous media

Evaporator apparatus (1) for the treatment of viscous media comprised of at least a feed chamber (2) having a perforated tray (3), a tube-bundle heat exchanger (4) connected thereto having perpendicularly arranged tubes (8) and a devolatilization chamber (5) connected thereto, a discharge unit (6) for the product and a vapor take-off (7) for removing volatile components, the tubes (8) of the heat exchanger (4) having a rectangular cross section over the greater part of their length.
Owner:BAYER TECH SERVICES GMBH

Pipe reactor with static mixing device

The invention discloses a pipe reactor with a static mixing device. The pipe reactor with the static mixing device comprises a Y-shaped fluid feed port, a static mixing device, and a pipe reacting device, wherein the Y-shaped fluid feed port is provided with a fluid inlet A and a fluid inlet B, and the static mixing device comprises a jacket and an SK-type static mixer; a jacketed inlet and a jacket outlet are arranged on the jacket, and the pipe reacting device comprises a reacting device shell and a pipe reactor; a heat carrier inlet and a heat carrier outlet are arranged on the reacting device shell, and one end of the SK-type static mixer is connected with the Y-shaped fluid feed port; and the other end of the SK-type static mixer is connected with the pipe reactor. According to the pipe reactor with the static mixing device, two streams of fluids have a good mixing effect at a low flow and a flow rate, the mixing and the reaction process of the two streams of fluids are carried out at different temperatures, and part of raw material is avoided being pre-reacted, so that the mixing and the reaction process of the two streams of fluids are safer and more stable. The pipe reactor with the static mixing device is suitable for the mixing reaction process of the two streams of fluids at a low flow and a flow rate.
Owner:ZHEJIANG UNIV

Embedded type short-screw-flight same-direction asymmetric multi-screw extruder and machining method thereof

The invention discloses an embedded type short-screw-flight same-direction asymmetric multi-screw extruder and a machining method thereof. A screw mechanism in the extruder comprises a first screw and a second screw which are engaged with each other. The first screw is of a single-start thread structure, and the second screw is of a four-start thread structure. Embedded type short screw flights used as auxiliary screw flights are arranged in screw channel passageways each formed between two adjacent main screw flights in the first screw. The height of the auxiliary screw flights is smaller than or equal to the height of the main screw flights. According to the machining method of the embedded type short-screw-flight same-direction asymmetric multi-screw extruder, material conveying is achieved under the common effect of the axial positive displacement conveying force of the screw mechanism and the friction force between the first screw and the second screw. By means of the homoclinic orbit flow disturbance which is introduced through the embedded type short screw flights and shaped like the Arabic number '8', the whole-journey chaotic mixing in the screw channel passageways, the one-to-two topological chaotic effect formed by a passageway composed of the first screw and the second screw, the periodic compression and expansion effect generated by the passageways of the screw mechanism and the differential-speed rotation effect of the two screws are triggered, and the materials are sufficiently mixed, molten, mixed and plastified.
Owner:GUANGDONG IND TECHN COLLEGE

Homodromous self-cleaning double-screw extrusion machine with number of starts gradually changing and with whole-process self-cleaning function and machining method thereof

The invention discloses a homodromous self-cleaning double-screw extrusion machine with the number of starts gradually changing and with a whole-process self-cleaning function and a machining method thereof. A screw assembly of the extrusion machine comprises a first screw and a second screw, wherein the first screw and the second screw rotate at equal speed and in the same direction and are kept engaged. The first screw comprises a first single-start thread element, a first transitional element, a multi-start thread element, a second transitional element and a second single-start thread element which are connected in sequence. The second screw comprises a first single-start thread element, a third transitional element, a multi-start thread element, a fourth transitional element and a second single-start thread element which are connected in sequence. The machining method includes the steps that materials are conveyed through rotation of the first screw and the second screw, and constituents in the materials are promoted to be mixed through a structure of gradually changing numbers of starts of threads; a runner expands, contracts and expands again in sequence, so that the materials are divided, combined and divided again in the runner for chaotic mixing; self-cleaning is achieved through mutual wiping of the first screw and the second screw.
Owner:GUANGDONG IND TECHN COLLEGE

