The invention relates to a rapid
analysis method of lead in gold mud. The method comprises the following steps:
processing a sample by
nitric acid,
aqua regia,
sulfuric acid, and a mixed acid of
nitric acid and
sulfuric acid in sequence, after the acid is smoked and evaporated, adding diluted
sulfuric acid, boiling to dissolve the salts, adding
excess sodium hyposulfite to reduce gold to zero valent and precipitate silver; allowing the
system to stand still to carry out aging, filtering, washing the precipitate by diluted sulfuric acid and water; dissolving the precipitate by an
acetic acid-
sodium acetate
buffer solution, filtering, recovering gold and silver, adding a
xylenol orange indicator into the filtrate, dropwise adding EDTA until the color of the solution changes from purple-red to light yellow, wherein the color change shows that the
titration end point is reached, and finally calculating the lead content. In the provided method,
sodium hyposulfite is used to reduce gold and precipitate silver so as to effectively separated gold and silver from lead, thus the interference of gold and silver on the end point is avoided, moreover, the operation is largely simplified, and precise and stable analysis results can be obtained by the provided method.