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35 results about "Polar crystal" patented technology

Polyvinylidene fluoride composite material and preparation method thereof

The present invention discloses a high beta crystal form content polyvinylidene fluoride composite material and a preparation method thereof. The composite material comprises ionic liquid modified carbon nanotubes and an organic material polyvinylidene fluoride, wherein a mass ratio of the polyvinylidene fluoride substrate to the modified carbon nanotubes is 100:0-12, and a mass ratio of the ionic liquid to the carbon nanotubes is 0-10:1. The preparation method comprises: carrying out coating modification on carbon nanotubes by using an ionic liquid, carrying out melt blending on the modified carbon nanotubes and polyvinylidene fluoride, and carrying out direct melt molding cooling to obtain the finished product. According to the present invention, polar crystal form content of PVDF in the prepared composite material can be 100%, the preparation process has characteristics of simpleness, energy source saving, and green environment protection, and the polyvinylidene fluoride composite material is expected to be provided for preparing various devices in fields such as piezoelectric materials, thermoelectric materials, dielectric materials and the like.
Owner:HANGZHOU NORMAL UNIVERSITY

Polar crystal-form polyvinylidene fluoride and preparation method of composite thereof

The invention discloses polar crystal-form polyvinylidene fluoride and a preparation method of a composite thereof. The preparation method includes: adding CTAB (cetyltrimethyl ammonium bromide) serving as nucleating agents so as to obtain high-content polar crystals, using 40%-99.9% of PVDF (polyvinylidene fluoride), 0.1%-10% of the cetyltrimethyl ammonium bromide and 0%-50% of packing as raw materials, uniformly mixing the raw materials by solution mixing or melting mixing, and forming so that the target composite is obtained. Highly-polar crystal-form PVDF material and the composite thereof are prepared by adding the CTAB playing a remarkable role in nucleation of polyvinylidene fluoride polar crystal forms. The composite can be formed by the aid of various methods (solution method and melting method) and various processing equipment (extruding, injection molding and mould pressing), and the preparation method is simple and convenient.
Owner:SICHUAN UNIV

Method for realizing high repetition frequency electro-optic Q-switching of solid laser based on periodic polar crystal

InactiveCN102593705ALow loading voltageLaser detailsResonant cavityFiltration
The invention relates to a method of electro-optic Q-switching of a solid laser, and in particular to a method for realizing high repetition frequency electro-optic Q-switching by using a periodic polar crystal as an electro-optic Q switch. The method at least comprises a pumping source, a coupling system and a resonant cavity which form the laser. The resonant cavity comprises a laser medium and an output mirror, wherein two isodirectional polaroids are arranged between the laser medium and the output mirror; and the periodic polar crystal is arranged between the two polaroids. The method is characterized in that voltage is loaded on the periodic polar crystal through a back-pressure type Q switch power supply so that the crystal axial direction of each electric domain just defects to the angle theta capable of realizing oscillation laser Saco filtration, then the polarization direction of the oscillation laser through the periodic polar crystal rotates by 90 degrees, failing to form oscillation through the second isodirectional polaroid; as a result, the energy-level particles on the laser medium are accumulated; when the on-load voltage loses transiently, the resonant cavity starts oscillation rapidly to form laser pulse and output. In the invention, the required on-load voltage is relatively low, therefore the operation of the high repetition frequency electro-optic Q-switching of the solid laser is easily achieved.
Owner:CHANGCHUN UNIV OF SCI & TECH

Battery coating film slurry, battery diaphragm, secondary battery and preparation method thereof

The invention provides a battery coating film slurry, a battery diaphragm and secondary battery and respective preparation methods thereof. The preparation of the battery coating film slurry comprisesthe steps: providing a polymerization unit including vinylidene fluoride and a fluorine-containing polymerization unit, providing a nucleating agent and adding the nucleating agent in the polymerization process of the polymerization unit so as to obtain a modified polymer; and preparing the battery coating film slurry based on the modified polymer. With application of the technical scheme, the battery coating film slurry is designed, the non-aqueous system is used, the diaphragm and the pole piece can be bonded together to improve the hardness of the battery, and the crystal form of the prepared polymer is transformed to the polar crystal form, the crystal structure is more perfect, the crystallinity is higher, the swelling ratio is low and the adhesion performance is superior; and the prepared battery has lower internal resistance and better cycling performance. The polymer is dispersed by using the aqueous system so that the shortage of the copolymer prepared by the oil-based systemcan be solved, the advantage of the aqueous polymer coating product can be exerted and the environmental protection effect can be further improved.
Owner:SHANGHAI ENERGY NEW MATERIALS TECH CO LTD

