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75results about How to "Change adsorption" patented technology

Method for preparing catalyst for treating high-concentration organic wastewater through catalytic oxidation

The invention discloses a method for preparing a catalyst for treating high-concentration organic wastewater through catalytic oxidation, which comprises the following steps: 1) drying a cocoanut active charcoal at a temperature of between 100 and 120 DEG C for 8 to 15 hours, taking out and adding the cocoanut active charcoal into 2 to 10 percent sulfuric acid solution to perform soakage for 12 to 36 hours, adding the cocoanut active charcoal into a 1 to 10 percent oxydol solution to perform soakage for 12 to 36 hours, taking the cocoanut active charcoal out, and draying the cocoanut active charcoal in shade to obtain an activated charcoal for standby; and 2) soaking constant volume of the activated charcoal into transition metal salt solution for 12 to 36 hours, drying the activated charcoal at a temperature of between 100 and 120 DEG C for 8 to 15 hours, and calcining the activated charcoal at a temperature of between 300 and 650 DEG C for 3 to 8 hours to obtain the catalyst for treating the high-concentration organic wastewater through the catalytic oxidation. The service life of an active charcoal catalyst bed prepared by the method can reach over 0.5 to 1 year. After the treatment of the wastewater, compared with a Fenton reagent, the treatment efficiency of the catalyst is improved obviously, and the treatment cost is reduced by about 20 percent.
Owner:ENVIRONMENTAL SCI RES & DESIGN INST OF ZHEJIANG PROVINCE

Preparation method and adsorption method of Ni<2+> adsorbent

The invention discloses a preparation method and an adsorption method of a Ni<2+> adsorbent. The method comprises the following steps: (1) with tetraethoxysilane as a silicon source and triblock copolymer (P123, EO20PO70EO20) as a template agent, synthesizing a silica-based mesoporous material SBA-15, and modifying the inner surface of the silica-based mesoporous material SBA-15 with 3-aminopropyl triethoxy silane (APTES) through an alkyl coupling method to obtain an amino functionalized silica-based mesoporous material NH2-SBA-15; (2) grafting amino acid onto NH2-SBA-15 by a post-transplantation method to obtain the amino acid modified silica-based mesoporous material, namely, the adsorbent; (3) regulating the pH value of the adsorbent to 3-5 by virtue of a water solution containing Ni<2+>, and feeding the adsorbent to adsorb Ni<2+> in a water body, wherein the mass ratio of the adsorbent to Ni<2+> in the water body is 5:1 to 8:1, the adsorption temperature is 20-30 DEG.C, and the adsorption time is 10-30 minutes. The adsorbent preparation method is high in operability and good in reproducibility, the obtained amino acid modified silica-based mesoporous material has a good removal effect for heavy metal ions, Ni<2+>, in a water body, the equilibrium adsorption capacity of the adsorbent reaches up to 60mg.g<-1> above, and thus the actual application value of the adsorbent is good.
Owner:常熟紫金知识产权服务有限公司

Method for preparing adsorbent by using bottom mud of Dian Lake and application thereof

InactiveCN104437374AChange surface electrical propertiesChange adsorptionOther chemical processesWater contaminantsSorbentCarbonization
The invention discloses a method for preparing adsorbent by using bottom mud of Dian Lake and application thereof, and belongs to the technical field of preparation of heavy metal adsorbents. The method comprises the following steps: soaking the bottom mud by distilled water, repeatedly washing and drying the bottom mud, adding a glutaraldehyde solution into the bottom mud to serve as an activator, adding the bottom mud into a polydimethyl diallylammonium chloride solution, putting in a water bath to carry out heating reflux, pouring the supernate and carrying out acidizing by hydrochloric acid, filtering and washing to neutral and drying to obtain initial samples, putting the samples in an electric furnace and carrying out high-temperature carbonization by taking vapor as protection gas, obtaining carbonized samples after cooling, repeatedly washing the samples to remove the impurities in the carbonized products until washing to neutral (pH>6.5), carrying out drying, grinding after cooling, and screening to obtain the samples according with adsorption. The method is simple in operation conditions, extremely high in adsorbent productivity; through combining the physical activation method and the chemical activation method, the activation effect is relatively good, the performance of the adsorbent is improved and the adsorption value of manganese is greater than 19mg / g.
Owner:KUNMING UNIV OF SCI & TECH

