4131results about "Contaminated groundwater/leachate treatment" patented technology

The present invention is directed to various sets of unit operations for treating aqueous effluents and logic for designing and effecting the treatment. The unit operations include stabilization of subterranean waters, sequential oxidation steps to alter selected target materials, oxidation to break up emulsions prior to removal of the emulsion components, and intense oxidation to break up difficult-to-remove organic target materials.

Methods and systems for a subsurface upflow wetland for wastewater treatment that includes a series of parallel treatment cells, each cell including from bottom to top, a layer of gravel, a layer of sand over the gravel to remove pathogens from a septic effluent, a pollution control medium above the sand layer to remove nutrients, total suspended solid, and biochemical oxygen demand and a growth media mixture layered on top of the pollution control media to grow plants, and a gravity distribution system to distribute effluent to the series of parallel treatment cells. The pollution control medium includes at least one recycled material and at least one naturally occurring material. In an embodiment it includes recycled tire crumb, sand and limestone or recycled tire crumb, compost, sand and limestone.

A method and apparatus creates gas-enriched fluid that is used to treat wastewater. In one embodiment, the wastewater is withdrawn from a supply of wastewater to be treated, and the wastewater is delivered in an atomized manner to a vessel pressurized with gas to form gas-enriched wastewater. The gas-enriched wastewater is then delivered to the supply of wastewater to be treated.

A two-step chemical precipitation process involving hydroxide precipitation and sulfide precipitation combined with “field separation ” technology such as magnetic separation, dissolved air flotation, vortex separation, or expanded plastics flotation, effectively removes chelated and non-chelated heavy metal precipitates and other fine particles from water. In the first-step, the non-chelated heavy metals are precipitated as hydroxides and removed from the water by a conventional liquid / solids separator such as an inclined plate clarifier to remove a large percentage of the dissolved heavy metals. The cleaned water is then treated in a second precipitation step to remove the residual heavy metals to meet discharge limits. In the second precipitation step, any metal precipitant more effective than hydroxide for metal precipitation can be used. The invention improves metal removal, lowers cost because fewer chemicals are used, produces less sludge, and reduces the discharge of toxic metals and metal precipitants to the environment. Magnetic separation is preferred for the separation of particles precipitated in the second stage. Similar methods can be employed for separation of other particulates from water. Particulates can also be removed by causing them to adhere to particles of expanded plastic, forming a floc lighter than water, so that the floc can be removed by flotation.

The present disclosure provides for a system and method that intensely oxidizes water as it navigates through a system and accurately, controllably neutralizes the oxidation by-products before the water exits the system.

Subsea wells are drilled and completed with an offshore floating platform in a manner that allows simultaneous work on more than one well. A first well is drilled and cased. Then a tubing hanger is run through a drilling riser and landed in the wellhead housing. Then, with the same floating platform, the drilling riser is disconnected and moved to a second well. While performing operations on the second well, the operator lowers a production tree from the floating platform on a lift line, and connects it to the first wellhead housing. An ROV assisted subsea plug removal tool is used for plug removal and setting operations. Seabed separation is configured upstream of a production choke valve.

A two-step chemical precipitation process involving hydroxide precipitation and sulfide precipitation combined with “field separation ” technology such as magnetic separation, dissolved air flotation, vortex separation, or expanded plastics flotation, effectively removes chelated and non-chelated heavy metal precipitates and other fine particles from water. In the first-step, the non-chelated heavy metals are precipitated as hydroxides and removed from the water by a conventional liquid / solids separator such as an inclined plate clarifier to remove a large percentage of the dissolved heavy metals. The cleaned water is then treated in a second precipitation step to remove the residual heavy metals to meet discharge limits. In the second precipitation step, any metal precipitant more effective than hydroxide for metal precipitation can be used. The invention improves metal removal, lowers cost because fewer chemicals are used, produces less sludge, and reduces the discharge of toxic metals and metal precipitants to the environment. Magnetic separation is preferred for the separation of particles precipitated in the second stage. Similar methods can be employed for separation of other particulates from water. Particulates can also be removed by causing them to adhere to particles of expanded plastic, forming a floc lighter than water, so that the floc can be removed by flotation.

A two-step chemical precipitation process involving hydroxide precipitation and sulfide precipitation combined with “field separation” technology such as magnetic separation, dissolved air flotation, vortex separation or expanded plastics flotation, effectively removes chelated and non-chelated heavy metal precipitates and other fine particles from water. In the first-step, the non-chelated heavy metals are precipitated as hydroxides and removed from the water by a conventional liquid / solids separator such as an inclined plate clarifier to remove a large percentage of the dissolved heavy metals. The cleaned water is then treated in a second precipitation step to remove the residual heavy metals to meet discharge limits. In the second precipitation step, any metal precipitant more effective than hydroxide for metal precipitation can be used. The invention improves metal removal, lowers cost because fewer chemicals are used, produces less sludge, and reduces the discharge of toxic metals and metal precipitants to the environment.

