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51results about How to "Increase response current" patented technology

Static electricity spinning prepared fixed enzymic electrode and method thereof

This invention discloses one static fabric processed fixed enzyme electrode and its method, which belongs to fixed enzyme electrode technique, wherein, the said enzyme electrode is composed of electrode base, reacting layer composed of polymer nanometer fiber film and oxidation and deoxidizing enzyme or the reacting layer is composed of polymer nanometer fiber film and oxidation and deoxidizing enzyme and metal particles with 5 to 100 nanometer electric activity or the reacting layer is composed of polymer nanometer fiber film and film oxidation and deoxidizing enzyme and electro medium.
Owner:TIANJIN UNIV

Parathion-methyl electrochemical biosensor based on sulfonic functionalized grapheme-chitosan

A method adopted by an electrochemical biosensor based on sulfonic functionalized grapheme-chitosan to detect methyl parathion belongs to the technical field of electrochemical sensors and is used for detecting methyl parathion residual quantity in vegetables, fruits and products thereof. The basis of the invention is that methyl parathion can play an inhibition role on acetylcholinesterase, and the acetylcholinesterase can catalyze acetylthiocholine chloride to achieve electrochemical reaction of hydrosulfuryl acetylcholine. Sulfonic functionalized grapheme-chitosan is decorated on the surface of a bare glass carbon electrode, so that not only acetylcholinesterase is effectively fixed on the electrode, but also an electrochemical signal is amplified; and the methyl parathion residual quantity is related with electrochemical summit current, so that a standard curve for quantified detection of methyl parathion is built. The invention aims to provide the methyl parathion quantified detection method with high sensitivity and strong operability and develops the application of novel material graphene.
Owner:JIANGNAN UNIV +1

Modified electrode based on phenylboronic acid imprinted polymer/carbon nanotube, preparation method thereof and application

The invention discloses a modified electrode based on phenylboronic acid imprinted polymer / carbon nanotube, a preparation method thereof and application. The preparation method comprises: 1) depositing carbon nanotube on the surface of the glassy carbon electrode to get a carbon nanotube modified electrode; 2) adding the carbon nanotube modified electrode prepared by step 1) into a buffer solution containing 3-aminophenylboronic acid and rutin to get a 3-aminophenylboronic modified electrode by using a cyclic voltammetry method; 3) and washing out the 3-aminophenylboronic modified electrode to get the modified electrode based on phenylboronic acid imprinted polymer / carbon nanotube. According to the invention, the effects on specific recognition of rutin, sensitive quantitative determination of rutin, high anti-interference capability, simple preparation and low cost can be realized.
Owner:ANHUI NORMAL UNIV

Preparation and analysis methods of electrochemical sensor for detecting heavy metal ions

The invention provides a preparation method of an electrochemical sensor for detecting heavy metal ions. The preparation method includes the following steps: 1) performing carboxyl functionalization to multi-wall carbon nano-tubes and performing in-situ synthesis with zirconium chloride and 2-aminoterephthalatic acid to prepare an MWCNTs@UiO-66-NH2 composite material; 2) dispersing the MWCNTs@UiO-66-NH2 composite material in N,N-dimethylformamide to prepare a suspension liquid, drop-coating a surface of a glass carbon electrode with the suspension liquid until the surface of the glass carbon electrode is completely covered thereby, and drying the glass carbon electrode in a drying device at room temperature to prepare the MWCNTs@UiO-66-NH2 composite material electrochemical sensor. The electrochemical sensor can achieve ultrasensitive detection on a sample. By an analysis method in the invention, an accurate analytic result can be acquired.
Owner:DAFENG YUELONG CHEM

Preparation method of aptamer sensor for detecting antibiotic residue

The invention discloses a preparation method of an aptamer sensor for detecting antibiotic residue, belonging to the technical field of safety test of agricultural products. The method comprises the steps of carrying out electrochemical polymerization on a gold electrode and thionine to obtain electrically polymerized thionine electrode; after that, evenly dripping the prepared carbon nano tube-graphene nano-composition onto the surface of the electrically polymerized thionine electrode; drying in the air, and then soaking the electrode into antibiotic aptamer solution; washing, drying in the air, and closing by bull serum albumin (BSA) solution to obtain the antibiotic aptamer sensor. The prepared aptamer sensor has the advantages of not needing pretreatment, being high in analysis speed, simple in an operation system, high in accuracy, high in specificity, low in cost, rapid in response and the like, and has the limit of detection reaching up to 0.8nm, thus being suitable for rapidly detecting the antibiotic residue.
Owner:SHANDONG UNIV OF TECH