Same-direction self-cleaned twin-screw extruder with baffle plates and processing method thereof

The invention discloses a same-direction self-cleaned twin-screw extruder with baffle plates and a processing method thereof. A screw mechanism of the same-direction self-cleaned twin-screw extruder comprises a first screw rod and a second screw rod, wherein the first screw rod is in a single thread structure, and the second screw rod is in a double thread structure; the baffle plates are arranged in the screw grooves of the first screw rod, and the height of each baffle plate is less than the depth of each screw groove of the fist screw rod; 8-shaped hyperbolic flow disturbance can be formed at the baffle plates in the screw grooves of the first screw rod; and the first screw rod and the second screw rod rotate at the same speed, are meshed with each other at all times and are self-cleaned simultaneously. According to the processing method, the screw grooves are triggered under the action of 8-shaped hyperbolic flow disturbance formed due to the arrangement of the baffle plates to mix materials chaotically all the way, two flowing ways formed by the two screw rods fulfill the topological chaotic mixing function of dividing materials into two parts, mixing the two parts of materials and dividing the mixture into two parts, and the first screw rod and the second screw rod fulfill the functions of compressing, expanding, recompressing and reexpanding periodically. Under the joint action of three reinforced mixing mechanisms, the materials can be molten and mixed efficiently.
Owner:GUANGDONG IND TECHN COLLEGE

Continuous production method and continuous production device for synthesizing biruea

The invention discloses a continuous production method for synthesizing biruea, comprising the following steps of: (1) continuously adding hydrazine hydrate and a urea solution into the middle lower part of an oscillating flow tubular reaction crystallizer to react and generate biruea grains; (2) along with the processes of reaction and crystallization, gradually increasing the grain diameter of the biruea grains, settling the biruea grains at the bottom of the reaction crystallizer, continuously discharging the biruea grains settled at the bottom of the reaction crystallizer, separating solids and liquid and cleaning to obtain the biruea; and (3) continuously discharging mother liquid with unconverted reactants from the upper part of the reaction crystallizer and continuously dischargingammonia as a by-product from the top of the reaction crystallizer. The invention also discloses the oscillating flow tubular reaction crystallizer which is used for implementing the production method. The continuous production method is suitable for alkaline condensation technology, increases an average reaction rate, has high production capacity of unit reactor volume and can control the grain diameter of the biruea to separate subsequently and reduce purification cost.
Owner:ZHEJIANG ENG DESIGN +2

Homodromous self-cleaning double-screw extruder with stretching function and processing method thereof

The invention discloses a homodromous self-cleaning double-screw extruder with a stretching function. The homodromous self-cleaning double-screw extruder with the stretching function comprises a machine barrel, a first screw and a second screw. The cross section of the first screw and the cross section of the second screw are both formed by multiple sections of circular arcs which are unequal in radius of curvature, and the cross section of the first screw and the cross section of the second screw are different in shape. The invention further provides a processing method of the homodromous self-cleaning double-screw extruder with the stretching function. According to the homodromous self-cleaning double-screw extruder with the stretching function and the processing method of the homodromous self-cleaning double-screw extruder with the stretching function, when the first screw and the second screw which are different in cross-section shape rotate in an identical direction, periodical change happens to a cross-section shape of a flow passage, so that a compression action and a squeezing action are applied on materials in the flow passage, a flowing space of the materials is compressed and expanded in a periodical mode, and therefore a chaotic mixing effect is generated, a mixing and heat transfer process is strengthened, a thermal and mechanical process which is plasticized is largely shortened, energy consumption is low, an energy-saving and consumption-reducing effect is notable.
Owner:GUANGDONG IND TECHN COLLEGE