Novel sulfonation melamino-formaldehyde resin and preparation method thereof

The invention relates to the technical field of resin materials, in particular to a novel sulfonated melamine-formaldehyde resin and a preparation method thereof. The raw materials of the sulfonated melamine-formaldehyde resin include modified melamine, formaldehyde, sodium metabisulfite, sulfuric acid, saturated calcium hydroxide, sodium hydroxide and water. Melamine can be replaced by modified melamine. When melamine is modified with lauryl alcohol Jinxin, its molecular weight can be increased, its production cost can be reduced, and thus it can be mass-produced.
Owner:SHENZHEN AIYIRUI TECH CO LTD

Sulfur-containing non-noble metal salt doped hollow nanometer metal organic framework material, and preparation method and application thereof

The invention discloses a sulfur-containing non-noble metal salt doped hollow nanometer metal organic framework material, and a preparation method and an application thereof. The preparation method comprises the following preparation steps: 1) preparation of a metal organic framework material precursor; 2) preparation of a sulfur-containing non-noble metal salt solution; 3) doping of a sulfur-containing non-noble metal salt solution; and 4) pyrolysis preparation of the sulfur-containing non-noble metal salt doped hollow nanometer metal organic framework material. According to the invention, the process flow is simple; the reaction process is easy to be controlled; a template does not need to be introduced in the preparation process; and by introduction of sulfur-containing non-noble metalsalt doping as an excellent cocatalyst, the sulfur-containing non-noble metal salt is highly dispersed in micropores of an original single-crystal metal organic framework structure, and original metalconnecting elements are replaced in the pyrolysis process, so the electronic state and the adsorption property of the surfaces of noble metal particles are changed, and the purpose of improving the catalytic performance is achieved.
Owner:XI AN JIAOTONG UNIV

Cerium-tin-zirconium composite oxide catalyst, and preparation method and use thereof

The invention relates to a cerium-tin-zirconium composite oxide catalyst, a preparation method and an application thereof. The catalyst has the following chemical composition: CeSn a Zr 2 o x , a ranges from 0 to 2.0 and does not include 0. The addition of Sn promotes the synergy between Sn, Ce, and Zr, changes the adsorption performance of the catalyst to the reactants, and makes the redox process of the catalyst easier to complete, thereby increasing the NO x removal efficiency. The CeSn a Zr 2 o x The catalyst activity is significantly improved, and the temperature window is also significantly widened. The cerium-tin-zirconium composite oxide catalyst has excellent NH 3 - SCR activity.
Owner:RES CENT FOR ECO ENVIRONMENTAL SCI THE CHINESE ACAD OF SCI

Method for preparing titanium dioxide catalyst with selectively deposited platinoid alloy granule

The invention belongs to the technical field of materials and environments, and discloses a method for preparing a titanium dioxide catalyst with selectively deposited platinoid alloy granules. The method comprises the following steps: by adopting HF (Hydrofluoric Acid) as an end-capping reagent, preparing {101} and {001} double-crystal surface exposed titanium dioxide crystal powder by using a solvent thermal method; putting the titanium dioxide crystal powder into a 0-10mol / L sodium hydroxide solution, stirring for 0-5 hours, and performing centrifugal separation and water washing drying on solid substances in the solution so as to obtain light blue powder; dispersing the light blue powder, copper nitrate and chloroplatinic acid powder in deionized water so as to obtain a mixed liquid, stirring the mixed liquid for 12 hours at a temperature of 80 DEG C, and performing evaporation drying till black powder is prepared; calcining the black powder in an air environment, and calcining in hydrogen flow, so as to obtain the titanium dioxide catalyst with the selectively deposited platinoid alloy granules.
Owner:HUAZHONG UNIV OF SCI & TECH

Oil-water separation system with efficient electromagnetic synchronous cooperation

