Patents
Literature
Hiro is an intelligent assistant for R&D personnel, combined with Patent DNA, to facilitate innovative research.
Hiro

47results about How to "Strong red light emission" patented technology

Red phosphor and preparation method thereof

The invention discloses a red phosphor and a preparation method thereof, the red phosphor has the chemical formula: M6Ln2-xEuxR2(PO4)6F2, wherein M is at least one of the alkaline earth metal ion group consisting of Ca2+, Sr2+ and Ba2+; Ln is rare earth metal ion selected from the group consisting of La3+, Gd3+ and Y3+; R is the alkaline earth metal ion selected from the group consisting of Na+ and K+; x is the coefficient of mole percent of doping element Eu in rare earth element Ln and is not less than 0.01 but not more than 0.90. Rare earth oxide, ammonium dihydrogen phosphate, alkaline (earth) metal carbonate and ammonium fluoride are mixed and then sintered in the atmosphere of CO at 950 DEG C or 1050 DEG C for 2 to 4 hours, and the product is obtained by grinding the sintered mixture. The resultant luminescent material can effectively absorb 147nm and 172nm vacuum ultraviolet lights, generate green emission with main emission peak at 618nm, and the emission intensity excited at 172nm is stronger than PDP red phosphor (Y, Gd) BO3:Eu3+(YGB). The resultant phosphor has the main emission at 618nm, which is better than chromaticity coordinate emitted at YGB 593nm. The resultant phosphor has high luminous intensity, high color purity and good chromaticity coordinate, and is suitable for serving as red light portion of the luminescent material for PDP and mercury-free fluorescent lamp.
Owner:SUN YAT SEN UNIV

High-color-purity red luminescent material for blue light excitation and preparation method of red luminescent material

The invention relates to the field of white light emitting diode, and discloses a preparation method of a high-color-purity red luminescent material for blue light excitation. The high-color-purity red luminescent material for blue light excitation comprises the following chemical constitutions: M<II>Ge(1-x)F6:xMn<4+>, wherein M<II> is selected from one or more of alkaline earth metal ions Ba<2+>, Sr<2+>, Ca<2+> and Mg<2+>; x is a molar percentage coefficient of the correspondingly doped Mn<4+> to Ge<4+> ions; x is larger than or equal to 0 and smaller than or equal to 0.10. The high-color-purity red luminescent material for blue light excitation is prepared with a hydrothermal method. The red florescent powder can be excited by blue light to irradiate 634 nm of red light with the high luminous efficiency and the good color purity.
Owner:YUNNAN MINZU UNIV

Rare-earth red luminous material for plasma panel display and non-mercury fluorescent lamp and preparing process thereof

The present invention discloses a rear-earth red-light-emitting material used for plasma display panels (PDP) and mercury-free fluorescent lamps. The expression of the chemical composition of the rear-earth red-light-emitting material is as follows: M(RE1-xEux)(PO3)4; wherein, M is alkali metal ion which is selected from Li, Na, K, Rb and Cs; RE is rear earth element which is selected from La<3 plus>, Gd<3 plus>, Y<3 plus> and Lu<3 plus>; Eu<3 plus> is an active ion; and x is the molar percentage content of luminous active ions relative to RE atoms, and the value range is 0.01 equal to or less than x equal to or less than 1.0. The preparation method is simple, and the prepared rear-earth red-light-emitting material used for PDPs and mercury-free fluorescent lamps is activated by vacuum ultraviolet (VUV) light to emit strong red light at 590nm, which is stronger than the red light emitted by the red fluorescent powder (Y, Gd)BO3 : Eu<3 plus> used in the prior plasma display panels, approximately 110 percent of the red light.
Owner:SUN YAT SEN UNIV

Novel electrically neutral tridentate iridium [iii] complex red light material and preparation method

The invention relates to the synthesis technology of new luminescent materials, and is a new-type electrically neutral tridentate iridium [III] complex red light material and a preparation method thereof. It is a 6-[5-trifluoromethylpyrazole]-2,2'-bipyridine·2,6-diphenylpyridine iridium[III] complex. Under the protection of nitrogen, the trihydrate iridium trichloride [III] metal salt reagent and 6-[5-trifluoromethylpyridine]-2,2'-bipyridine tridentate chelate ligand were heated in ethanol, and the reaction The liquid was pumped dry for recrystallization, filtered, washed, and vacuum-dried to obtain an orange-yellow solid intermediate; in a nitrogen glove box, the orange-yellow intermediate, silver trifluoromethanesulfonate, and 2,6-diphenylpyridine ligand were uniformly mixed , ground into powder, heated, after the reaction solution was cooled to normal temperature, the filtrate was collected and dried to obtain the crude product, the crude product was separated, the second orange-red eluate was collected and dried, and vacuum-dried to obtain the final product, the yield was up to 30-68%.
Owner:JIANGXI UNIV OF SCI & TECH

