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Reinforcing flexibilizer used for 3D printing of ABS, ABS composite material, production method of ABS composite material

A technology of strengthening and toughening and 3D printing, which is applied in the direction of additive processing, etc., can solve the problems of high shrinkage, insufficient toughness and strength of ABS, warping and other problems, achieve small shrinkage, improve toughness and strength, and reduce irritating odor Effect

Inactive Publication Date: 2016-09-14
GUANGXI MEDICAL UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, with the passage of time, people's requirements for 3D printing quality have improved, and some problems of ABS materials have gradually emerged. The most important ones are the lack of toughness and strength of ABS and the warping phenomenon caused by large shrinkage during the cooling process.

Method used

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  • Reinforcing flexibilizer used for 3D printing of ABS, ABS composite material, production method of ABS composite material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] A reinforcing and toughening agent for 3D printing ABS, which is made by fully mixing the following raw materials: 150g of carbon black with a particle size of 30nm; 40g of glass fiber with a monofilament diameter of 2μm and an aspect ratio of 6; 70 g of 10 μm SBS resin powder.

Embodiment 2

[0026] A reinforcing and toughening agent for 3D printing ABS, which is made by fully mixing the following raw materials: 270g of carbon nanotubes with a particle size of 65nm; 65g of glass fibers with a monofilament diameter of 5.6μm and an aspect ratio of 8.2; 100 g of SBS resin powder with a particle diameter of 15 μm.

Embodiment 3

[0028] A reinforcing and toughening agent for 3D printing ABS, which is made by fully mixing the following raw materials: 270g of graphene with a particle size of 80nm; 65g of glass fibers with a monofilament diameter of 8μm and an aspect ratio of 10; 100 g of 20 μm SBS resin powder.

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Abstract

The invention belongs to the field of polymer materials for 3D printing, and concretely relates to a reinforcing flexibilizer used for 3D printing of ABS, an ABS composite material, a production method of the ABS composite material. The reinforcing flexibilizer is prepared through fully mixing, by weight, 15-30 parts of carbon nano-powder, 4-8 parts of glass fibers and 7-12 parts of SBS resin powder; and the ABS composite material is prepared from, by weight, 40-60 parts of ABS resin powder, 15-20 parts of PLA resin powder, 10-20 parts of the reinforcing flexibilizer, 0.2-0.7 parts of an antioxidant and 5-10 parts of a dispersing agent. The reinforcing flexibilizer can be used to be combined with ABS resin in order to greatly improve the toughness and the strength of an ABS material; the ABS composite material has obviously enhanced strength and toughness, and the shrinkage rate of the melt of the ABS composite material is reduced to 0.5% or below in the cooling process; and components of the ABS composite material contain PLA resin, so the ABS composite material has reduced irritating smell when used in 3D printing.

Description

technical field [0001] The invention belongs to the field of polymer materials for 3D printing, and in particular relates to a reinforcing and toughening agent for 3D printing ABS, an ABS composite material and a production method thereof. Background technique [0002] 3D printing is a kind of rapid prototyping technology. It is a technology based on digital model files and using bondable materials such as powdered metal or plastic to construct objects by layer-by-layer printing. 3D printing technology is generally used in the fields of mold manufacturing and industrial design, especially in the manufacture of samples before production. With the development of technology, it is gradually used in the direct manufacture of some products. In the prior art, 3D printing commonly used ABS materials of plastic materials adopts the manufacturing method of "layer-by-layer superimposition, inter-layer bonding", but limited by the strength and bonding performance of the material itself...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08K3/04C08K7/14C08K7/24C08L53/02C08L55/02C08L67/04B33Y70/00
CPCC08K3/04C08K7/14C08K7/24C08K2201/003C08K2201/011C08K2201/016C08L55/02C08L2205/03C08L53/02C08L67/04
Inventor 郑立赵劲民靳攀梁体洪刘慧
Owner GUANGXI MEDICAL UNIVERSITY
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