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64 results about "Silver nanorods" patented technology

High-stability surface-enhanced Raman substrate and preparation method thereof

The invention discloses a high-stability surface-enhanced Raman substrate and a preparation method thereof and belongs to the technical field of detection on trace organic substances. The preparation method of the high-stability surface-enhanced Raman substrate comprises the following steps: preparing a silver nanorod array by an oblique growth method and then uniformly coating the surface of silver nanorods with an amorphous-state aluminum oxide film by a low-temperature atom layer deposition technology. Due to the adoption of relatively low deposition temperature in the substrate prepared by the method, the shape of the silver nanorods is unchanged; meanwhile, by virtue of the ultrathin aluminum oxide film, a surface-enhanced Raman effect is not greatly attenuated, so that the substrate has a good surface-enhanced Raman effect; the surface of the silver nanorods is uniformly coated with the aluminum oxide film, so that the silver nanorods are isolated from an outside environment, the oxidation resistance and the vulcanization resistance of the silver s are improved, and the stability of the surface-enhanced Raman effect of the silver nanorods is greatly improved; the high-stability surface-enhanced Raman substrate has wide application prospects in the aspects of trace and fast detection on organic substances.
Owner:TSINGHUA UNIV

Silver nanorod/ polymer/ silver nanosheet core-shell nanometer material and preparation method and application thereof

The invention discloses a silver nanorod / polymer / silver nanosheet core-shell nanometer material and a preparation method and application of the silver nanorod / polymer / silver nanosheet core-shell nanometer material. The silver nanorod / polymer / silver nanosheet core-shell nanometer material is characterized in that the core-shell nanometer material is composed of the three portions of a silver nanorod core, a polymer cladding layer and a silver nanosheet outer layer, the polymer cladding layer is polystyrene-polyacrylic acid segmented copolymer layer with the thickness being 10 nanometers; the length of the silver nanorod core is from 400 nanometers to 1.3 microns, and the silver nanosheet outer layer is irregular sheets with the edge length being 120-320 nanometers correspondingly; or the length of the silver nanorod core is 175-310 nanometers, and the silver nanosheet outer layer is in a bolt shape with the bottom edge length being 510-780 nanometers correspondingly and covers half of the silver nanorod core. The silver nanorod / polymer / silver nanosheet core-shell nanometer material is prepared through a seed inducement method. The silver nanorod / polymer / silver nanosheet core-shell nanometer material and the preparation method and application of the silver nanorod / polymer / silver nanosheet core-shell nanometer material have the advantages that SERS signal output quite high in intensity is generated, the preparation technology is simple, the preparation period is short, the yield is high, and popularization and mass production are easy.
Owner:东营睿港投资服务有限责任公司

Method of regulating and controlling lengths of silver nanorods in polyhydric alcohol reduction method through hydrogen peroxide

The invention provides a method of regulating and controlling lengths of silver nanorods in a polyhydric alcohol reduction method through hydrogen peroxide. The method comprises the following steps that silver nitrate and glycerol are blended and stirred and dissolved to obtain a solution A; sodium chloride, polyvinylpyrrolidone, the glycerol and the hydrogen peroxide are blended and stirred and reacted at the temperature which ranges from 160 DEG C to 200 DEG C for 15 minutes to 4 hours to obtain a solution B; the solution A is mixed in the solution B and reacted at the temperature which ranges from 160 DEG C to 200 DEG C for 15 minutes to 4 hours, a centrifugal separation of a reaction solution is conducted, a lower layer sediment is obtained and washed, and the silver nanorods with different lengths are obtained. The method is simple in technology, low in cost, the lengths of the silver nanorods can be changed only by adding the hydrogen peroxide, the lengths of the silver nanorods can be regulated and controlled according to the adding amount of the hydrogen peroxide, the diameter of the silver nanorods has no obvious changes while the lengths are changing, the uniqueness of regulation and control is guaranteed, and the method is incapable of introducing impurities and is suitable for large-scale industrial production.
Owner:山东利特纳米技术有限公司