A subsea wellhead assembly has a tubing hanger with a tubing annulus passage and a production passage. A metal-sealing shuttle valve is mounted in the tubing hanger for blocking upward flow through the tubing annulus passage. The shuttle valve has a retention mechanism that prevents the shuttle from moving to the open position when fluid pressure is applied from above. The retention mechanism is released by the running tool after testing has been completed, causing the shuttle to close. The tree has an engaging member that can be stroked downward into the tubing hanger annulus passage to move the shuttle valve to the open position for communicating with the annulus.

Devices and methods of use of a non-traditionally powered environmental remediation device and, more particularly, to devices utilizing programmable logic controllers for remote operation, monitoring and data collection.

Systems and methods for generating reactive oxygen species formulations useful in various oxidation applications. Exemplary formulations include singlet oxygen or superoxide and can also contain hydroxyl radicals or hydroperoxy radicals, among others. Formulations can contain other reactive species, including other radicals. Exemplary formulations containing peracids are activated to generate singlet oxygen. Exemplary formulations include those containing a mixture of superoxide and hydrogen peroxide. Exemplary formulations include those in which one or more components of the formulation are generated electrochemically. Formulations of the invention containing reactive oxygen species can be further activated to generate reactive oxygen species using activation chosen from a Fenton or Fenton-like catalyst, ultrasound, ultraviolet radiation or thermal activation. Exemplary applications of the formulations of the invention among others include: cleaning in place applications, water treatment, soil decontamination and flushing of well casings and water distribution pipes.

A system for treating wastewater having a treatment bed of particulate material, inflow distributing plumbing for applying wastewater from a wastewater supply source to upper part of the treatment bed. The wastewater percolates downwardly through the particulate material and is collected by outflow plumbing and conveyed out of the treatment bed. Preferably, the particulate material in the treatment bed is suitable for supporting aquatic plant life.

A method of processing landfill leachate by use of a membrane separation process is disclosed. Specifically, the following steps are taken to process landfill leachate: collecting landfill leachate in a receptacle suitable to hold said landfill leachate; treating said landfill leachate with one or more water soluble polymers, wherein said water soluble polymers are selected from the group consisting of: amphoteric polymers; cationic polymers; zwitterionic polymers; and a combination thereof; optionally mixing said water soluble polymers with said landfill leachate; passing said treated landfill leachate through a membrane, wherein said membrane is an ultrafiltration membrane or a microfiltration membrane; and optionally back-flushing said membrane to remove solids from the membrane surface.

There is disclosed a method and apparatus for treating produced water from a heavy oil thermal recovery unit to achieve water recovery and recycle levels of greater than 80% and as high as 100% to achieve zero discharge criteria. The method includes the initial steps of capturing the waste heat energy from the high pressure steam separator located downstream of the steam generators. Further, transferring the heat energy into a heated separator and reboiler exchanger to distill oil reservoir produced water and recover distilled water and a concentrated brine or solid product. The heated separator concentrated stream is circulated through the reboiler exchanger to maintain from 1% to about 50% mass vapour in the stream returning to the heated separator and prevent fouling and scaling. The apparatus includes a low pressure waste energy separator, heated separator and vapour compressor in combination with a forced circulation circuit to generate the distilled water.

The present invention provides a process for removing arsenic from ground water to be processed and used in remote dwellings. The process includes (a) contacting a clay, a coagulant, and an oxidizer with water containing arsenic to form a coagulated colloidal mixture; (b) adsorbing the arsenic onto the coagulated colloidal mixture; and (c) separating the water from the coagulated colloidal mixture. The invention also provides a composition ready for use in removing arsenic from ground water to be used in remote areas. The composition includes an activated clay, a coagulant, and an oxidizer in predetermined proportions for efficient removal of arsenic from ground water.

Apparatus for active in situ multi-element gas sparging for bioremediation or physico-chemical degration for removal of contaminants in a soil formation containing a subsurface groundwater aquifer or a substantially wet unsaturated zone, the multi-gas contained in bubbles, wherein the apparatus includes a plurality of injection wells extending to a depth of a selected aquifer; introducing an oxidizing agent comprising ozone mixed with ambient air to provide a multi-element gas by means of microporous diffusers, without applying a vacuum for extraction of stripped products or biodegration by-products, wherein said diffusers form micro-fine bubbles containing said multi-element gas that oxidizes, by stripping and decomposition, chlorinated hydrocarbons from the aquifer and surrounding saturated soil formation into harmless by-products; also including a pump for agitating water in the well selecting microbubbles, injecting them into the aquifer and effective to alter the path of micro-fine bubbles through a porous solid formation whereby enhanced contact between the oxidizing agent contained in each said bubble by stripping pollutant from solution in ambient water into the mini-atmosphere of each bubble effective to increase the efficiency and speed of remediation of a site.