Mn<4+> activated polyfluoride red luminous material and preparation method

The invention relates to the field of inorganic functional materials and discloses a Mn<4+> activated polyfluoride red luminous material capable of being effectively excited by blue light, and a preparation method of the material. A chemical composition of the Mn<4+> activated polyfluoride red luminescent material capable of being effectively excited by the blue light is Ba2M1-xF8:xMn<4+>, wherein M is Zr or Hf, x is a mole percentage coefficient of corresponding Mn<4+>-doped ions relative to M<4+> ions, and x is greater than 0 and less than or equal to 0.10. The red luminous material mainly emits red light of about 628nm under the excitation of the blue light, and is high in luminous efficiency. The preparation method of the blue light excited high-color-purity red oxyfluoride luminous material is a hydrothermal method, and a synthesis process is simple.
Owner:YUNNAN MINZU UNIV

Fluoride red fluorescent powder for blue-ray excited white-light LED and preparation method thereof

The invention provides fluoride red fluorescent powder for a blue-ray excited white-light LED and preparation and modification methods thereof. A general formula A2MF6: xMn<4+>, yBF is adopted to represent the material composition of the fluoride red fluorescent powder, wherein A and B independently represent Na or K respectively and are different, M is Ti or Si, x is equal to mMn / mM, x is greaterthan and or equal to 0 and smaller than or equal to 0.1, y is equal to mBF / mM, and y is greater than and or equal to 0 and smaller than or equal to 0.1. According to the preparation method of the fluoride red fluorescent powder for the blue-ray excited white-light LED, industrial and commercial raw materials are adopted, the process is simple, preparation is carried out at normal pressure and temperature, and therefore the preparation method of the fluoride red fluorescent powder for the blue-ray excited white-light LED is suitable for large-scale industrial production.
Owner:广西经正科技开发有限责任公司

Double perovskite-type molybdate red phosphor and preparation method thereof

ActiveCN109021973AStabilized double perovskite structureStable structureLuminescent compositionsLight emissionChemistry
The invention discloses a double perovskite-type molybdate red phosphor and a preparation method thereof. A chemical formula of the phosphor is: (Ba1-x, Eux) 2MgMoO6, wherein x is greater than or equal to 0.01 and less than or equal to 0.2; and the red phosphor is prepared by using EDTA and citric acid as complexing agents through a sol-gel method. The double perovskite phosphor provided by the invention uses molybdate as a matrix, and uses Ba<2+> and Mg<2+> to occupy a A position and a B position respectively, a stable double perovskite structure is formed, the relative content of Eu<3+> instead of Ba<2+> (x is greater than or equal to 0.01 and less than or equal to 0.2) is adjusted to increase the intensity of red light emission, not only strong red light emission can be obtained under the excitation of a LED near ultraviolet chip, but also high intensity can be obtained under the excitation of a LED blue chip, the pure-phase double perovskite powder can be obtained at lower temperature in a shorter time, the production cycle is short, and the cost is low.
Owner:XUZHOU NORMAL UNIVERSITY

Rare earth organic complex red luminescent material for 390-420 nm luminous semiconductor chip and preparation method thereof

the invention discloses a rare earth organic red luminous material and preparing method of 390-420 nm luminous semiconductor chip in the luminous material domain of semiconductor diode, which displays Eubeta3Lx, wherein the Eu is rare earth iron Eu3+; beta is first organic ligand beta-diketone; L is second organic ligand with 2 nitrogen atoms or one oxygen atom as ligand atom; the molar rate of subscript 3 and x in the corresponding composition is x=1 or x=2. The preparing method comprises two steps: first, synthesizing Eubeta3 .2H2O complex; second, synthesizing Eubeta3Lx complex.
Owner:SUN YAT SEN UNIV

Fluorescent powder capable of being effectively excited by blue light and preparation method thereof

