287 results about "Cobalt phosphide" patented technology

A preparation method of a polyhedral cobalt phosphide catalyst for hydrogen production through water electrolysis comprises steps as follows: Co(NO3)2*6H2O and 2-methylimidazole are dissolved in methanol respectively, a 2-methylimidazole solution is poured into a Co(NO3)2 solution, the mixture is stirred and then aged at the room temperature, a product is centrifugally separated, vacuum drying is performed after washing with methanol, and a polyhedral metal organic frame ZIF-67 is obtained; then the polyhedral metal organic frame ZIF-67 is placed in a tube furnace, cobaltosic oxide is obtained through calcination in the air atmosphere, then the cobaltosic oxide and NaH2PO2*H2O are placed at two ends of a porcelain boat respectively, the NaH2PO2*H2O is located in the windward position of the tube furnace, and the polyhedral cobalt phosphide catalyst for hydrogen production through water electrolysis is obtained through calcination in the inert atmosphere. The crystallinity of the prepared cobalt phosphide catalyst material is high, the polyhedral morphology of a metal organic frame template is kept, the catalyst shows excellent properties in an electrocatalytic hydrogen evolution reaction, and the preparation technology is simple in process.

The invention relates to a catalyst for loading cobalt phosphide on activated carbon as well as preparation and application of the catalyst. The catalyst is prepared by taking multilayer nanoporous activated carbon (HNC) as a carrier and loading cobalt phosphide (CoP) on the surface of the activated carbon. The preparation method comprises the following steps: mixing cobalt nitrate hexahydrate (Co(NO3)2.6H2O), urea (CO(NH3)2), ammonium fluoride (NH4F) and deionized water to obtain a reaction mixture raw material; mixing a certain quantity of HNC with the reaction mixture raw material under an ultrasonic condition for hydrothermal reaction; carrying out suction filtration drying to obtain a precursor; conducting annealing on the precursor and sodium hypophosphite under the protecting atmosphere of argon; carrying out cooling. The catalyst prepared according to the preparation method can be used for electrochemical hydrogen evolution, and is excellent in catalytic activity for hydrogen evolution.

The invention belongs to preparation of a porous nano catalytic material, and particularly relates to a preparation method and application of a porous carbon-doped high-dispersion cobalt-phosphide-loaded material. The material is a carbon-based composite material which is of a mesoporous-macropore hierarchical porous structure and in which nitrogen atoms and phosphorus atoms are chemically doped in carbon skeletons and cobalt phosphide nanoparticles are loaded in a high-dispersion mode, and the specific surface area reaches up to 867 m<2> / g. The material is synthesized through the method comprising the steps that prepolymerization is firstly performed on organic phosphonic acid and melamine, and then high-temperature carbonization is performed. The material is applied to electro-catalysis hydrolysis hydrogen production and has the good effect. Used equipment is simple, the synthesis conditions are mild, the raw materials are easy to obtain, and the material is suitable for industrialized mass production.

The invention relates to a preparation method of cobalt phosphide coated with carbon layers. According to the method, cobalt salt and organic ligands are used as raw materials, a cobalt-containing metal-organic framework material is synthesized firstly and then subjected to high-temperature pyrolysis, air oxidation and low-temperature phosphating sequentially, and cobalt phosphide coated with the carbon layers is synthesized. Prepared cobalt phosphide is used as a hydrogen evolution catalyst under acidic and alkaline conditions and has high activity and high stability. The method is low in cost, mild in condition and suitable for industrial large-scale production, and products with relatively high purity can be obtained.

The invention relates to the technical field of color masterbatches and specifically relates to an antistatic and antibacterial color masterbatch and a preparation method thereof. The color masterbatch is prepared from the following raw materials in parts by weight: 48-63 parts of polypropylene resin, 19-36 parts of toner, 2-7 parts of dispersant, 0.5-1.5 parts of antistatic agent and 0.5-1.5 parts of antibacterial agent, wherein the polypropylene resin is metallocene polypropylene of which the melt index is 5-25g / 10min and the density is 0.886-0.924g / cm<3>; the antistatic agent is a mixture of octadecylamine polyoxyethylene ether, dodecylamine polyoxyethylene ether and monoglyceric stearate in the weight ratio of (0.5-1.5) to 1 to (2.4-3.2); the antibacterial agent is a mixture of silver-loaded zeolite and silver-loaded cobalt phosphate in the weight ratio of (1.5-2.5) to 1. The antistatic and antibacterial color masterbatch is good in antistatic effect, and has a relatively high safety coefficient, good antibacterial function and low harm.

The invention discloses a sulfur-doped cobalt phosphide - carbon nanofiber composite material and a preparation method thereof. The preparation method comprises the following steps of electrospinning a polyacrylonitrile dispersion liquid to obtain a polyacrylonitrile nanofiber membrane; pre-oxidizing the polyacrylonitrile nanofiber membrane and performing heating and carbonization to obtain a carbon nanofiber membrane, and causing the carbon nanofiber membrane to undergo surface hydrophilic treatment, to obtain a carbon nanofiber pretreatment membrane; proportionally dispersing cobalt salt and thiourea in an organic solvent, and then causing the dispersion liquid and the carbon nanofiber pretreatment membrane to be subjected to a solvothermal reaction to obtain a cobalt sulphide / carbon nanofiber composite material; and causing the cobalt sulphide / carbon nanofiber composite material to undergo phosphorylation reaction with sodium hypophosphite to prepare the sulfur-doped cobalt phosphide - carbon nanofiber composite material. The prepared composite material is controllable in morphology, has high specific surface area and excellent conductivity, and can be used as an ideal high-performance electrocatalytic material as well as an electrode material of new energy devices such as supercapacitors and lithium-ion batteries.

The invention provides a method for preparing a zinc phosphide / cobalt phosphide heterojunction photocatalyst based on an MOFs template and belongs to the technical field of preparation of photocatalytic materials. ZIF-ZnCo is used as a template, and the zinc phosphide / cobalt phosphide heterojunction photocatalyst with a porous structure is formed by conducting oxidation and phosphating treatment on the template. The original framework structure characteristics of a precursor MOFs are kept based on the catalyst, active catalysis sites are fully exposed, meanwhile the catalyst promotes separation of photoproduced electron holes and improves an photo-response behavior through a good synergistic effect, and therefore shows excellent water photolysis hydrogen-production performance.