The invention discloses a thermally stable lead-free high-temperature piezoelectric
ceramic and a preparation method thereof, which is characterized in that the thermally stable lead-free high-temperature piezoelectric
ceramic consists of components expressed by the following general formulas: (Naa Kb Lic Agd Bie) (Nbu Tay) O3 +xM1 +yM2, M1 is
titanate of the following metals: Mg, Ca, Ba and Sr; M2 is the
carbonate or
oxide of the following metals: Na, K, Li, A1, Cu, Fe, Mn, Zn, Pr, Nd, Sm, Gd, La, Dy, Er, Yb, Sc and Sb; x and y are the percentages for which the weights of M1 and M2 account in the overall weight of raw materials. The lead-free high-temperature piezoelectric
ceramic of the invention is a lead-free, environmentally coordinative, high-temperature piezoelectric ceramic with low agglomerating temperature, high
curie temperature, stable thermal performance of
electricity, and high
mechanical strength, and has stable preparation technique and can be obtained by adopting the preparation technique and industrial materials for traditional piezoelectric ceramics, so the invention is practical.