Surface-enhanced Raman scattering substrate with pin holes in its surface and preparation method

ActiveCN105241862AGood surface enhances Raman activityGood chemical stabilityRaman scatteringSpecific detectionSurface layer
The invention especially relates to a surface-enhanced Raman scattering substrate with pin holes in its surface and a preparation method, belonging to the technical field of detection of trace substances. According to the invention, a silver nanorod array film is prepared by using an inclined growth process; and then a layer of an alumina film with pin holes is uniformly deposited on the surface of the silver nanorod array film by using low-temperature atomic layer deposition technology, and an obtained sliver-alumina composite nanostructure with pin holes in its surface is used as the surface-enhanced Raman scattering substrate. The method can adjust the parameters of the low-temperature atomic layer deposition technology to control the proportion of the pin holes in the alumina film; an ultrathin oxide layer of the alumina film ensures good surface-enhanced Raman scattering activity of the substrate; and interior silver nanorods are isolated from the outside, so chemical stability of the substrate is greatly improved. Moreover, the alumina film and silver surface layers in the pin holes can both adsorb specific detection molecules; and the substrate is applicable to detection of a plurality of chemical substances, expands the application scope of surface-enhanced Raman scattering and has wide application prospects.
Owner:广西三环高科拉曼芯片技术有限公司

Surface-enhanced Raman substrate and preparation method thereof

ActiveCN109136860AInhibit high temperature deformationHigh thermal stability temperatureVacuum evaporation coatingSputtering coatingElectromagnetic fieldThermal stability
The invention belongs to the technical field of detection of trace organics and discloses a surface-enhanced Raman substrate and a preparation method thereof. The preparation method employing obliquegrowth comprises: depositing an oxide layer at the top end of a silver nanorod array; depositing silver nano particles at the top end of the oxide layer to obtain silver nanorod-oxide-silver particlecomposite serving as the surface-enhanced Raman substrate. The surface-enhanced Raman substrate prepared via the preparation method gains improved thermal stability owing to high melting point of theoxide layer and protection for silver nanorods; the silver nanorods and the silver nano particles are isolated via the oxide layer which is ultra-thin, strong local electromagnetic field enhancement is provided at a gap, and therefore, sensitivity of the substrate herein is greatly improved. The substrate herein is applicable to detection at high temperatures, has great signal-enhancing capacity,provides a widened applicable range for surface enhanced Raman technology, and has great development potential.
Owner:UNIV OF SCI & TECH BEIJING

Display panel and display device

ActiveCN110752311AImprove transmittanceThe transmittance is greater than the transmittance increase in the second stateSolid-state devicesSemiconductor/solid-state device manufacturingImaging qualityDisplay device
The invention provides a display panel and a display device, wherein the display panel comprises: a first display area and a second display area; and a light emitting device located in the first display area; the light emitting device comprises a composite anode structure; in a direction perpendicular to the display panel and directed to a light emitting surface of the light emitting device, the composite anode structure comprises a first electrode layer, a function adjustment layer and a second electrode layer, which are sequentially stacked; and the function adjustment layer comprises a plurality of silver nanorods, the composite anode structure comprises a first state and a second state, and the transmittance of the composite anode structure in the first state is greater than the transmittance in the second state. The display panel is used for improving the imaging quality.
Owner:WUHAN TIANMA MICRO ELECTRONICS CO LTD

Control method for gold atom deposition on silver nanostructure

The invention discloses a control method for gold atom deposition on a silver nanostructure. The control method for gold atom deposition on the silver nanostructure comprises the following steps of S1, taking a gold nano bipyramid as a core, epitaxially growing silver to prepare a silver nanorod, and distributing a high surface energy surface and a tip position in an ectopic mode; S2, dispersing the silver nanorod serving as a reaction template into a hexadecyl trimethyl ammonium bromide solution, adding an ascorbic acid solution, and uniformly stirring; S3, adjusting the pH value of the mixed solution so as to adjust the reducibility of the ascorbic acid solution and to achieve the adjustment of the ratio between the replacement reaction and the co-reduction reaction in a reaction system; and S4, dropwise adding a gold precursor solution into the obtained reaction system, wherein the reaction system is converted into a co-reduction reaction system from a replacement reaction system, and the deposition position of reduced gold atoms is gradually migrated to the tip of the silver nanorod from the high surface energy face. According to the control method for gold atom deposition on the silver nanostructure, controllable deposition of the gold atoms can be achieved by adjusting the pH value of the reaction system, the conditions are simple and mild, and operability is high.
Owner:NANJING UNIV OF AERONAUTICS & ASTRONAUTICS