Co-rotating differential multi-screw extruding machine with gradually changing type thread number and machining method thereof

InactiveCN107031015AFacilitate interface updatesIncrease the exhaust areaDifferential equationEngineering
The invention discloses a co-rotating differential multi-screw extruding machine with the gradually changing type thread number and a machining method thereof. A first threaded rod in the extruding machine comprises two single-start thread elements, three single-start-gradually-changed-to-double-start transition thread elements, a double-start thread element and three double-start-gradually-changed-to-single-start transition thread elements; and a second threaded rod comprises two double-start thread elements, three double-start-gradually-changed-to-four-start transition thread elements, a four-start thread element and three four-start-gradually-changed-to-double-start transition thread elements. According to the machining method, a threaded rod mechanism achieves five enhancement mixing mechanisms by adopting the structure of the threaded rod mechanism, and conducts all-sided enhancement mixing on materials.
Owner:徐百平

Chip type structure catalysis multiphase microreactor

The invention relates to a chip type structure catalysis multiphase microreactor which comprises a microreaction chip and a structure catalyst and comprises a gas-liquid two-phase reactant distributor, a multiphase catalysis reaction chamber, heat exchange channels on two sides of the catalysis reaction chamber and heat exchange channels on two sides of the gas-liquid two-phase reactant distributor; and gas-liquid or liquid-liquid is uniformly distributed to an inlet of a catalyst with a high-precision structure at the rear end by utilizing a dendritic distribution form and T-shaped shear mixing, and flowing heat exchange areas are respectively arranged on the upper side and the lower side of the catalytic reaction chamber. By optimizing the structural design of the reactor, the reactor has the advantages of excellent mass transfer and heat transfer characteristics, controllable reactant retention time, narrow retention time distribution, personalized design of a catalyst structure according to a reaction system, easiness in amplification and the like, and solves the bottleneck problem that a homogeneous catalyst or a fine powder catalyst is difficult to separate from a product; and the chip type structure catalysis multiphase microreactor is widely applicable to petrochemical, chemical, pharmaceutical, environmental protection, food and other fields.
Owner:EAST CHINA UNIV OF SCI & TECH

Two step process for chemically recycling plastic waste

A two-step process that includes a pyrolytic first step carried out in a mechanically or gravitationally impelled reactor and a catalytic fluid bed second step that upgrades the resulting vapor, for the conversion of waste plastics, polymers, and other waste materials to useful chemical and fuel products such as paraffins, olefins, and aromatics such as BTX is described.
Owner:R PLUS JAPAN LTD

Device and method for continuously isomerizing epoxide

The invention relates to a device and a method for continuously isomerizing epoxide, which can be used for continuous isomerizing preparation of corresponding allyl alcohol products from epoxide. Themethod comprises steps as follows: reaction raw materials and carrier gas are preheated to certain temperature, the raw materials are contacted with a regenerated catalyst and a newly supplemented catalyst in a fluidized state in a fluidized bed reactor at a certain air speed, an isomerization reaction is performed under certain pressure, reaction gas and a carbon deposit catalyst are obtained through separation in a settler, wherein reaction gas rises and enters a product separation system via a reaction liquid pipeline at the top of the settler, the carbon deposit catalyst enters a regenerator for regeneration, and the regenerated catalyst returns to a lifting pipe reactor via a regenerated catalyst pipeline. The process has the characteristics of high atom economy, product yield and selectivity and no pollution and is notably superior to a current slurry bed process.
Owner:WANHUA CHEM GRP CO LTD

