Electrochemical etching tailors
topography of a nanocrystalline or
amorphous metal or
alloy, which may be produced by any method including, by electrochemical deposition. Common
etching methods can be used.
Topography can be controlled by varying parameters that produce the item or the
etching parameters or both. The nanocrystalline article has a surface comprising at least two elements, at least one of which is
metal, and one of which is more electrochemically active than the others. The active element has a definite
spatial distribution in the workpiece, which bears a predecessor
spatial relationship to the specified
topography.
Etching removes a portion of the active element preferentially, to achieve the specified
topography. Control is possible regarding: roughness, color, particularly along a spectrum from silver through grey to black,
reflectivity and the presence, distribution and
number density of pits and channels, as well as their depth, width, size.
Processing parameters that have been correlated in the Ni—W
system to topography features include, for both the deposition phase and the
etching phase of a nanocrystalline surface:
duty cycle,
current density, deposition duration, plating
chemistry, polarity ratio. The relative influence of the
processing parameters can be noted and correlated to establish a relationship between values for
processing parameters and degree of topography feature. Control can be established over the topography features. Correlation can be made for any such
system that exhibits a definite
spatial distribution of an active element that bears a predecessor
spatial relationship to a desired topography feature.