Method for manufacturing immunosensor for detecting chlorpyrifos

The invention discloses a method for manufacturing an immunosensor for detecting chlorpyrifos, which belongs to the technical field of biologic sensor manufacturing. The method comprises the following steps: dropwise coating the surface of a naked glassy carbon electrode, which is subjected to cleaning, activation and performance testing, with a nickel aluminum hydrotalcite-graphene compound liquid, subsequently modifying by hollow nanogold, further fixing a chlorpyrifos monoclonal antibody on the modified electrode, and finally, sealing by bovine serum albumin. The immunosensor manufactured by the method has the characteristics of high sensitivity, low cost, high detection speed, good stability and high sample recycling rate. The detection limit of the immunosensor manufactured by the method can be 0.052ng / L, the linear range of the immunosensor is 5ng / mL-2 micrograms / mL, the recycling rate of the immunosensor can be 82.0-118.0%, and therefore the immunosensor is applicable to rapid detection on the residual amount of chlorpyrifos in fruits and vegetables.
Owner:SHANDONG UNIV OF TECH

Micron-sized diode chip and preparation method

ActiveCN110061107AReduce areaRestricted shipping routesSemiconductor devicesQuantum wellThermal expansion
The invention provides a micron-sized diode chip. The micron-sized diode chip comprises a first table surface, a second table surface, a gallium nitride layer, an n-GaN layer, a stress release layer,a multi-quantum-well light-emitting layer, a p-GaN layer, a first electrode, a second electrode and an insulating layer, wherein the sizes of the first table surface and the second table surface are different. The technical problems that an original LED is low in output light power and large in mismatch with GaN in thermal expansion rate and lattice constant are avoided; and the technical effectsof integration of multiple functions of communication, illumination, detection and the like on the same chip, and high light extraction efficiency are achieved.
Owner:纳微朗科技(深圳)有限公司

Preparation method of aptamer sensor for pesticide detection

The invention discloses a preparation method of an aptamer sensor for pesticide detection, and belongs to the technical field of safety detection of agricultural products. The preparation method provided by the invention comprises the following steps: drop-coating carbon black-chitosan compound liquid on a surface of a bare glassy carbon electrode after cleaning, activation and performance testing; then, modifying with a graphene oxide-iron oxide compound; immobilizing a pesticide aptamer on the modified electrode; and finally, closing with bovine serum albumin. The aptamer sensor prepared in the invention has characteristics of high sensitivity, low cost, high detection speed, good stability and high sample recovery rate, has a detection limit of 0.033 ng / mL, a linear range of 0.1-105 ng / mL, a recovery rate of 96.0-106.0%, and is suitable for rapid detection of pesticide residues in fruits and vegetables.
Owner:SHANDONG UNIV OF TECH

Method for preparing metal micro-nano array electrode by using ZnO crystal as template

The invention provides a method for preparing a metal micro-nano array electrode by using a ZnO crystal as a template. The method employs a ZnO crystal array as the template and comprises the steps of submerging the template by photoresist, dissolving ZnO away after the photoresist is stabilized, and electrodepositing the metal crystal in holes formed by dissolving ZnO away. The obtained metal crystal has ZnO morphology, being in hexagonal prism shapes.
Owner:LIAOCHENG UNIV

Method for detecting phenol compounds by using horseradish peroxidase-modified electrode

The invention relates to a method for detecting phenol compounds by using an aluminum oxide nanoparticle / chitosan / horseradish peroxidase composite film-modified glassy carbon electrode and belongs to the technical field of electrochemical analysis detection. The key point of the method is to obtain the modified glassy carbon electrode which is equivalent to a current type biosensor by dispensing a certain amount of aluminum oxide nanoparticle / chitosan / horseradish peroxidase mixed solution on the surface of the glassy carbon electrode and use the aluminum oxide nanoparticle / chitosan / horseradish peroxidase composite film-modified glassy carbon electrode to quantitatively detect the phenol compounds. The method has the characteristics of quickness, sensitivity, accuracy, stability and the like.
Owner:SHANGHAI UNIV