Continuous synthesis method and device of amion-2,2,6,6-tetramentylniperidine

PendingCN110317162ASmall footprintSmall footprint, safety hazardOrganic chemistryDistillationHydrogenation reaction
The invention relates to a continuous synthesis method of amion-2,2,6,6-tetramentylniperidine. The method includes the following steps that triacetylamine is used as a raw material, a catalyst is added, and ammonia gas is introduced for reaction at a first channel 2 of a microchannel for 5-300 seconds at the temperature of 50-150 DEG C and the pressure of 0.3-3 Mpa; hydrogen is introduced at a second channel 2 of the microchannel, the hydrogenation temperature is 50-150 DEG C, and hydrogenation lasts for 10-300 seconds at the pressure of 0.3-3 Mpa. After gas-liquid separation, the obtained reaction liquid enters a distillation tower for distillation to obtain the finished product. According to the technical scheme, a microchannel reactor is used for hydrogenation, the shortcomings of the prior art is overcome and a safer and more convenient production way is provided.
Owner:宿迁联盛科技股份有限公司

Continuous process for producing a tenside in a tube reactor

The invention relates to a continuous method for producing a tenside, containing a compound of the formula (1), wherein R2 is a fatty acid alkyl residue and R1 is a linear or branched C1 to C12 hydrocarbon residue, and x is in the range from 1 to 15 by conversion of fatty acid alkyl esters or fatty acid triglycerides having an N-n-alkylized polyhydroxy compound in the presence of an alkali catalyst or a catalyst selected from hydroxides or alcoholates of the 2nd and 4th secondary group of the periodic system at a temperature in the range from 40 to 300 DEG C.
Owner:CLARIANT INT LTD

Method of granulation with a fluidized bed granulator

A granulator, having a granulation unit having a bottom floor with a perforated plate as its bottom part; an upper air-supplying pipe for supplying a fluidizing air to the bottom floor of the granulation unit; a lower air-supplying pipe; air-spouting pipes, each of which is branched from the lower air-supplying pipe, and has an opening in the bottom floor of the perforated plate, for jetting the air into the granulation unit; and spray nozzles for spraying a granulation raw material liquid, which each are provided in the center of an air outlet of the air-spouting pipe, or a granulator, having: the bottom floor; the air-supplying pipe; and spray nozzles for spraying a granulation raw material liquid each of which are provided in an opening in the bottom floor of the perforated plate, and use a high-pressure atomizing air as an auxiliary gas, wherein, in each granulator, the spray nozzles are provided in a triangular arrangement.
Owner:TOYO ENG CORP

Catalytic rectifying column plate allowing online replacement of catalyst

The invention discloses a catalytic rectifying column plate allowing online replacement of a catalyst. The catalytic rectifying column plate comprises a column tray, a plurality of gas-liquid contactelements and suspended downcomers arranged on the column tray, a suspended receiver tray arranged below the suspended downcomers, and a catalyst handling hole for handling a catalyst on the column tray. A free space formed by the suspended downcomers, the gas-liquid contact elements, the column tray and a column wall is a catalyst filling area; the catalyst is loosely packed in the catalyst filling area; each suspended downcomer comprises an inner downcomer passed through the column tray and an outer guide hood that covers the part, above the bottom of the column tray, of the inner downcomer.The catalytic rectifying column plate has no need for complex packaging of a catalyst; the catalyst is directly loosely packed on the column tray; the catalyst can be replaced online with no need forstopping equipment; the catalyst is distributed evenly; pressure drop of the column tray is low; rectifying efficiency is high. In addition, expensive catalyst packaging material and filling materialare omitted, and the cost can be significantly reduced.
Owner:WANHUA CHEM GRP CO LTD

A reaction device for producing light olefins from methanol and/or dimethyl ether

The invention relates to a reaction device for preparing low-carbon olefin by employing methyl alcohol and / or dimethyl ether, in particular to a reaction device for preparing low-carbon olefin by employing methyl alcohol and / or dimethyl ether. The reaction device mainly comprises a dense-phase fluidized bed reactor (2), a cyclone separator (3), a stripper (5), a lift pipe (7), a dense-phase fluidized bed regenerator (10), a cyclone separator (11), a stripper (13) and a lift pipe (15), wherein the dense-phase fluidized bed reactor (2) is partitioned into n (n is greater than or equal to 2) secondary reaction zones by material flow controllers (17); and the dense-phase fluidized bed regenerator (10) is partitioned into m (m is greater than or equal to 2) secondary regeneration zones by the material flow controllers (17). By virtue of the reaction device, the problems in the prior art that carbon deposit distribution of a catalyst is uneven and low-carbon olefin selectivity is relatively low are solved.
Owner:中科催化新技术(大连)股份有限公司