The present invention utilizes fungal spore mass or hyphal fragments in burlap bags or sacks filled with biodegradable materials. The fungi may include saprophytic fungi, including gourmet and medicinal mushrooms, mycorrhizal fungi, entomopathogenic fungi, parasitic fungi and fungi imperfecti. The fungi function as keystone species, delivering benefits to both the microsphere and biosphere. Such fungal delivery systems are useful for purposes including ecological rehabilitation and restoration, preservation and improvement of habitats, bioremediation of toxic wastes and polluted sites, filtration of agricultural, mine and urban runoff, improvement of agricultural yields and control of biological organisms.

The invention belongs to the technical field of polluted ground water remediation, and particularly relates to a method and a system by using micro-namo bubbles to perform reinforcement in-situ remediation on polluted ground water. The method comprises the steps of: arranging a water injection well at the upper reaches of a region with ground water polluted by pollutants, and feeding micro-nano bubble water containing nutrient salts; leading the micro-nano bubble water to flow to the polluted region with the ground water, so as to decompose the pollutants or continuously compensate electron acceptors or electron donors for microorganisms and facilitate degradation and removal of organic pollutants; at the same time, arranging a water pumping well to pump water at lower reaches of the polluted region, so as to form a subsurface flow field; and using a monitoring well to monitor and analyze parameters in real time during the process of removing the organic pollutants, and adjusting the generating time and the aeration intensity of the micro-nano bubbles. According to the invention, the micro-nano bubbles are good in oxygen supply effect, long in lasting time and wide in influencing range, the method and the system provided by the invention can make up the shortages of common in-situ remediation technologies such as natural degradation, bioventing and the like and are low in cost and high in energy-saving efficiency, thereby being applicable in remediation for a field with a limit area and a high pollution load.

The invention relates to an in-situ thermal desorption repair system and a method for polluted soil. The system comprises a plurality of in-situ heating electrodes, a plurality of injection wells, a plurality of extraction wells, a plurality of groundwater monitoring wells, electrode power control and adjustment facilities, in-situ temperature and pressure monitoring facilities, sewage treatment facilities and waste gas treatment facilities; each extraction well is provided with an extraction device which is connected with a sewage treatment facility and a waste gas treatment facility; each injection well is internally provided with an injection device which is connected with a material storage box containing a leaching reagent; and the in-situ heating electrodes are arranged in a regulartriangular or regular hexagonal manner. Compared with the prior art, after the leaching reagent is added to dissolve pollutants, the solubility of the pollutants is increased, the speed of the pollutants entering a liquid phase from a soil adsorption phase is increased, and the removal rate and removal efficiency of the pollutants are improved.

A photoelectrocatalytic oxidizing device having a photoanode being constructed from a conducting metal such as Ti as the support electrode. Alternatively, the photoanode is a composite electrode comprising a conducting metal such as Ti as the support electrode coated with a thin film of sintered nanoporous TiO2. The device is useful in methods for treating an aqueous solution such as groundwater, wastewater, drinking water, ballast water, aquarium water, and aquaculture water to reduce amounts of a contaminant. The method being directed at reducing the amount and concentration of contaminants in an aqueous solution comprising providing an aqueous solution comprising at least one contaminant, and, photoelectrocatalytically oxidizing the contaminant, wherein the contaminant is oxidized by a free radical produced by a photoanode constructed from an anatase polymorph of Ti, a rutile polymorph of Ti, or a nanoporous film of TiO2.

An activated carbon material for removing a contaminant from a liquid. The activated carbon material can be a plurality carbon grains that have a pore volume of approximately 0.1 milliliters per gram (mL / g) in the range of less than about 15 angstroms in width. The carbon grains can also have or contain a nitrogen-containing species having a concentration of more than 2 atomic percent nitrogen. A plurality of the carbon grains can be used to make a contactor that is operable to remove or reduce perchlorate having a concentration of 20 parts per billion (ppb) to less than 4 ppb from 4,500 bed volumes of water with the nitrogen-containing species leaching off of the carbon grains less than 0.1 mg / L. The activated carbon material can also be electrochemically regenerated.

A zero-valent metal emulsion containing zero-valent metal particles is used to remediate contaminated natural resources, such as groundwater and soil. In a preferred embodiment, the zero-valent metal emulsion removes heavy metals, such as lead (Pb), from contaminated natural resources. In another preferred embodiment, the zero-valent metal emulsion is a bimetallic emulsion containing zero-valent metal particles doped with a catalytic metal to remediate halogenated aromatic compounds, such as polychlorinated biphenyls (PCBs), from natural resources.