The invention belongs to the technical field of rare earth luminescent materials, and in particular relates to fluorescent powder capable of being effectively excited by blue light and a preparation method thereof. The general formula of chemical compositions of the fluorescent powder is Li2Sr1-z(SiO4)1-0.75x-0.5y(M1O4)x(M2O4)y:zEu2+, wherein M1 refers to P; M2 refers to S; x is more than or equal to 0 and less than or equal to 0.2; y is more than or equal to 0 and less than or equal to 0.3; and z is more than or equal to 0 and less than or equal to 0.01. The preparation method comprises the following steps of: correctly weighing raw materials in a stoichiometric ratio of the general formula, uniformly mixing the raw materials fully, and pre-sintering the raw materials into a high temperate furnace at the temperature of between 400 and 800 DEG C for 1 to 12 hours; and sintering the pre-sintered raw materials in the reducing atmosphere at the temperature of between 700 and 1,000 DEG C for 1 to 10 hours. The fluorescent powder can be effectively excited by the blue light between 400 and 550nm, intense fluorescence-emission of which the main peak is about 580 to 610nm is obtained, and the fluorescent powder can be matched with a blue LED chip and is used for assembling white LEDs. Meanwhile, the fluorescent powder also can be excited by ultraviolet light between 250 and 280nm to emit intense red fluorescence. The fluorescent powder prepared by the invention has stable chemical properties, the preparation process is easily controlled, and the industrial production can be realized by utilizing basic equipment in the current fluorescent powder plants. Therefore, the fluorescent powder is new fluorescent powder with application potential.
Owner:瑞金市工业投资发展有限公司

Aluminum gallate-based fluorescent material and preparation method thereof

ActiveCN105778904AStrong green emissionGood green fluorescent materialLuminescent compositionsUltravioletGreen-light
The invention discloses an aluminum gallate-based fluorescent material. The aluminum gallate-based fluorescent material adopts a chemical formula of M1-xAlyGazO4:xRE, wherein M is at least one of Ca (calcium), Sr (strontium) and Mg (magnesium); RE is at least one of Eu3+ (europium), Sm3+ (samarium) and Tb3+ (terbium); x, y and z are atom molar ratios of the elements in material composition, x is greater than 0 and is smaller than 0.15, y is greater than or equal to 0.8 and is smaller than or equal to 1.2, and z is greater than or equal to 0.8 and is smaller than or equal to 1.2. When Eu3+, Sm3+ and Tb3+ are singly doped, the obtained red fluorescent material, orange fluorescent material and green fluorescent material can be respectively excited at high efficiency in the 300-500nm waveband, and can be well matched with ultraviolet, near-ultraviolet chips or blue light chips. The aluminum gallate-based fluorescent material has the advantages that by adopting the same matrix material, the broadband multi-color emitting in the 500-700nm waveband can be realized, the wavebands of blue-green light, green light, orange light and red light are covered, the problem of instable light color caused by different attenuation rates of multiple matrixes in the same LED (light emitting diode) device is solved, and the light color stability and color rendering property of the LED are improved.
Owner:HEFEI UNIV OF TECH

Coumarin-based red light aggregation-induced emission material and preparation method thereof

The invention discloses a coumarin-based red light aggregation-induced emission material and a preparation method thereof, and belongs to the technical field of organic chemistry and material chemistry. The structural formula of the luminescent material for solving the technical problem is shown in the specification and named CRTP. The synthesis of the CRTP comprises the following steps: firstly, mixing 4-(diethylamino)salicylaldehyde, ethyl acetoacetate and piperidine in absolute ethyl alcohol, conducting refluxing and heating to obtain a G-1 product, and then further catalyzing the compound G-1 and 4-(diphenylamine) benzaldehyde with equal amount of substance under the action of piperidine to obtain a final product. The red light aggregation-induced emission material CRTP is prepared from coumarin and triphenylamine. Raw materials are easily available, and synthesis is simple and feasible. When the CRTP is gathered in a poor solvent or a water phase, the CRTP can realize obvious red light emission, the aggregation-induced quenching phenomenon of a traditional organic fluorophore can be effectively avoided, and the CRTP is expected to be applied to high-sensitivity fluorescence detection in a solid luminescent material and a living body.
Owner:DALIAN UNIV

Uniform-appearance and high-color-purity Mn4+ activated red fluoride luminescent material prepared by using micro-emulsion method

