The invention provides odor-free wear-resistant ultraviolet curing coating and a preparation method thereof. The coating consists of the following components: ultraviolet curing resin, a reaction type acrylate monomer, a photoinitiator, an antifoaming agent, a leveling agent and a wetting dispersant. The coating provided by the invention is odor-free wear-resistant UV (Ultraviolet) curing coating which is used for coating processes including spray-coating, roller-coating, shower-coating and the like of suite furniture, cupboards, door plates and the like. Meanwhile, the wear resistance and the leveling effect are excellent, the top side is flat, GB18582-2009 and GB / T9756-2009 can be satisfied while the construction period is short, and poisonous and harmful substances including benzene, formaldehyde, free TDI (Toluene Diisocynate) and the like are not contained; moreover, the heavy metal content is far lower than the European standard, and therefore, the coating is a functional product with excellent environment-friendly performances, and benzene content (mg / M<2>) not bigger than 0.003 before and after the construction, and is also odor-free wear-resistant ultraviolet curing coating.