Fabrication of semi-polar crystal structures

A method of growing a group III nitride crystal structure comprises: providing a silicon substrate(12); forming a first mask (10) on the substrate, the mask having a plurality of apertures (14) through it each exposing a respective area of the silicon substrate; etching the silicon exposed by each of the apertures to form a respective recess(16)having a plurality of facets(18, 20, 22, 24); depositing a second mask over some of the facets of each recess leaving at least one of the facets(22)of each recess exposed; and growing group III nitride on the exposed facets(22) and then over the substrate to form a continuous layer.
Owner:SEREN PHOTONICS

Method of utilizing a built-in electric field in polar crystal to adjust and control separation efficiency and optic electrochemical activity of photon-generated carriers in photoelectrode of ZnO single crystal

The invention provides a method of utilizing a spontaneous polarization built-in electric field in a ZnO single crystal to adjust and control separation efficiency and optic electrochemical property of photon-generated carriers in a photoelectrode of the ZnO single crystal. Through adjusting direction of the polarization built-in electric field in the electrode of the ZnO single crystal, separation efficiency of photon-generated carriers in the electrode of the ZnO single crystal is controlled to regulate and control light current and photoelectric conversion efficiency. When the direction of the built-in electric field in the ZnO single crystal is perpendicular to the surface of the electrode and points to the outer surface (O-SC), light current, quantum conversion efficiency and separation efficiency of carriers in the electrode are effectively enhanced. The method is simple and effective to further improve the separation efficiency and activity of carriers of the photoelectrode of photoelectrochemistry and has potential application value.
Owner:SHANDONG UNIV

Polar crystal La3SbS4OCl2 and preparation method thereof

The invention discloses a polar crystal La3SbS4OCl2 and a preparation method thereof, and relates to the technical field of intraocular lens, the crystal is a sulfur-oxygen-chlorine mixed anion compound with a non-centrosymmetric structure, the crystal system is a hexagonal crystal system, the space group is P63mc, and the unit cell parameter unit cell volume is prepared in a way that under the protection of inert gas according to the stoichiometric ratio of La3SbS4OCl2, elemental lanthanum, lanthanum trichloride, elemental antimony, antimony trioxide and elemental sulfur are mixed and then put into a quartz tube, vacuumized, heated to 920-980 DEG C, a solid-phase chemical reaction is performed, and cooling is performed, thereby obtaining the product. According to the invention, the anti-laser-damage functional element is utilized to regulate and control the SbS3 triangular pyramid structure units of the polar functional element to realize equidirectional arrangement, so that the spontaneous polarization intensity is increased, the non-centrosymmetric structure is assembled on the molecular level, and the polar crystal La3SbS4OCl2 is successfully synthesized. The polar crystal has strong spontaneous polarization intensity and high laser damage threshold.
Owner:HUANGSHAN UNIV

Battery coating film slurry, battery separator, secondary battery and preparation method thereof

The invention provides a battery coating film slurry, a battery separator, a secondary battery and their respective preparation methods. The preparation of the battery coating film slurry includes: providing a polymer unit, the polymer unit comprising vinylidene fluoride and a fluorine-containing polymer unit , providing a nucleating agent, adding the nucleating agent during the polymerization of the polymerization unit to obtain a modified polymer; and preparing the battery coating film slurry based on the modified polymer. Through the above technical solution, the present invention designs the battery coating film slurry, and adopts a non-aqueous system, which can not only bond the diaphragm and the pole piece together, improve the hardness of the battery, but also the crystal form of the polymer prepared Polar crystal transformation, more complete crystal structure and higher crystallinity, smaller swelling ratio, better bonding performance; the manufactured battery has smaller internal resistance and better cycle performance. The water-based system is used to disperse the polymer, which solves the shortcomings of the oil-based system for preparing copolymers, gives full play to the advantages of water-based polymer coating products, and further improves the environmental protection effect.
Owner:SHANGHAI ENERGY NEW MATERIALS TECH CO LTD
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