The invention discloses a sodium chloride-free environment-friendly coal-saving combustion improver special for cement, which aims to solve the technical problem of eliminating the damage of sodium chloride to furnaces, kiln bodies and the atmosphere. The combustion improver consists of an industrial grade finished product raw material, industrial residue, and a tailing material, and contains a barium compound, boride, carbonate, a chromium compound, fluoride, a magnesium compound, a manganese compound, nitride, a molybdenum compound II, a zirconium compound, industrial residue or tailings of rare earth, oxide and dicyclopentadienyl iron. Compared with the prior art, the combustion improver completely cancels the sodium chloride, furthest reduces the content of Cl<-> in ingredients, eliminates the damage of the sodium chloride to the furnaces, the kiln bodies and the atmosphere, reduces the damage of causing acid rain to the atmosphere, increases a plurality of metal acids, oxygen compounds and rare earth minerals, contains waste residue, ensures that the combustion is controllably performed, improves combustion environment, improves the combustion efficiency of fire coal, reduces energy consumption, prolongs the service life of equipment, and protects the environment.