The invention discloses a method for preparing a visible light self-repairing waterborne
polyurethane coating material with double
selenium bonds on a main chain. The method comprises the following steps: firstly, preparing an
isocyanate end capped
polyurethane prepolymer with double
selenium bonds on a main chain from raw materials of diisocyanate, dihydroxyethyl
diselenide,
macromolecule dihydric
alcohol and
dimethylolpropionic acid; secondly, adding
triethylamine for
neutralization, further adding a proper amount of deionized water for rapid emulsification, slowly adding a
diamine chain
extender which is diluted with water, and performing emulsification chain expansion under a condition that the rotation speed is greater than 1200r / min, thereby obtaining the visible light self-repairing waterborne
polyurethane coating material with the double
selenium bonds on the main chain. On the basis of the visible light reversibility characteristic of double-selenium dynamic covalent bonds, the waterborne
polyurethane coating material with the double selenium bonds on the main chain is capable of achieving self-repairing of cracks and broken parts under
radiation of gentle visible illumination, so that the service life of the material can be greatly prolonged, the potential safety
hazard in use can be reduced, and a relatively long service life can be achieved for the waterborne
polyurethane coating material. The waterborne
polyurethane coating material with double selenium bonds on the main chain is applicable to
coating of leather, textiles, paper, furniture, wall surfaces and the like, and has wide application prospects.