Large volume of
flue gas containing
sulfur dioxide with low concentration is generated in an industrial process, phosphoric ore
slurry desulfurization has obvious technical advantages in
phosphorus chemical production enterprises, so the popularization and application are achieved. The
absorption efficiency of phosphoric ore
slurry to
sulfur dioxide is not stable due to the influence of fluctuation of
flue gas volume and change of the
sulfur dioxide concentration in the
flue gas. The method provided by the invention adopts
ammonium fluoride wastewater and
phosphate rock
powder discharged in the
phosphorus chemical enterprises to prepare a desulfurization absorber, so that the
sulfur dioxide with low concentration in the
flue gas can be absorbed. The method comprises the steps of uniformly mixing the pretreated
ammonium fluoride wastewater and fine-grained phosphoric ore to obtain the desulfurization absorber with 15 to 50 percent of
solid content, and the pH value is 8.0 to 9.0, the liquid-gas ratio is controlled to be 4-12 L / m<3> in an absorption process; when the pH value of circulating
slurry is less than 4.0, discarding 50 percent of absorption slurry, and adding the same amount of newly prepared phosphoric ore slurry absorption liquid into a circulating tank. The prepared absorbent has stable desulphurization efficiency, and the obvious influences of the
sulfur dioxide concentration and of the fluctuation of the flus gas volume to the
absorption efficiency of the
sulfur dioxide do not exist. According to the method, waste control by waste is realized, and the method has the characteristics of being simple in process facility, low in cost of operation, cheap and easily obtained materials.