A method for producing low-carbon olefins from oxygen-containing compounds and equipment used therefor

The invention relates to a method for preparing light olefins from oxygen-containing compounds and equipment used therefor. More specifically, the present invention provides a method for producing low-carbon olefins from oxygen-containing compounds, using methanol and / or dimethyl ether as the main raw materials, using multi-stage (n≥2) dense-phase fluidized bed reactors and multi-stage ( m≥2) The catalyst regenerator solves the problems in the prior art that it is difficult to control the carbon deposition amount and uniformity of carbon content of the catalyst and the low selectivity of low-carbon olefins.
Owner:中科催化新技术(大连)股份有限公司

Micro-chemical preparation method of nano-iron phosphate and nano-iron phosphate

ActiveCN103259017BNarrow distributionParticle size distribution high speedMaterial nanotechnologyCell electrodesIron saltsPhosphate
The invention discloses a nano iron phosphate micro chemical preparation method and nano iron phosphate. The method comprises the following steps of: S1, respectively dissolving soluble iron salt and phosphate into deionized water according to a ratio that Fe: P=1:(0.8-1.2), wherein the concentrations of solutions are both 0.1-1mol / L, and the final volume parts of an iron salt solution and a phosphate solution are the same; S2, weighing and dissolving a surfactant which can theoretically generate 1wt.%-10wt.% of iron phosphate into the iron salt solution; S3, dropwise adding ammonia water into the phosphate solution, and regulating the pH to be 8-10; S4, regulating the rotation speed of a mechanical pump to be 10-300 rounds / minute, simultaneously adding the same flow of the iron salt solution and the phosphate solution into a microreactor of a micro chemical system to react for 10-60 minutes, and thus obtaining a turbid liquid; and S5, filtering and separating the turbid liquid, washing and drying at 70-90 DEG C so as to obtain spherical nano iron phosphate. The method can be used for preparing the nano iron phosphate with regular shape, good dispersibility, uniform size distribution and high reactivity.
Owner:深圳市毓丰新材料有限公司

Applications of micro-channel reactor in zaltoprofen cyclization reaction, and zaltoprofen cyclization method

The invention belongs to the technical field of pharmaceutical synthesis, and specifically discloses a zaltoprofen cyclization method and applications of a micro-channel reactor in a zaltoprofen cyclization process. According to the present invention, cyclization is performed in a micro-channel reactor, and the uniformly stirred material is heated to a temperature of 60-70 DEG C before the material enters the micro-channel reactor, wherein the reaction temperature is 60-90 DEG C, the flow rate is controlled at 5-10 ml / min, the pressure drop is 6 bar, the material passing time is 5-10 s, and amass ratio of a zaltoprofen intermediate II 5-(2-propionyloxy)-2-phenylthiophenylacetic acid to polyphosphoric acid to phosphoric acid is 1:3-4:0.5. According to the present invention, by using the micro-channel reactor, the cyclization yield can be substantially increased, the reaction time can be shortened, the product quality can be stabilized, the post-treatment difficulty can be substantiallyreduced, and the pollution degree can be substantially improved.
Owner:河南后羿制药有限公司

