The invention provides a preparation method of a composite nano-
filtration membrane with self-repairing, bacterium-resisting and
solvent-resisting functions. The specific method comprises: mixing a
transition metal ion solution and a bichelidoxalic acid solution; adjusting the pH (Potential of
Hydrogen) value of a mixed
system through utilizing a buffering solution; sufficiently stirring to obtain a super-molecular
polymer solution; fixing a base membrane in a container with a porous supporting layer and putting a
membrane surface upward; adding a cationic
polyelectrolyte solution; pressurizing, assembling and washing with water; then adding into the super-molecular
polymer solution, and pressurizing, assembling and washing with the water; carrying out heat treatment to obtain a double-layered modified membrane; repeating for 1 to 3 times to obtain a multilayered super-molecular
polymer nano-
filtration membrane; finally, immersing the multilayered super-molecular polymer nano-
filtration membrane into a
polylysine solution; pressurizing, assembling and washing with the water; carrying out the heat treatment to obtain the composite nano-
filtration membrane with the self-repairing, bacterium-resisting and
solvent-resisting functions. The preparation method provided by the invention is simple and efficient; the prepared nano-
filtration membrane is high in flux and good in separation effect and also has self-repairing, bacterium-resisting,
solvent-resisting and
fluorescence performance.