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90results about How to "Uniform crosslinking" patented technology

Gelatin embolism microsphere and preparation method and application thereof

The invention provides a gelatin embolism microsphere and a preparation method and an application thereof. The preparation method of the gelatin embolism microsphere comprises the following steps of: (1) preparing a gelatin aqueous solution of which the concentration is 10-50 percent g / ml; (2) adding the gelatin aqueous solution prepared in the step (1) into an emulsifier-containing oil phase of which the temperature is 50-60 DEG C, stirring for 10 minutes, lowering the temperature to 2-5 DEG C, stirring for 30 minutes at the stirring speed of 100-900 revolutions per minute, and standing to precipitate the microsphere; (3) pouring the oil phase out, repeatedly washing the oil phase left on the surface of the microsphere with acetone, and filtering the microsphere out; and (4) adding the microsphere obtained in the step (3) into a crosslinking agent aqueous solution of which the pH is 8-9 and the concentration is 1-15 percent g / ml, reacting at the temperature of 4 DEG C for 0.5-25 hours, and washing the microsphere with distilled water. The gelatin embolism microsphere provided by the invention is crosslinked uniformly, is regularly spherical, and is convenient for screening grading and accurate marking of the particle diameter; and the degradation time and elasticity of the gelatin embolism microsphere are more suitable for clinical application.
Owner:HYGEA MEDICAL TECH CO LTD

Preparation and its products for composite nanometer filter membrane

A process for preparing the composite nano-class filtering membrane includes such steps as providing the ultra-filter membrane made of polysulfone or poly vinylidene fluoride as substrate, dipping in the aqueous solution of aminoester polyacrylate polymers chosen from polymethyl acrylate-N, N-dimethylamino ethylester, polymethyl acrylate-N, N-dimethylamino methylester, polymethyl acrylate-N, N-diethylamino methylester, etc, drying, and beta-ray irradiating for cross-linking.
Owner:TIANJIN MOTIAN MEMBRANE ENG & TECH

Preparation method of antibacterial super absorbent resin

The invention discloses a preparation method of antibacterial super absorbent resin. The preparation method comprises the following steps: firstly adding acrylic acid and deionized water into a reactor, adding 50% sodium hydroxide solution for neutralization, and adding acryloyl morpholine, ultrafine silicon dioxide and a complex cross-linking agent; then introducing nitrogen to remove oxygen for 30 min, adding an initiator to initiate a polymerization reaction at 20-30 DEG C, and regarding that the reaction is completed when the temperature does not rise; pelleting, drying and crushing gel to obtain water-absorbent resin particles; finally carrying out high-temperature processing at 120 DEG C on the resin particles through ethylene glycol, a nano-silver antibacterial and 25% aluminum sulfate for 2-5 hours to obtain the antibacterial super absorbent resin. The reparation method adopts a new antibacterial polymeric monomer, and the resin particles can reach a good antibacterial and sterilizing effect; a high low temperature compound type cross-linking agent is adopted, so that the cross-linking of molecules is more uniform; suspended silicon dioxide particles can guarantee good conductivity among the resin particles. No azo initiator is used, so that the antibacterial super absorbent resin is free of azo substance residues.
Owner:SHANDONG NUOER BIOLOGICAL TECH

High-temperature-resistant silicone rubber foam material and preparation method thereof