The invention relates to an oil-water separation system with efficient electromagnetic synchronous cooperation, comprising a reinforced coalescing device and a precipitating separating device and characterized in that a drain pipe liquid distributor is arranged at the inner bottom of the precipitating separating device, the reinforced coalescing device is provided with an electromagnetic coalescing component, a liquid-distributing orifice plate is arranged between an inlet head and the electromagnetic coalescing device, the electromagnetic coalescing component includes an electric field generating component and a magnetic field exciting component which are in coaxial distribution; an electric field and a magnetic field are orthogonally distributed to arrive at synchronous cooperation. Theelectric field generating component includes a grounding external electrode and an axial electrode coated with an insulating sleeve, allowing electric field intensity to be increased to 350 kV/m; themagnetic field exciting component includes outer and inner coils coaxially and hermetically sleeving the external electrode, the outer coil is greater than the inner coil in the number of turns, and the outer coil and the inner coil are contained in a self-circulating cooling sleeve. The oil-water separation system has the advantages that oil-water separation efficiency is significantly improved,oil-water separation range is significantly widened, the system is capable of treating oil-water emulsions having a water content of up to 40%, and therefore, the system is widely applicable to efficient and stable equipment and facilities for oil-water separation on land and sea.
Owner:CHINA UNIV OF PETROLEUM (EAST CHINA)

Clamping tool with magnetism and monitoring device adopting clamping tool

ActiveCN105728189AAvoid enteringThe size of the adsorption force is adjustableMagnetic separationMetal impuritiesMechanical engineering
The invention relates to a mechanical part installed on a liquid passing pipeline, in particular to a clamping tool with the magnetism and a monitoring device adopting the clamping tool. The clamping tool comprises a clamping part matched with a pipeline, the clamping part is provided with at least one sliding groove, and magnetic devices used for attracting metal impurities in the pipeline are arranged in the sliding grooves and can slide along the sliding grooves. When the clamping part clamps the pipeline, the magnetic devices on the clamping part can attract the metal impurities in the pipeline, therefore, the metal impurities are accumulated at the position, corresponding to the clamping range of the clamping part, of the pipeline, it is guaranteed that liquid passing through the clamping range of the clamping part does not contain the metal impurities any more, the metal impurities are prevented from entering the monitoring device which utilizes the magnetic principle and is arranged on the pipeline, and therefore accurate working of the monitoring device is guaranteed.
Owner:CHINA PETROLEUM & CHEM CORP +1

Self-permeating type soil heavy metal repair agent and preparation method thereof

The invention discloses a self-permeating type soil heavy metal repair agent and a preparation method thereof, and belongs to the technical field of repair agent preparation. According to the self-permeating type soil heavy metal repair agent and the preparation method thereof, organic matter is mixed with a base material of organic acid, the promoting property of the repair agent on growth and development of plants is effectively improved, physical properties of repaired soil are improved, activities of microorganisms and soil organisms are promoted, nutrient elements in the soil are promotedto be decomposed, and meanwhile, air permeability, permeability and adsorbability of the soil are changed; by addition of mineral improvers such as zeolite, peat, charcoal, weathered coal and the like, on one hand, reaction performance such as adsorption, ion exchange and the like of heavy metal elements is improved, heavy metal pollutants such as cadmium, chromium, lead and the like in soil canbe cured and passivated, bio-availability of the heavy metal pollutants and mobility in soil are reduced, risks that the pollutants are absorbed by crops and transferred to food chains are reduced, and on the other hand, physical and chemical properties of the soil are improved.
Owner:杨涛

Device and method for transforming physical characteristics of coal seam through downhole heat injection

