The invention relates to a method for treating the heavy-
nitrogen mother solution generated from production of dinitrodiazophenol, comprising the following steps of: collecting the heavy-
nitrogen mother solution into a primary acid-base regulation
pool, mixing, adjusting the pH value to 3, lifting onto an iron-carbon
bed, making the
effluent flow into a secondary acid-base regulation
pool, adjusting the pH value to 3-4, feeding into a Fenton-like reaction
pool for reaction, making the mother
solution flow into a
neutralization pool, adding
carbide slag to adjust the pH to 7-8, filing
nitrogen in the mother solution at the same time, making the mother
solution flow into a
flocculation and
sedimentation pool, feeding the supernatant obtained by
settling into a subsequent biological
treatment unit, treating until the supernatant reaches the standard, discharging or recycling, lifting the
sludge obtained by precipitating into a
sludge concentration pool, making the supernatant obtained by concentrating reflow into the primary acid-base regulation pool, feeding the concentrated
sludge into a horizontal
helical centrifuge for centrifugal dehydrating, mixing the dehydrated sludge into
steam coal for
combustion and utilization, and making a
centrifugal separation solution reflow into the primary acid-base regulation pool. The method provided by the invention has the advantages of low investment and stable effect, adopts the
carbide slag and waste the
scrap iron as the materials for treatment and achieves the purpose of treating the wastes by the wastes.