The invention discloses a high-toughened chloroethylene grafted
copolymer and a preparation method thereof, and belongs to the field of
high polymer materials. The high-toughened chloroethylene grafted
copolymer is characterized in that the graft copolymerization process is divided into two stages for preparing the chloroethylene grafted
copolymer, wherein the first stage is to prepare
acrylate rubber latex which adopts a core-shell structure and is rich in unsaturated
double bond active
grafting sites on the surface; the second stage is to carry out graft copolymerization to 1-10% of the
acrylate rubber latex and 90-99% of chloroethylene in
mass fraction; the
acrylate monomer is copolymerized with the crosslinking monomers containing two or more non-conjugated double bonds to prepare the crosslinked
polymer latex as a core, and then the crosslinking monomers are polymerized on the surface of the core to form a shell, so as to prepare the acrylate rubber latex, the average grain
diameter of which is 0.080-0.500 microns. The copolymer resin prepared by the preparation method disclosed by the invention is excellent in
shock strength and processability; the extra
impact modifier is not required to be used.