The invention relates to a preparation method for
ferric oxide coated
tin dioxide nanometer polycrystalline microballoons, and belongs to the technical field of preparation of
new energy materials of inorganic compounds. The
ferric oxide coated
tin dioxide nanometer polycrystalline microballoons are prepared by the hydrothermal method with
cane sugar,
urea,
tin tetrachloride and
ferric trichloride as raw materials. The method comprises the following steps: dissolving tin
tetrachloride in water, adding
cane sugar, carrying out stirring for 0.5 hour at
room temperature, putting the obtained solution into a hydro-thermal vessel with a volume of 45 ml, heating the solution to a temperature of 180 DEG C for a hydro-
thermal reaction for 24 hours, carrying out
centrifugal separation when the reaction is finished, and carrying out rinsing with considerable deionized water so as to obtain black
powder; dissolving ferric trichloride and
urea in a
mixed solution of
ethanol and water, adding the black
powder into the solution, carrying out stirring and ultrasonic treatment, putting the obtained liquid into the hydro-thermal vessel with a volume of 45 ml, and heating the liquid to a temperature of 60 DEG C for a hydro-
thermal reaction for 48 hours; carrying out
centrifugal separation when the reaction is finished, and carrying out rinsing with considerable deionized water and
sintering at a temperature of 500 DEG C in air for 4 hours so as to obtain
red ferric oxide coated
tin dioxide nanometer polycrystalline microballoons. The invention has the advantages of simple operation, cheap raw materials,
environmental protection, high yield, etc.