The invention relates to the field of white light emitting diodes, and discloses a preparation method for a red fluoride luminescent material which is suitable for blue light excitation, high in color purity and is activated by Mn4+. The red fluoride luminescent material which is suitable for blue light excitation and high in color purity is prepared from a chemical composition of A2X1-xF6 :xMn4+, wherein A is one or any combination of two from Na, K, Rb, and Cs; M is one or two of Ti, Si, Ge and Zr; x is a coefficient of the molar percentage of corresponding doped Mn4+ ions relative to X4+ ions, and x is larger than 0 and smaller than or equal to 0.10. When the related red luminescent material is excitated by blue light, red light with the wavelength of 633 nm or 627 nm is mainly emitted, the luminous efficiency is high, and the color purity is high. The related red luminescent material which is excitated by blue light and high in color purity is prepared through a micro-emulsion method. The preparation method is simple in synthetic process, convenient to operate and suitable for large-scale industrialized production.
Owner:YUNNAN MINZU UNIV

Novel Mn<4+> activated high color purity fluoride red light emitting material preparation method

The invention relates to the field of white light emitting diodes, and discloses a preparation method of a novel Mn<4+> doped high color purity red fluoride light emitting material suitable for blue light excitation, wherein the chemical composition is K3Zr1-xF7:xMn<4+>, x is the mole percent coefficient of the corresponding doped Mn<4+> ions relative to Zr<4+> ions, and x is more than 0 and is less than or equal to 0.10. According to the present invention, the red light emitting material mainly emits 627 nm red light under blue light excitation, the light emitting efficiency is high, and the color purity is good; the novel Mn<4+> doped high color purity red fluoride light emitting material is prepared by using the ion-exchange method; and the synthesis process of the preparation method is simple, and the preparation method is suitable for industrial large-scale production.
Owner:YUNNAN MINZU UNIV

Preparation method of fluoride red phosphor used for blue-light semiconductor light emitting diode

The invention relates to the field of white light emitting diodes, and discloses fluoride red phosphor used for a blue-light semiconductor light emitting diode and a preparation method of the fluoride red phosphor. The chemical composition of the fluoride red phosphor used for the blue-light semiconductor light emitting diode is K<2>M<1-x>F<7:x>Mn4+, wherein M is Nb or Ta, and x is the mole percentage coefficient of correspondingly doped Mn4+ ions to M5+ ions, and is larger than zero and no larger than 0.10. The red phosphor related in the invention mainly emits red light with the wave length being about 628 nm when being excited by blue light, and the luminous efficiency is high. The high-color-purity red fluoride luminescent material excited by blue light is prepared through an ion exchange method at a room temperature. The preparation method is simple in synthesizing process and suitable for industrial mass production.
Owner:YUNNAN MINZU UNIV

Red light fluorescent powder capable of being used for blue light excitation of white light LED and preparation method of red light fluorescent powder

The invention belongs to the field of fluorescent powder preparation, and particularly relates to red fluorescent powder capable of being used for blue light excitation of a white light LED and a preparation method of the red fluorescent powder, and the general formula of the combination ratio of the prepared red fluorescent powder is K2MF6: xMn < 4 + > (at) GQDs (ymg / mol), wherein M is Si or Ti; x is the mole fraction of Mn < 4 + > doping, and x is more than 0 and less than or equal to 0.06; the GQDs are green light graphene quantum dots; y is the content of GQDs in the red-light fluorescent powder, 0 < y < = 7, and the unit is mg / mol. The Mn < 4 + >-doped fluoride red-light fluorescent powder coated with the green-light graphene quantum dots can be excited by blue light emitted by an InGaN chip, has excellent high-temperature fluorescence performance, heat resistance and water resistance, and has a good market prospect.
Owner:广西经正涂料有限公司 +1

Organic-inorganic hybrid fluorine titanium potassium red-light fluorescent powder and preparation method thereof