The invention provides a device and method for transforming physical characteristics of a coal seam through downhole heat injection, and relates to coal mining technologies. According to the device and method for transforming the physical characteristics of the coal seam through downhole heat injection, the technical problem that rock burst or outburst of coal and gas easily occurs during coal roadway tunneling is solved. According to the device and method for transforming the physical characteristics of the coal seam through downhole heat injection, a coal seam heating system is composed of acoal mine neutral water purifier-softener, a high pressure water pump, an electric heater, a heat injection pipeline and a heat injection drilling hole; water is injected into the electric heater through the high pressure water pump after being processed through the purifying-softener, the water is heated by the electric heater in the high-pressure state, and the generated superheated water is injected into the coal seam along a hole sealing pipe of the heat injection pipeline and the heat injection drilling hole; after water enters the coal seam, part of water is converted into water vapor along with reduction of pressure, and the superheated water and the water vapor is subjected to seepage along cracks of the coal seam and heat the coal seam; and the water after heat is released flowsinto a pumping and mining drilling hole and is discharged from the coal seam. After the coal seam is heated for a period of time, the physical characteristics such as adsorption, the strength and thespontaneous combustion point of coal can be changed in a short time, and rock burst or outburst of coal and gas during coal roadway tunneling is effectively prevented.
Owner:TAIYUAN UNIV OF TECH

ni 2+ Preparation of Adsorbent and Its Adsorption Method

The invention discloses the preparation and adsorption method of Ni2+ adsorbent, which comprises the following steps: (1) using tetraethyl orthosilicate as silicon source and three-block copolymer (P123, EO20PO70EO20) as template to synthesize silicon-based media Pore ​​material SBA-15, and then modified 3-aminopropyltriethoxysilane (APTES) to the inner surface of silicon-based mesoporous material SBA-15 by alkyl coupling method to obtain amino-functionalized silicon-based mesoporous Material NH2‑SBA‑15; (2) Amino acids were grafted onto NH2‑SBA‑15 by the post-grafting method to obtain silicon-based mesoporous materials modified by amino acids, that is, adsorbents; (3) Ni2+-containing aqueous solution, adjusted When the pH value reaches 3~5, put in the adsorbent to absorb Ni2+ in the water body, the mass ratio of the adsorbent to the Ni2+ in the water body is 5:1~8:1, the adsorption temperature is 20~30°C, and the adsorption time is 10~30 min. The preparation method of the adsorbent of the present invention has strong operability and good reproducibility, and the obtained amino acid-modified silicon-based mesoporous material has a good removal effect on heavy metal ions Ni2+ in water, and the equilibrium adsorption capacity reaches 60 mg·g-1 Above, the practical application value is good.
Owner:常熟紫金知识产权服务有限公司

Preparation method of beef proteins with high adsorption property to flavor components

The invention discloses a preparation method of beef proteins with high adsorption property to flavor components. The method comprises the following steps: (1) removing impurities from fresh beef, dicing and mincing; (2) degreasing beef samples to obtain crude beef proteins; (3) performing pulse microwave treatment on the extracted crude beef proteins, wherein the output power of the pulse microwaves is 20-500W, the microwave output duty ratio is 5-60%, the pulse width is 10-100ms, the frequency is 2400-2500MHz, the phase is 0-180 degrees, and the pulse microwave treatment time is 5-100seconds; and (4) performing vacuum freeze drying, grinding into powder, and screening, thereby obtaining the beef proteins with high adsorption property to flavor components. According to the beef proteins prepared by the method disclosed by the invention, the adsorption capacity of flavoring compounds can be wholly improved by 20-50%.
Owner:SOUTH CHINA UNIV OF TECH

Modified lanthanide-series-metal organic framework material and preparation method thereof

InactiveCN106040179AChange the adsorption processImprove hydrogen storage capacity at room temperatureHydrogenOther chemical processesMetal-organic frameworkLanthanide
The invention provides a modified lanthanide-series-metal organic framework material and a preparation method thereof. The modified lanthanide-series-metal organic framework material comprises a lanthanide-series-metal organic framework material and a palladium catalyst, wherein the palladium catalyst accounts for 0.1-1% of the total mass of the raw materials when being counted by palladium. The modified lanthanide-series-metal organic framework material has the advantages that the palladium is introduced into the metal organic framework of the modified lanthanide-series-metal organic framework material, the absorption process of hydrogen in the framework is changed, and room-temperature hydrogen storage quantity is increased.
Owner:MATERIAL INST OF CHINA ACADEMY OF ENG PHYSICS
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