Gun propellant mixing and extruding device

InactiveCN102950662AProcess adjustmentQuality improvementGear wheelReduction drive
The invention discloses a gun propellant mixing and extruding device, which comprises a motor, a conic reducer, a main reducing gear, a connecting device, a feeding machine barrel, a sealing machine barrel, a gas exhauster barrel and an explosion venting machine barrel, wherein the motor is connected with the conic reducer through a coupler and a wall penetration shaft; the conic reducer is connected with the main reducing gear through the coupler; the main reducing gear is connected with a connecting device; the connecting device is connected with the feeding machine barrel; the feeding machine barrel is connected with the sealing machine barrel; the sealing machine barrel is connected with the gas exhauster barrel; the gas exhauster barrel is connected with the explosion venting machine barrel; and the sealing machine barrel is internally provided with a co-rotating twin screw. With the adoption of the gun propellant mixing and extruding device, the intermittent mixing of a gun propellant extruder is changed into the continuous mixing, and the gun propellant extruder is in enclosed environment when in processing, thus greatly improving the production efficiency and the quality of products; and the gun propellant mixing and extruding device is good in self-cleaning property, so that residence time distribution range of materials in the gun propellant mixing and extruding device is narrower, and the mixing is uniform.
Owner:恒力石化股份有限公司

Preparation method of N, N-dimethyl-1, 3-propane diamine

The invention provides a preparation method of N, N-dimethyl-1, 3-propane diamine, which comprises the following steps: mixing acrylonitrile and a dimethylamine solution, injecting the mixture into a micro-channel reaction device for addition reaction, mixing the reaction liquid with hydrogen, preheating the mixture, feeding the preheated mixture into a continuous hydrogenation reactor filled with a Ni-based alloy hydrogenation catalyst, carrying out hydrogenation reaction and carrying out vacuum rectification separating to obtain the required product. According to the preparation method disclosed by the invention, the microchannel reactor has the advantages of continuity, high mass and heat transfer efficiency, narrow residence time distribution, no amplification effect and the like, so that the addition reaction of acrylonitrile and dimethylamine has the characteristics of high efficiency, high conversion rate and few byproducts; and the hydrogenation reaction is carried out under extremely mild reaction conditions by using the novel Ni-based alloy catalyst, and meanwhile, very high conversion rate and product selectivity are obtained, so that the whole reaction system has the advantages of continuous production, convenience in operation, high resource utilization rate and the like.
Owner:CHINA TIANCHEN ENG

Method and catalyst for carrying out selective nitro reduction hydrogenation reaction by using micro-packed bed

The invention discloses a method for carrying out selective nitro reduction hydrogenation reaction by using a micro-packed bed and a catalyst. Comprising the following steps: (1) mixing a reaction substrate with a reaction solvent to prepare a raw material solution; (2) introducing the raw material liquid and hydrogen into a microreactor for reaction, wherein a reaction tube of the microreactor is filled with a modified catalyst; the modified catalyst comprises a catalyst active component, a catalyst auxiliary agent and a catalyst carrier; the catalyst active component is selected from one or more of Pd, Ru and Pt; the catalyst auxiliary agent is selected from one or more of Fe, Cu, Ni and Co; the catalyst carrier is activated carbon; and (3) carrying out gas-liquid separation and purification on a gas-liquid mixture obtained after the reaction is finished to obtain a reaction product. Through the combination of the micropacked bed and the modified catalyst, nitro reduction is realized with high selectivity, the selectivity can reach 99%, and the generation of by-products is effectively reduced.
Owner:PHARMABLOCK SCIENCES (NANJING) INC

Method for preparing α-hydroxyketone photoinitiator in a microreactor

The invention relates to a method for preparing an α-hydroxy ketone photoinitiator in a microreactor. Isobutyrylbenzene is used as a raw material, and chlorine gas is introduced into it to obtain an intermediate chloroisobutyryl chloride, and the effect of the intermediate in an aqueous sodium hydroxide solution The α-hydroxy ketone photoinitiator is obtained by alkaline hydrolysis. The preparation method of the α-hydroxy ketone photoinitiator provided by the invention has high operational safety and high selectivity, small reaction volume, short reaction time, less corrosion to equipment, low energy consumption, green environmental protection, and is Process method suitable for industrial production.
Owner:TIANJIN JIURI NEW MATERIALS CO LTD
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