The invention belongs to the technical field of preparation of fluorescent powder, and particularly relates to organic-inorganic hybrid fluorine titanium potassium red-light fluorescent powder, the general formula of which is K2TiF6: xMn < 4 + >, ytetaH < + >, tetaH < + > represents that triethylene tetramine is subjected to organic-inorganic hybridization, and triethylene tetramine exists in a protonation form after hybridization; x is the mole fraction of Mn < 4 + > doping, y is the mole fraction of triethylene tetramine doping, x is larger than or equal to 0.01 and smaller than or equal to 0.12, and y is larger than or equal to 0.0 and smaller than or equal to 0.15. The invention also provides a preparation method of the organic-inorganic hybrid potassium titanium fluoride red-light fluorescent powder, which comprises the following steps: (1) reacting triethylene tetramine with an H2TiF6 solution and a K2CO3 solution, and drying to obtain K2TiF6: ytetaH < + >; and (2) reacting KF. 2H2O with an HF solution, a K2MnF6 solution and K2TiF6: ytetaH < + >, sealing, standing, carrying out suction filtration, washing and drying to obtain the K2TiF6: xMn < 4 + >, ytetaH < + >. The obtained red-light fluorescent powder has the advantages of high luminescence, high intensity, water resistance, thermal stability and the like.
Owner:广西经正涂料有限公司 +1

Platinum complex with aggregation-caused red light emitting function as well as preparation method and application of platinum complex

The invention belongs to the field of organic photoelectric functional materials, and particularly relates to a platinum complex with an aggregation-caused red light emitting function as well as a preparation method and an application of the platinum complex in organic electroluminescence and bioimaging fields. The platinum complex comprises a cyclometalated complex, a platinum center and an auxiliary ligand. The general structural formula is shown in the specification. The synthesis procedure of the platinum complex is simple, synthesis conditions are mild, the platinum complex seldom emits light in a solvent state but has a high red light emitting function in a solid state, and the platinum complex with the aggregation-caused red light emitting function can be applied to organic electroluminescence and biological imaging.
Owner:NANJING UNIV OF POSTS & TELECOMM

Up-conversion luminescent nano-material surface-modified with alkyne silver, and preparation method and application thereof

The invention provides a preparation method of an up-conversion luminescent nano-material surface-modified with alkyne silver. The preparation method comprises a step of preparing nano-particles withup-conversion luminescence performance and a step of modifying the surface with an alkyne silver compound. According to the step of preparing the nanoparticles with the up-conversion luminescence property, adopted raw materials comprise Y(NO3)3*6H2O, Yb(NO3)3*6H2O, Er(NO3)3*6H2O, sodium fluoride and polyacrylic acid. The step for modifying the surface with the alkyne silver compound comprises: YYEP is dispersed in a mixed solvent of methyl alcohol and water, a silver salt is added, stirring is performed to achieve complete dissolving, an organic alkyne compound is added, a light yellow turbidliquid is formed under a dark condition, suction filtration is carried out, then washing is conducted, and drying is conducted to obtain the surface-modified up-conversion luminescent nano-material. The detection on glutathione small molecules in the cells is realized.
Owner:UNIV OF JINAN

Method for preparing novel Mn (IV) ion activated red luminescence material

The invention relates to the field of white light emitting diodes, and discloses a method for preparing a novel Mn (IV) ion activated red luminescence material. The novel Mn (IV) ion activated red luminescence material disclosed by the invention has the chemical composition of AB4-xO9:xMn<4+>, wherein A refers to one or more of alkaline-earth metals ions such as Ba<2+>, Ca<2+> and Mg<2+>; B refers to one or more of alkaline-earth metals ions such as Ge<4+>, Ti<4+> and Zr<4+>; x refers to a molar percentage coefficient of correspondingly doped Mn<4+> relative to B<4+>; x is more than 0 and less than or equal to 0.10. The red luminescence material disclosed by the invention has the principle red emission of 667nm under blue light excitation and has high luminous efficiency. The novel Mn (IV) ion activated red luminescence material disclosed by the invention is prepared by a high temperature solid state method.
Owner:YUNNAN MINZU UNIV

Red-light fluorescent powder excited by blue light and synthesis method of red-light fluorescent powder

The invention belongs to the technical field of preparation of fluorescent powder, and particularly relates to red fluorescent powder excited by blue light, the general formula of which is Na2SiF6: xMn < 4 + >, yLi < + >-CA, wherein CA represents surface passivation with citric acid, x represents that x is greater than or equal to 0.01 and less than or equal to 0.14, and y represents that y is greater than or equal to 0.01 and less than or equal to 0.14. The invention also relates to a preparation method of the red-light fluorescent powder. The preparation method comprises the following steps: (1) preparing NaSiF6: yLi powder; (2) preparing Na2SiF6: xMn < 4 + >, yLi < + > red fluorescent powder crystals; and (3) preparing Na2SiF6: xMn < 4 + >, yLi < + >-CA red fluorescent powder crystals. The obtained red-light fluorescent powder has the characteristics of long-range good water resistance, high luminous intensity and thermal stability.
Owner:广西经正涂料有限公司 +1

