The invention relates to a hierarchical pore structure
silicon-based negative
electrode material for a
lithium battery and a preparation method of the hierarchical pore structure
silicon-based negative
electrode material. The preparation method comprises the following steps: using a waste ultrafine
silicon dioxide
powder material generated in
optical fiber production, firstly performing acid
pickling and purification on the
silicon dioxide powder, then using a water bath method to disperse the purified
silicon dioxide powder into deionized water, adding a
silane coupling agent, then adding an acid to the solution, further adding a surfactant, stirring, standing, crystallizing, filtering,
drying and calcining the
crystal at high temperature to form a modified carrier; adding the modified
carrier material to an
ethanol solution or deionized water, adding silica powder, stirring and dispersing, filtering and
drying to obtain the silicon-based material with a mesoporous structure; then adding the purified
silicon dioxide powder to a
sodium hydroxide solution, performing high temperature
autoclave reaction, adding the silicon-base material with the mesoporous structure and a carbon material to the obtained product, then adding an acid solution, washing,
drying and calcining at high temperature, and naturally cooling to obtain the silicon-based negative
electrode material with the hierarchical pore structure.