The invention discloses a high-temperature-resistant silicone rubber foam material and a preparation method thereof. The preparation method of the high-temperature-resistant silicone rubber foam material is characterized by comprising the following steps: mixing 100 parts of silicone rubber base stock, 20-35 parts of a reinforcing agent, 2-3 parts of a structure controlling agent, 0-0.2 part of colour master batch, 60-150 parts of a pore-forming agent and 4-5 parts of a radiation sensitizer, moulding, crosslinking through gamma ray radiation, forming pores through subsection dissolving-out, and drying, so that the silicone rubber foam material which is resistant to high temperature of 250 DEG C and still maintains excellent performance after equivalent time of 20000 hours can be obtained. The preparation method of the high-temperature-resistant silicone rubber foam material has the advantages that radiation crosslinking and dissolving-out pore forming are combined, so that crosslinking is uniform, control is easy, energy conservation and environmental protection are realized, a technology is concise, reproducibility is good, and production efficiency is high; the high-temperature-resistant silicone rubber foam material still maintains high tensile strength, high weight loss, low longitudinal deformation and low surface hardness after the equivalent time of 20000 hours at the temperature of 250 DEG C, permanent compressive deformation is slightly increased, the high-temperature-resistant silicone rubber foam material does not become brittle or hard, and the high-temperature-resistant silicone rubber foam material can serve as filling and positioning, sealing cushion, cable insulation as well as buffer and vibration-absorptive materials or parts which are used in high-temperature environment.
Owner:INST OF NUCLEAR PHYSICS & CHEM CHINA ACADEMY OF

Low-density and high-porosity silicone rubber foam material and preparation method thereof

The invention discloses a low-density and high-porosity silicone rubber foam material and a preparation method thereof. The method is characterized by comprising the following steps: 100 parts of silicone rubber, 10 to 50 parts of a reinforcing agent, 1 to 7 parts of a control agent, 200 to 600 parts of a pore-forming agent, and 0 to 5 parts of a sensibilizer are mixed and molded, and then are radiated through gamma ray, so as to be subjected to crosslinking; the amount of radiation absorber is 30 to 100kGy; then the low-density and high-porosity silicone rubber foam material with excellent performance is obtained after elution and freeze drying. The material has the advantages that the technology is simple, complex chemical control process or professional auxiliary equipment is not needed, simple equipment, such as a two-roll mill, is only needed, and the cost is low; the silicone rubber foam material has the characteristics of low density and high porosity, is soft in material and excellent in elasticity, and can serve as a filling, positioning, sound-proof and vibration-absorptive material.
Owner:SOUTHWEAT UNIV OF SCI & TECH +1

Self-adhesion silicon rubber material and preparation method thereof

The invention discloses a self-adhesion silicon rubber material and a preparation method thereof. The preparation method is characterized in that 100 parts of silicon rubber, 10 to 80 parts of a reinforcing agent, 1 to 9 parts of a controlling agent and 0 to 5 parts of a sensitizing agent are mixed and formed, and then are subjected to gamma-ray radiation to be crosslinked to obtain the self-adhesion silicon rubber material with excellent performance, wherein the radiation absorbed dose is 30 to 100 kGy. The self-adhesionsilicon rubber material and the preparation method thereof have the advantages that the process is simple, complex chemical raw materials and process control or professional auxiliary equipment are not needed, and the cost is relatively low; and the prepared silicon rubber material can be well adhered to various components or assemblies, such as metal, glass, polyethylene, polytetrafluoroethylene and the like, can maintain lasting adhesion, and can effectively prevent the components or the assemblies from falling off or sliding.
Owner:SOUTHWEAT UNIV OF SCI & TECH +1

Preparation method of super absorbent resin resistant to moisture absorption and caking

ActiveCN107474170ASolve product quality fluctuationsImprove stabilitySuper absorbentAluminium salts
The invention relates to a preparation method of super absorbent resin resistant to moisture absorption and caking. The preparation method comprises the following steps: introducing nitrogen to removal oxygen after mixing acrylic acid, water and a cross-linking agent, then adding an initiating agent until the temperature is not increased, and then preserving the temperature to obtain a product; treating the obtained product to obtain resin particles; adding reinforcing agent powder into the resin particles to be mixed uniformly, then adding a surface cross-linking solution to be stirred uniformly, preserving the temperature at the temperature of 120 to 200 DEG C to obtain the super absorbent resin, wherein the reinforcing agent is selected from one or more of calcium oxide, kaoline, silica, aluminum sulfate, aluminum oxide, calcium carbonate and magnesium carbonate. The super absorbent resin synthesized by using the method is highly uniform in surface cross-linking degree and high in strength, is not easy for moisture absorption and caking in air, can be stored for longer time, is unlikely to cause gel blockage after liquid absorption, and has good liquid flowing performance and conduction performance.
Owner:SHANDONG NUOER BIOLOGICAL TECH

