The invention relates to an ultra-low-hydrogen, moisture-absorption-resistant electric welding electrode whose welding core is a seamless flux-cored wire and a preparation method thereof, belonging to the field of welding materials. The electric welding electrode includes a welding core and a coating; the welding core includes a skin and a coating Core; the components and content of the drug core are: nickel 20‑26%, chromium 3‑5%, molybdenum+tungsten 1‑1.5%, graphite 0.5‑1%, potassium carbonate 2‑4%, potassium titanate 1‑ 3%, the rest is reduced iron powder; the components and contents in the coating are: marble 25‑33%, barium carbonate 10‑16%, fluorite 25‑30%, sodium fluoride 3‑5%, magnesium fluoride 1‑4%, phlogopite 2‑4%, quartz 4‑7%, titanium iron 5‑8%, rare earth ferrosilicon 3‑6%, manganese 2‑4%, CMC 1‑2%. The welding electrode has stable arc, clear molten pool, easy slag removal, extremely low diffusible hydrogen, good moisture absorption resistance and good low-temperature toughness, and can meet the welding requirements of 690MPa grade steel.