On-line monitoring method for end insulation state of inverter driving motor

The invention relates to an on-line monitoring method for the end insulation state of an inverter driving motor, and the method comprises the steps: 1) collecting current signals on three-phase phase lines of the motor, and intercepting a switch high-frequency oscillation current segment; 2) decomposing the intercepted switch high-frequency oscillation current segment into three sub-modes by using a variational mode decomposition algorithm, obtaining a high-frequency common-mode current and a center frequency thereof, and taking the center frequency of the high-frequency common-mode current as an extracted frequency feature; 3) calculating the total variation of the three-phase insulation capacitance by using the center frequency of the high-frequency common-mode current; and 4) obtaining the amplitude variation of the three-phase high-frequency common-mode current at the resonance point as an extracted amplitude feature, and carrying out fault phase positioning by using the amplitude feature. Compared with the prior art, the method has the advantages of high sensitivity, high robustness, high safety and the like.
Owner:SHANGHAI UNIVERSITY OF ELECTRIC POWER

Artificial nerve synaptic device and preparation method thereof

The invention discloses an artificial nerve synaptic device and a preparation method thereof. The artificial nerve synaptic device comprises a first electrode layer, a second electrode layer and a function layer arranged between the first electrode layer and the second electrode layer. The resistive random access device prepared based on the material of the function layer has a unidirectional resistive random access characteristic and a bidirectional resistive random access characteristic at the same time. According to the artificial neural synaptic device and the preparation method thereof, related characteristics of associative learning and non-associative learning can be realized at the same time, and when the related characteristics of non-associative learning are realized, a three-terminal transistor does not need to be matched, and complex excitation conditions do not need to be provided.
Owner:INST OF MICROELECTRONICS CHINESE ACAD OF SCI

Graphene photoelectric detector based on interdigital electrode structure

The invention relates to a graphene photoelectric detector based on an interdigital electrode structure. The photoelectric detector comprises a substrate layer and an optical waveguide disposed on thesubstrate layer. The optical waveguide is provided with a dielectric isolation layer; the dielectric isolation layer is provided with two metal layers which are not in contact with each other; the two metal layers serve as electrodes; graphene layers are arranged on the two metal layers; and the graphene layers serve as light absorption layers. The provided graphene photoelectric detector based on the interdigital electrode is compatible with a CMOS process and has high performance.
Owner:苏州枫桥光电科技有限公司

Non-volatile memory component based on RbAg4I5 film and producing method thereof

The present invention discloses resistance switch effect based non-volatilisation phase transition memory element physical design preparation method. It contains setting solid electrolyte RbAg 4I5 film between reaction electrode and non - reaction electrode to construct one miniature sandwich structure of memory unit, said memory unit together with substrate and insulating layer all having five layers, depositing single-layer non - reaction electrode on substrate, depositing single-layer insulating layer on non - reaction electrode, and etching one micro pore in it to expose non - reaction electrode, depositing single-layer RbAg 4I5 film on insulating layer, thereon depositing single-layer reaction electrode, respectively leading out leading wire on non - reaction electrode and reaction electrode. Said memory element has advantages of compactness, simple structure, non-volatilisation, rapid read-write, low operating voltage and energy consumption, non - moving part, and nondestructive readout etc.
Owner:NANJING UNIV

Electrolyte thin film (AgI)x(AgPO3)1-x based on amorphous solid and its preparing method

The invention discloses a novel memory material - an amorphous solid electrolyte membrane (AgI) x (AgPO3)1-x, which is utilized to prepare a nonvolatile memorizer and can be used for an integrated circuit like information storage and other varieties. The amorphous solid electrolyte membrane (AgI) x (AgPO3)1-x of the invention is characterized in that: the (AgI) x (AgPO3)1-x is a solid electrolyte membrane material, has ionic conductivity, can be reversibly converted into electronic conductivity under certain conditions and takes the structure of an amorphous material under room temperature, and the nonvolatile memorizer with small size, high density and stable performance can be prepared by utilization of the membrane. The invention provides a preparation method for the amorphous solid electrolyte membrane (AgI) x (AgPO3)1-x, comprising the following steps: AgI, AgNO3 and (NH4)2HPO4 with adequate mixture ratio are melted and then fabricated into glass target materials, and then the amorphous solid electrolyte membrane is prepared by utilization of a laser pulse sedimentation method.
Owner:NANJING UNIV