Preparation method of calcium alginate electrically-driven film adopting microwave vacuum low-temperature drying technology

The invention provides a preparation method of a calcium alginate electrically-driven film adopting a microwave vacuum low-temperature drying technology. The microwave vacuum low-temperature drying technology is adopted, and through the combination with the two technologies of microwave drying and vacuum drying, the advantages of the two technologies are sufficiently and comprehensively developed.The preparation method comprises the following steps: using natural macromolecular biological materials of sodium alga acid as a film forming main material and a cross-linking agent CaCl2, and addingplasticizer glycerinum and plastic assisting agent lauryl sodium sulfate so as to prepare the calcium alginate electrically-driven film of a three-dimensional network gel structure. The raw materialsare wide in sources and low in cost, and the obtained electrically-driven film is non-toxic, tasteless and biodegradable. After microwave vacuum drying, hierarchical pore structures are connected with one another and are regular, the ionic cross-linking of Ca<2+> on the inner layer and the outer layer is comprehensive and uniform, and the electrically-driven film is excellent and controllable inelectrically-driven performance and long in service life. The microwave vacuum low-temperature drying technology of the calcium alginate electrically-driven film prepared in the invention is energy-saving, efficient and free of pollution, and is mostly beneficial for high molecular material synthesis and curing reaction with extremely high requirement for heating rate and uniformity.
Owner:HARBIN ENG UNIV

Preparation method of edible collagen membrane

The invention discloses a preparation method of an edible collagen membrane. The method comprises the following steps: first, performing a reaction on animal collagen dissolved by an acetic acid solution and hydroxycarboxylic acid-N-hydroxysuccinimide ester, removing bubbles, performing film forming and drying to obtain a transparent collagen membrane, soaking the obtained transparent collagen membrane in a solution containing oxidase for a reaction, after the reaction is finished, performing washing by water and performing drying to obtain the edible collagen membrane. In the method provided by the invention, with the adoption of step-by-step crosslinking modification on a collagen membrane, the system is uniform in crosslinking, the membrane is more uniform and compact, and the crosslinking degree is higher, so that the tensile strength of the membrane can be greatly improved, and meanwhile, the membrane is transparent in color, and is more suitable for being used as a packaging material for highlighting the color of packaged objects. The method provided by the invention is simple in method and easy in operation and is easy for popularization and application.
Owner:SICHUAN UNIV

A kind of preparation method of antibacterial superabsorbent resin

The invention discloses a preparation method of antibacterial super absorbent resin. The preparation method comprises the following steps: firstly adding acrylic acid and deionized water into a reactor, adding 50% sodium hydroxide solution for neutralization, and adding acryloyl morpholine, ultrafine silicon dioxide and a complex cross-linking agent; then introducing nitrogen to remove oxygen for 30 min, adding an initiator to initiate a polymerization reaction at 20-30 DEG C, and regarding that the reaction is completed when the temperature does not rise; pelleting, drying and crushing gel to obtain water-absorbent resin particles; finally carrying out high-temperature processing at 120 DEG C on the resin particles through ethylene glycol, a nano-silver antibacterial and 25% aluminum sulfate for 2-5 hours to obtain the antibacterial super absorbent resin. The reparation method adopts a new antibacterial polymeric monomer, and the resin particles can reach a good antibacterial and sterilizing effect; a high low temperature compound type cross-linking agent is adopted, so that the cross-linking of molecules is more uniform; suspended silicon dioxide particles can guarantee good conductivity among the resin particles. No azo initiator is used, so that the antibacterial super absorbent resin is free of azo substance residues.
Owner:SHANDONG NUOER BIOLOGICAL TECH
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