39 results about "Perfluorooctanesulfonic acid" patented technology

A stretchable coated fabric to which water repellency has been imparted using a fluorochemical water repellent (C6 fluorochemical water repellent) comprising a copolymer containing a C6 or lower perfluoroalkyl group. As a result of this configuration, no C8 fluorochemical water repellent containing perfluorooctanoic acid, perfluorooctanesulfonic acid, or the like is used and, hence, the coated fabric exerts no influence on the environment. The fluorochemical water repellent has a toluene repellency of 100 seconds or higher, the synthetic-resin solution to be applied to at least one surface of a stretchable cloth has a thixotropic index measured at 23ºC of 1.4-2.0, and the synthetic resin has a 100% modulus of 5 kgf / cm2 or higher. Consequently, the stretchable coated fabric is free from, for example, synthetic-resin leakage to the back, and a coating resin film is formed with excellent film formation properties.

A liquid organic, fuel cell is provided which employs a solid electrolyte membrane. An organic fuel, such as a methanol / water mixture, is circulated past an anode of a cell while oxygen or air is circulated past a cathode of the cell. The cell solid electrolyte membrane is preferably fabricated from Nafion™. Additionally, a method for improving the performance of carbon electrode structures for use in organic fuel cells is provided wherein a high surface-area carbon particle / Teflon™-binder structure is immersed within a Nafion™ / methanol bath to impregnate the electrode with Nafion™. A method for fabricating an anode for use in a organic fuel cell is described wherein metal alloys are deposited onto the electrode in an electro-deposition solution containing perfluorooctanesulfonic acid. A fuel additive containing perfluorooctanesulfonic acid for use with fuel cells employing a sulfuric acid electrolyte is also disclosed. New organic fuels, namely, trimethoxymethane, dimethoxymethane, and trioxane are also described for use with either conventional or improved fuel cells.

The present invention discloses a preparation method of a porous ceramic surface perfluorooctane sulfonic acid molecularly imprinted adsorbent. According to the preparation method, waste ceramic is used as the supporting body of an adsorbent, and perfluorooctane sulfonic acid is used as a template molecule; 58-65% by mass of N,N-dimethylformamide, 15-20% by mass of succinimide, 1.0-3.0% by mass of perfluorooctane sulfonic acid, 12-18% by mass of aminated porous ceramic powder, and 1.0-4.0% by mass of ammonium persulfate are added to a reactor, a stirring reaction is performed for 6 h at a temperature of 75+ / -2 DEG C in the absence of oxygen, the obtained product is subjected to stirring washing for 12 h with the mixed solution of ethanol and sodium hydroxide, the template molecule is removed, and drying is performed to obtain the porous ceramic surface perfluorooctane sulfonic acid molecularly imprinted adsorbent. According to the present invention, the porous ceramic surface perfluorooctane sulfonic acid molecularly imprinted adsorbent can specifically recognize perfluorooctane sulfonic acid, and has advantages of high selectivity, good mechanical property, good chemical stability, fast adsorption, easy elution, and regenerative capacity.

The present invention discloses a solid-phase extraction analysis method of perfluorooctane sulfonic acid compounds in wastewater. The solid-phase extraction analysis method comprises: rinsing a solid-phase extraction column sequentially with 0.1% ammonium acetate-containing methanol, pure methanol and ultrapure water, and discarding the solutions after completing the rinsing; using a vacuum solid-phase extraction device to suck a wastewater sample, passing through the solid-phase extraction column, sequentially adding 2 mL of a solution containing acetone, acetonitrile and formic acid according to a ratio of 50:50:1, 3 mL of pure methanol and 3 mL of 0.1% ammonium acetate-containing methanol to carry out elution, and collecting and merging the eluent; blowing the eluent with nitrogen to approach a drying state, adding 1 mL of a solution containing methanol and water according to a ratio of 1:1, and uniformly mixing; and carrying out analysis testing through LC / MS / MS to obtain the result. According to the present invention, the sampling amount of the method is large, such that the samples have the good representativeness and can characterize the performance of the wastewater to the maximum extent; the operation process is simple and efficient, and the reproducibility of the laboratory data is stable; and the standard addition method recovery rate achieves 70%, the detection limit is low and is 0.01 [mu]g / L, the ecological requirements of the environment are met, and the tested compound variety is diverse.

The invention belongs to the technical field of a magnetic molecular imprinting polymer, and particularly relates to a magnetic molecular imprinting polymer for separating and enriching perfluorooctane sulfonate and a preparation method thereof. The magnetic molecular imprinting polymer has an ultrathin molecular imprinting film, and achieves fast adsorption dynamics, high adsorption selectivity and repeated use performance; the perfluorooctane sulfonate in water can be effectively and fast removed.

The invention provides a titanic acid nano material absorbent for enriching and / or purifying the organic pollutant in the biological and / or environmental samples and a preparation method thereof. The absorbent provided by the invention is a titanic acid nano tube modified by a hydrophobic group and a hydrophilic group simultaneously, preferred a titanic acid nano tube modified by C18 and aminopropyl, which can be uniformly dispersed in the water solution and has high adsorption capacity and better selectivity to the perfluorochemical in virtue of the mixed mechanism of the hydrophobic functionand the electrostatic attraction, and is especially suitable for the enrichment and / or purification of the perfluorooctane sulfonate and the perfluorooctane carboxylic acid in the biological and / or environmental samples. The absorbent provided by the invention is prepared by a hydrothermal method and an sol-gel method. The reagent and device are simple and cheap and the repeatability is good.

The invention provides a method for quantitatively detecting perfluorooctane sulfonate isomeride in a water sample, which belongs to the field of perfluorooctane sulfonate monitoring. The method for quantitatively detecting the perfluorooctane sulfonate isomeride in the water sample comprises the steps of (1) solid phase extraction: quantitatively taking the water sample, carrying out extraction with a solid phase extraction column, carrying out centrifugation to eliminate moisture in the extraction column after extraction, then purifying the dried extraction column by a buffer solution and methanol, eluting the purified extraction column with alkaline methanol, and collecting an eluant; (2) chemical processing of an extract: drying nitrogen of the eluant with wind, adding derivatization reagents, tetrabutylammonium hydroxide and methyl tertiary butyl ether, to be mixed, drying the solution nitrogen with wind, and adding the methyl tertiary butyl ether to be uniformly mixed so as to keep the volume constant; and (3) gas chromatography-mass spectrometric detection. The method successfully realizes the effective separation of the PFOS (perfluorooctane sulfonate) isomeride so as to realize the accurate and quantitative detection of the PFOS isomeride. Compared with the existing test technology, the method realizes the quantitative analysis and detection of the PFOS isomeride, and solves the problem of quantitative errors of PFOS.

The invention provides a method for synthesizing a corresponding ketone through catalyzing and hydrolyzing an alkyne with silver perfluorooctanesulfonate. According to the method, water serves as a solvent, an alkyne serves as a raw material, silver perfluorooctanesulfonate serves as a main catalyst, and perfluorooctanesulfonic acid serves as an auxiliary catalyst, and reaction is carried out to synthesize a corresponding ketone. The method provided by the invention is an environment-friendly method for synthesizing a ketone by hydrolyzing an alkyne. The method has the advantages that the selectivity and yield of the target product are more than 90%, n-hexane or diethyl ether is added at the end of reaction to divide reactants into two phases, the catalysts can be reused directly in the water phase, the product of reaction is extracted and separated simply to obtain a corresponding ketone, and the whole reaction and separation processes are simple and environment-friendly.