The invention especially relates to a surface-enhanced
Raman scattering substrate with pin holes in its surface and a preparation method, belonging to the technical field of detection of trace substances. According to the invention, a silver
nanorod array film is prepared by using an inclined growth process; and then a layer of an
alumina film with pin holes is uniformly deposited on the surface of the silver
nanorod array film by using low-temperature
atomic layer deposition technology, and an obtained sliver-
alumina composite
nanostructure with pin holes in its surface is used as the surface-enhanced
Raman scattering substrate. The method can adjust the parameters of the low-temperature
atomic layer deposition technology to control the proportion of the pin holes in the
alumina film; an ultrathin
oxide layer of the alumina film ensures good surface-enhanced
Raman scattering activity of the substrate; and interior
silver nanorods are isolated from the outside, so
chemical stability of the substrate is greatly improved. Moreover, the alumina film and silver surface
layers in the pin holes can both adsorb
specific detection molecules; and the substrate is applicable to detection of a plurality of chemical substances, expands the application scope of surface-enhanced Raman scattering and has wide application prospects.