Preparation and application of plant fiber-based reinforced carbon fiber network

The invention provides a plant fiber reinforced carbon fiber network, and belongs to the technical field of flexible pressure sensors. Steps of adding plant fibers into a periodic acid solution to form a paper pulp suspension, and heating to react to obtain a plant fiber network; calcining the dried plant fiber network, and taking out to obtain a carbon fiber network; immersing the carbon fiber network into a dopamine hydrochloride solution, and reacting, washing and drying are carried out to obtain the plant fiber-based reinforced carbon fiber network. The plant fiber reinforced carbon fibernetwork prepared by the invention is applied to a flexible piezoresistive pressure sensor, the compression strength of the carbon fiber network is greatly improved, and the plant fiber reinforced carbon fiber network has the advantages of short response time, large response current, low detection limit, wide working range and good anti-fatigue stability.
Owner:QILU UNIV OF TECH

Preparation method of ionic liquid electrolyte system for electrochemical oxygen sensor

The invention provides a preparation method of an ionic liquid electrolyte system for an electrochemical oxygen sensor. The preparation method comprises: mixing alkyl imidazole, alkyl halide and hexafluorophosphate in a ratio of 1:1.1:1.1, heating and refluxing in a water bath at 60-90 DEG C for 3-5 h, cooling, and washing with water until it is detected that no precipitate is produced in the upper layer of silver nitrate solution to obtain AMIMPF6 (1-alkyl-3-methylimidazolium hexa uorophosphate); mixing the AMIMPF6 with allyl imidazole, and ultrasonically treating for 1-2 h until uniform mixing; preparing electrolyte solution of electrodeposition inorganic matters, applying cathode current constantly in -5 mA to electrically deposit for 2400-360 s, collecting an inorganic catalyst by ultrasonic vibration, and mixing in the inorganic catalyst to obtain the final electrolyte. The preparation method is capable of synthesizing electrochemical oxygen sensor electrolyte high in oxygen sensitivity, good in catalytic performance and easy to prepare.
Owner:HARBIN ENG UNIV

Based on phenylboronic acid imprinted polymer/carbon nanotube modified electrode and its preparation method and application

The invention discloses a modified electrode based on phenylboronic acid imprinted polymer / carbon nanotube, a preparation method thereof and application. The preparation method comprises: 1) depositing carbon nanotube on the surface of the glassy carbon electrode to get a carbon nanotube modified electrode; 2) adding the carbon nanotube modified electrode prepared by step 1) into a buffer solution containing 3-aminophenylboronic acid and rutin to get a 3-aminophenylboronic modified electrode by using a cyclic voltammetry method; 3) and washing out the 3-aminophenylboronic modified electrode to get the modified electrode based on phenylboronic acid imprinted polymer / carbon nanotube. According to the invention, the effects on specific recognition of rutin, sensitive quantitative determination of rutin, high anti-interference capability, simple preparation and low cost can be realized.
Owner:ANHUI NORMAL UNIV

Solid electrolyte silver germanium oxygen thin film and preparation method and use thereof

This invention discloses a solid electrolyte argentums germanium oxygen film of new memory material, whose formula is AgxGeyO1-x-y, Ag-Ge-O film for short. The non-volatile memory made from this film can be used for information storage and integral circuits of other sorts. The manufacturing method of solid electrolyte film Ag-Ge-O of this invention is to roast powders of Ag2O and GeO2 with proper proportion so as to prepare the ceramic target, and then use the deposition method of laser impulse to prepare the solid electrolyte film. The solid electrolyte Ag-Ge-O film following characteristics: the main body is the material of solid electrolyte film, which has ion conductibility, can be reversibly converted to the electronic conductibility under a certain condition and used for manufacturing the non-volatile memory with small size, high intensity and steady property.
Owner:NANJING UNIV

Electrochemical biosensor for detecting bisphenol-A, and preparation method and application thereof