Preparation method of red fluorescent powder for LED (light-emitting diode)

InactiveCN101845305AEasy to implementReduced chance of impuritiesLuminescent compositionsOxideEuropium
The invention relates to a preparation method of a red fluorescent powder for LED, which comprises the following steps: (1) dissolving a given amount of europium oxide in concentrated nitric acid; heating and stirring until the europium oxide is completely dissolved; continue heating for evaporation to dryness, and then adding deionized water to obtain a solution A; dissolving a given amount of sodium tungstate or ammonia tungstate in the deionized water to obtain a solution B; (2) dropwise adding the solution B to the solution A and continuously stirring to obtain a white turbid solution, and then adding a salpeter solution or a sodium hydroxide solution to the white turbid solution to regulate the pH value to 2-4; (3) filling the white turbid solution to a high pressure kettle, heating to 170-240 DEG C, preserving heat for 20-72 hours, and naturally cooling to the room temperature; and (4) filtering and drying obtained products to obtain the red fluorescent powder. The invention hassimple process, is easy to implement and can reduce the probability of introducing impurities; the preparation process of the preparation method requires simple equipment, has high reaction speed andis more suitable for large-scale production.
Owner:LIAOCHENG UNIV

A red-light enhanced up-conversion luminescence porous ZNO nanoparticle and preparation method thereof

The invention provides a red-light enhanced up-conversion luminescent porous ZnO nanoparticle and a preparation method thereof. A red-light-enhanced upconversion luminescent porous ZnO nanoparticle is a ZnO nanoparticle doped with Yb, Er, and Mn, including the following raw materials made, Zn 2+ Ionic solution, Yb 3+ Ionic solution, Er 3+ Ionic solution, Mn 2+ Ionic solution, CO 3 2‑ Ionic solution, where Zn 2+ : Yb 3+ :Er 3+ :Mn 2+ The molar ratio of Zn is 2+ : Yb 3+ :Er 3+ :Mn 2+ =100~60: 3~6: 0.3~0.6: 6~10. The ZnO nanoparticles are prepared by thermal decomposition and high-temperature calcination. The shape of the ZnO nanoparticles is regular spherical, small in size, porous, and the red light emission is enhanced.
Owner:ZHOUKOU NORMAL UNIV

A kind of preparation method of circular cake-shaped europium-doped lanthanum vanadate red fluorescent powder

The invention discloses a method for preparing a round cake-shaped europium-doped lanthanum vanadate red fluorescent powder. The method selects PVP as a template agent, uses lanthanum nitrate or lanthanum chloride as the lanthanum source, and uses europium nitrate or europium chloride as the lanthanum source. Europium source, using sodium metavanadate or ammonium metavanadate as vanadium source, using hydrothermal reaction method, by changing initial pH, hydrothermal reaction time and temperature, europium source content and PVP content, round cakes with different diameters can be obtained. The europium-doped lanthanum vanadate red phosphor has a diameter of 1~5.5μm and a thickness of 0.1~0.5μm. It has a tetragonal zircon phase structure and good red light emission properties. The method of the invention has simple raw materials and easy operation, the prepared product has high purity and regular particles, and the product particle morphology and phase structure are controllable, and has strong red light emission, and the obtained round cake-shaped europium-doped lanthanum vanadate is obtained Crystals have excellent application prospects in the fields of PDP, LED, photocatalysis and luminescent ceramics.
Owner:惠州市鑫正科技有限公司

Preparation method and application of benzoquinoline ratio-type near-infrared fluorescent molecular probe capable of being used for fluorine ion detection