Surface-enhanced Raman scattering detection kit for detecting tumor micro nucleic acid markers as well as preparation method and application of surface-enhanced Raman scattering detection kit

The invention discloses a surface-enhanced Raman scattering detection kit for detecting small tumor nucleic acid markers for a non-disease diagnosis purpose as well as a preparation method and application of the surface-enhanced Raman scattering detection kit. The kit comprises an SERS detection chip, a first reagent and a second reagent. The SERS detection chip is a silver nanorod array substrate with the surface modified with a hairpin type DNA single chain H1, the first reagent is a hairpin type DNA single chain H2, the second reagent is an SERS probe, after the first reagent and the second reagent are added to the SERS detection chip at the same time, the single chain P of the probe on the second reagent is hybridized with the cohesive end of the H1-H2 double chain, and the SERS detection chip is a silver nanorod array substrate with the surface modified with the hairpin type DNA single chain H1. The SERS probe is captured on the SERS detection chip (the base sequence of the nucleic acid probe is adjustable), the detection of the small nucleic acid marker of the gastric cancer is realized by testing the Raman signal of the SERS probe on the SERS detection chip, the integrated detection of multiple nucleic acid biomarkers in complex environments such as serum and the like can be realized, and the detection specificity and accuracy are effectively improved.
Owner:NANJING UNIV OF POSTS & TELECOMM

Preparation method, product and application of zinc oxide modified gallium nitride silver-loaded nanorod heterojunction photocatalyst

The invention discloses a preparation method, product and application of a zinc oxide modified gallium nitride silver-loaded heterojunction photocatalyst. (GaN)1-x(ZnO)x solid solution gel is preparedby virtue of a sol-gel method, spin-coating of the (GaN)1-x(ZnO)x solid solution gel on the surface of a Si sheet growing on a crystal face (100) is carried out, treatment is conducted by virtue of ammonia gas to obtain a (GaN)1-x(ZnO)x solid solution nanorod, and then photodeposition Ag-loaded modification is conducted on the nanorod, and the Ag/(GaN)1-x(ZnO)x nanorod material is obtained. The catalyst is mainly characterized in that the structure of the catalyst is a silver-loaded heterojunction nanorod of zinc oxide modified gallium nitride; the specific one-dimensional nanorod heterojunction structure has a shorter longitudinal carrier migration path and an ultra-large specific surface area, electron hole separation and migration in the photocatalysis process are facilitated, and an optical excitation system can be utilized to the maximum extent. The catalyst product has the characteristics of being capable of effectively carrying out photocatalytic degradation on phenol and showing excellent photodegradation performance on phenol.
Owner:SHANGHAI NAT ENG RES CENT FORNANOTECH

Preparation and application of nanorod array with adjustable resonance wavelength

The invention belongs to the technical field of detection of trace organic pollutants, and particularly relates to preparation of a nanorod array with adjustable resonance wavelength and a method forquickly detecting trace hydrazine through utilization of the surface-enhanced Raman effect of a silver nanorod. A surface-enhanced Raman substrate comprises a substrate body, and metal silver is deposited on the substrate body, and forms the nanorod array with a forky top. By preparing an independent silver nanorod array thin film with the forky top, the substrate with an excellent surface-enhanced Raman effect is obtained, and then trace hydrazine is quickly detected through the utilization of the surface-enhanced Raman effect. The method is simple, quick, low in cost and high in sensitivity.
Owner:TSINGHUA UNIV
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