The invention discloses an electrochemical biosensor for detecting bisphenol-A, and a preparation method and an application thereof. The electrochemical biosensor comprises a counter electrode, a reference electrode and a working electrode. The electrochemical biosensor is characterized in that the working electrode is a glassy carbon electrode surface-modified by a graphene / gold complex, tyrosinase and chitosan. The preparation method comprises a step of preparing the graphene oxide; a step of preparing the graphene / gold complex; and a step of polishing and cleaning a bare glassy carbon electrode. A three electrode system electrochemical enzyme sensor is formed in the way that the graphene / gold complex, the tyrosinase and the chitosan are modified on the glassy carbon electrode to be used as the working electrode, a platinum electrode is used as the counter electrode and a saturated calomel electrode is used as the reference electrode. The concentration of bisphenol-A in a to-be-detected sample is determined by immersing the electrochemical biosensor in the to-be-detected sample and according to a quantitative relationship between corresponding current value and the concentration of bisphenol-A. The electrochemical biosensor has high sensitivity, strong selectivity, high accuracy and fast detection speed. The preparation method is simple and practical, and convenient for operations in actual detection.
Owner:NINGBO UNIV

Preparation method of multi-wall carbon nanotube/poly L-histidine modified glass carbon electrode and application thereof in determining hydroquinone

A multi-wall carbon nanotube / poly L-histidine compound membrane electrode (MWCNTs / poly-L-HiS / GCE) is prepared by polymerizing L-histidine to a glass carbon electrode and then dropping a multi-walled carbon nanotube suspension liquid to poly-L-HiS / CGE. In a PBS buffer solution, the pH of which is 7.0, an electrochemical behavior of hydroquinone (HQ) on a modified electrode is researched by virtue of cyclic voltammetry, and the property thereof is represented by means of electrochemical impedance spectroscopy (EIS), influence on hydroquinone determination by sweep rate, pH and etc. are discussed, the experimental condition is optimized, and finally, the HQ solutions with different concentrations are determined by means of differential pulse voltammetry (DPV). Experimental results verify that the response current on a composite electrode of HQ is obviously enhanced, and a good linear relationship with an oxidation peak current (Ipa) in a concentration range of 5.0*10<-8>-8*10<-4>mol / L is shown. The coefficient of association is 0.998, and when the signal to noise ratio is 3, the detection limit is 1.0*10<-8>mol / L.
Owner:XINYANG NORMAL UNIVERSITY

A micron-scale light-emitting diode chip and its preparation method

The invention provides a micron-sized diode chip. The micron-sized diode chip comprises a first table surface, a second table surface, a gallium nitride layer, an n-GaN layer, a stress release layer,a multi-quantum-well light-emitting layer, a p-GaN layer, a first electrode, a second electrode and an insulating layer, wherein the sizes of the first table surface and the second table surface are different. The technical problems that an original LED is low in output light power and large in mismatch with GaN in thermal expansion rate and lattice constant are avoided; and the technical effectsof integration of multiple functions of communication, illumination, detection and the like on the same chip, and high light extraction efficiency are achieved.
Owner:纳微朗科技(深圳)有限公司

A preparation method and application of silicon-based microneedles by metal-assisted wet etching

The present invention provides a preparation method to prepare silicon -based microneedles with metal auxiliary wet etching, including: the pre -processing silicon wafer surface is applied to the graphic processing to obtain the sample;Fluoric acid 纯 ultra -pure water hybrid solution is deposited to obtain sedimentary silicon wafers; the sedimentary silicon wafers are carved in the hydrogen hydrogen peroxide hydrogen peroxide mixed solution, soaked in the ingredients solution after washing, and then removed the silicon nano wire., Get the silicon -based microneedle.The method provided by the present invention only needs to be treated with a simple map with photoresist, and then the metal auxiliary wetting method is used to etched out large -sized microcliclement under acidic conditions.The etching time is short, the process is simple, and the effect is significant.The height of the silicon -based microneedle is 90 to 137 microns; the prepared sensors have a good linear response to hydrogen peroxide, and the response current is large. It can detect changes in the concentration of hydrogen peroxide at no less than 4 hours.
Owner:UNIV OF SCI & TECH OF CHINA

Preparation method of electrochemical sensor used for highly sensitively detecting copper ions