A liquid treatment device comprising: two antennae; an enclosure for holding a liquid including a solvent and a solute; a generator operatively connected to the two antennae to generate an oscillating voltage in each antenna, wherein each voltage is out of phase with the other to create an oscillating electric-field; and the liquid in the enclosure being subjected to the electric-field in the presence of a magnetic field to change the chemical and / or physical properties of the solute, without the liquid contacting the two antennae.

The present invention is directed to an adsorbent for removing arsenic species from ground water and / or surface water systems. Such adsorbent removes both As(III) and As(V), thereby providing potable water. Also provided is a method and / or device (e.g., filter) for removing arsenic species from contaminated waters utilizing such adsorbent.

A method and system for treatment of flow-back and produced water from a hydrocarbon well in which fracturing operations are carried out using a phase separation and creating of positive charge in the water.

The invention discloses an environment-friendly domestic garbage disposal device. The environment-friendly domestic garbage disposal device comprises a bottom plate. Supporting rods are arranged at the four corners of the upper side of the bottom plate. A box body is arranged on the upper sides of the supporting rods. A charging inlet is formed in the left end of the upper side of the box body. A pair of crushing shafts are arranged under the charging inlet. Crushing blades are arranged on the crushing shafts. An inclined filter screen is arranged below the crushing blades. A liquid storage cavity is formed below the inclined filter screen. A discharging outlet is formed in the right side of the inclined filter screen. An extrusion cavity is formed in the right side of the discharging outlet. A supporting plate is arranged at the inner lower end of the extrusion cavity. An extrusion plate is arranged on the upper side of the supporting plate. Connecting rods are arranged on the upper side of the extrusion plate. A connecting plate is arranged on the upper sides of the connecting rods. Lead screws are arranged at the left end and the right end of the connecting plate. Second motors are arranged on the upper sides of the lead screws. An exhaust port is formed in the upper side of the extrusion cavity. An air purifier is arranged on the upper side of the exhaust port. An exhaust pipe is arranged on the right side of the air purifier. Domestic garbage can be effectively crushed, subjected to solid-liquid separation and compressed, and thus disposal of domestic garbage is effectively facilitated.

The invention discloses a method for preparing a charcoal nanometer zero-valent iron compound with a one-step method. The method comprises the following steps of after adsorbing water-soluble iron salt with biomass, performing heating pyrolysis by virtue of microwaves under the anaerobic condition; and reducing iron ions into zero-valent iron by taking pyrolysis gas in the pyrolysis process as a reducing agent, adsorbing zero-valent iron ultrafine particles in situ by taking charcoal produced in the pyrolysis process as a porous adsorption carrier, and synthesizing the charcoal nanometer zero-valent iron compound with the one-step method and low cost. Charcoal zero-valent iron provided by the invention has very strong adsorption performance and the ability of reducing and degrading organicchloride, bisphenol A and antibiotics, has obvious adsorption and passivation effects to heavy metals and can provide an effective repair material to removal or passivation of organic chloride residues, bisphenol A, the antibiotics and heavy metal residues which are difficultly degraded in water body and soil.

A water treatment system that utilizes magnetic seeding and magnetic separation to treat water. A magnetic collector is provided for collecting magnetic floc from the water being treated. A floc removal device in the form of a scraper is magnetically held adjacent to or in contact with the magnetic collector for scraping magnetic floc from the magnetic collector. Also disclosed is a disk type magnetic collector that includes a plurality of spaced apart magnetic disks supported on a shaft. A plurality of hook shaped floc removal devices are supported on the shaft with each hook shaped floc removal device being disposed between two magnetic disks or at least adjacent one magnetic disk. The hook type removal devices are spaced so as to engage an adjacent surface of a rotating magnetic disk. As the disk type magnetic collector is rotated, the hook type removal devices engage magnetic floc collected on the surfaces of the magnetic disks and scrape the magnetic floc from the disks.

This invention relates to a refuse landfill leachate wastewater treatment system comprising a collection well, an adjustment tank, a filter, a comprehensive treatment system having a multi-stage anoxic / aerobic pool and a membrane biological reactor. The process of treatment is: waste water enters a adjustment tanke in which water quality and quantity are adjusted; subsequently, enters a filter, the water discharged from the filter and enters a comprehensive treatment system having a multi-stage anoxic / aerobic pool and a membrane biological reactor, wherein waster water is bio-chemically treated to remove the organic substances, nitrogen and ammonia, and then the wastewater is discharged into a catalyzed oxidation tower; the organic substance in waste water is oxidized on effect of ozone and under the existing catalyst function and then the biochemical capacity thereof is enhanced; and then the catalyzed and oxidized waste water enters carbon filter pool, the remaining contaminated matter can be further removed by degradation of the anoxic oxidation of the biological membrane on the packing material in pool, then the output water meets the requirement of National Standard or other relevant industrial standards.