The invention discloses a preparation method and application of a benzoquinoline ratio type near-infrared fluorescent molecular probe capable of being used for fluorine ion detection. The chemical structural formula of the benzoquinoline ratio type near-infrared fluorescent molecular probe is formula I shown in the specification. The ratio type fluorescent probe takes a 10-hydroxybenzo[H]quinoline derivative as a parent structure, and the detection of fluorine ions in a pure water system and a biological system is realized based on an ESIPT mechanism. The maximum emission wavelength of the probe molecule in a PBS buffer solution is 498 nm, after fluorine ions are added, the maximum emission wavelength of the probe is subjected to red shift to 637 nm and is in a near-infrared region, and the interference of biological autofluorescence can be effectively avoided. Meanwhile, the fluorescent molecular probe disclosed by the invention is good in water solubility, high in sensitivity and strong in specificity, and has a relatively strong practical application value in the fields of environment and life science.
Owner:HUNAN TARGETING DETECTION TECH CO LTD

Fluorescent powder capable of being effectively excited by blue light and preparation method thereof

The invention belongs to the technical field of rare earth luminescent materials, and in particular relates to fluorescent powder capable of being effectively excited by blue light and a preparation method thereof. The general formula of chemical compositions of the fluorescent powder is Li2Sr1-z(SiO4)1-0.75x-0.5y(M1O4)x(M2O4)y:zEu2+, wherein M1 refers to P; M2 refers to S; x is more than or equal to 0 and less than or equal to 0.2; y is more than or equal to 0 and less than or equal to 0.3; and z is more than or equal to 0 and less than or equal to 0.01. The preparation method comprises the following steps of: correctly weighing raw materials in a stoichiometric ratio of the general formula, uniformly mixing the raw materials fully, and pre-sintering the raw materials into a high temperate furnace at the temperature of between 400 and 800 DEG C for 1 to 12 hours; and sintering the pre-sintered raw materials in the reducing atmosphere at the temperature of between 700 and 1,000 DEG C for 1 to 10 hours. The fluorescent powder can be effectively excited by the blue light between 400 and 550nm, intense fluorescence-emission of which the main peak is about 580 to 610nm is obtained, and the fluorescent powder can be matched with a blue LED chip and is used for assembling white LEDs. Meanwhile, the fluorescent powder also can be excited by ultraviolet light between 250 and 280nm to emit intense red fluorescence. The fluorescent powder prepared by the invention has stable chemical properties, the preparation process is easily controlled, and the industrial production can be realized by utilizing basic equipment in the current fluorescent powder plants. Therefore, the fluorescent powder is new fluorescent powder with application potential.
Owner:瑞金市工业投资发展有限公司

Red fluorescent powder with high luminous intensity, thermal stability and water resistance and preparation method thereof

The invention belongs to the field of preparation of fluorescent powder, and particularly relates to red fluorescent powder with high luminous intensity, thermal stability and water resistance and a preparation method of the red fluorescent powder, and the general formula of the combination ratio of the prepared red fluorescent powder is K2MF6: xMn < 4 + >-SP, wherein SP represents surface passivation, and M is Ti or Si; x is Mn < 4 + > doped mole fraction, and x is more than 0 and less than or equal to 0.12. According to the preparation method, materials are taken from industrial and commercial raw materials, the process is simple, preparation is carried out under the conditions of normal temperature and normal pressure, the preparation method is suitable for large-scale and industrial production, the luminous intensity of the prepared red fluorescent powder is 1.1 times that of an unpassivated control sample, the thermal stability of the red fluorescent powder is shown as follows: the integral luminous intensity at 180 DEG C is 1.70 times or above of the initial value at 30 DEG C, and the red fluorescent powder is suitable for industrial production. After being soaked in water for 6 hours, the light yellow light appearance is kept all the time, and the residual emitted light intensity is up to 88% or above.
Owner:广西经正涂料有限公司 +1

a mn 4+ Activated polyfluoride red luminescent material and preparation method

The invention relates to the field of inorganic functional materials and discloses a Mn<4+> activated polyfluoride red luminous material capable of being effectively excited by blue light, and a preparation method of the material. A chemical composition of the Mn<4+> activated polyfluoride red luminescent material capable of being effectively excited by the blue light is Ba2M1-xF8:xMn<4+>, wherein M is Zr or Hf, x is a mole percentage coefficient of corresponding Mn<4+>-doped ions relative to M<4+> ions, and x is greater than 0 and less than or equal to 0.10. The red luminous material mainly emits red light of about 628nm under the excitation of the blue light, and is high in luminous efficiency. The preparation method of the blue light excited high-color-purity red oxyfluoride luminous material is a hydrothermal method, and a synthesis process is simple.
Owner:YUNNAN MINZU UNIV
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products