The invention relates to a preparation method of an electrochemical sensor used for sensitively detecting copper ions. The preparation method includes the following steps: synthesizing polyvinylpyrrolidone (PVP) / cobalt oxyhydroxide composite material through a hydrothermal method; and carrying out drip-coating of polyvinylpyrrolidone / cobalt oxyhydroxide suspended liquid on a glassy carbon electrode, and carrying out drying under an infrared lamp to obtain the electrochemical sensor by preparation. Cobalt oxyhydroxide has good electrochemical catalytic activity, complexation of heteroatoms (nitrogen and oxygen atoms) in polyvinylpyrrolidone and the copper ions shows high selectivity, combination of the two parts enables the electrochemical sensor of the invention to have high specific response to the copper ions, and sensitive detection on a trace amount of copper ions is realized. According to the electrochemical sensor to which the invention relates, preparation is simple, costs are low, stability is good, a linear range is wide, sensitivity and selectivity are high, and a fast, effective and sensitive method with high accuracy is provided for detection of copper in soil, water and food.
Owner:ZHAOQING UNIV

Preparation and analysis method of an electrochemical sensor for detecting heavy metal ions

The invention provides a preparation method of an electrochemical sensor for detecting heavy metal ions. The preparation method includes the following steps: 1) performing carboxyl functionalization to multi-wall carbon nano-tubes and performing in-situ synthesis with zirconium chloride and 2-aminoterephthalatic acid to prepare an MWCNTs@UiO-66-NH2 composite material; 2) dispersing the MWCNTs@UiO-66-NH2 composite material in N,N-dimethylformamide to prepare a suspension liquid, drop-coating a surface of a glass carbon electrode with the suspension liquid until the surface of the glass carbon electrode is completely covered thereby, and drying the glass carbon electrode in a drying device at room temperature to prepare the MWCNTs@UiO-66-NH2 composite material electrochemical sensor. The electrochemical sensor can achieve ultrasensitive detection on a sample. By an analysis method in the invention, an accurate analytic result can be acquired.
Owner:DAFENG YUELONG CHEM

Attapulgite/nitrogen-doped graphene modified glassy carbon electrode as well as preparation method and application thereof

The invention discloses an attapulgite / nitrogen-doped graphene modified glassy carbon electrode, a preparation method of the glassy carbon electrode, and application of the glassy carbon electrode, insynchronous detection of catechol and hydroquinone. The method comprises the following steps: mixing acid-modified attapulgite and nitrogen-doped graphene according to a mass ratio of (2-4):1, and ultrasonically dispersing in N,N-dimethylformamide; dispensing the dispersion on a glassy carbon electrode, and preparing a Pal / NGE modified glassy carbon electrode constructed by the composite film andglassy carbon electrode. The attapulgite / nitrogen-doped graphene modified glassy carbon electrode disclosed by the invention is simple in preparation, green, economic and low in cost. The attapulgite / nitrogen-doped graphene modified glassy carbon electrode can be applied to synchronous detection of catechol and hydroquinone and is excellent in reproducibility, high in stability and short in response time, and the lowest detection limit of the catechol and hydroquinone is respectively 0.13umol / L and 0.8 umol / L.
Owner:NANJING UNIV OF SCI & TECH

Electrochemical method for measuring COD of surface water

The invention relates to an electrochemical method for measuring COD of surface water. The electrochemical method comprises the following steps: (1) measuring background currents I1 and I2 of a background test solution consisting of deionized water and sodium sulfate under constant voltages V1 and V2; (2) measuring a response current I3 of a surface water test solution composed of surface water, deionized water and sodium sulfate under the constant voltage V1, respectively adding an organic matter capable of increasing the COD of the solution by X1 or chloride capable of increasing the chloride ion concentration of the solution by Y1, and measuring response currents I4 and I5 under the constant voltage V1; (3) according to the method in the step (2), respectively measuring the response current I6 of the surface water test solution, the response current I7 of the COD increased by X2 and the response current I8 of the chloride ion increased by Y2 under the constant voltage V2; and (4) calculating the COD value in the surface water according to a formula. The invention provides the method for measuring the response current of the surface water test solution under different conditionsby using the electrochemical device and calculating the COD value of surface water.
Owner:北京沅瀚环境科技有限公司
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