30results about How to "Low diffusible hydrogen" patented technology

A highly basic particle flux for submerged arc welding that produces less than 7 ml / 100 gr of diffusible hydrogen in the weld metal, which flux comprises a carbon dioxide containing compound with an effective amount of heat releasable carbon dioxide in the range of 0.5-3.5% by weight of the flux over 10% by weight of a low melting point compound and a binder.

The invention discloses a preheat-free welding rod and application thereof. The preheat-free welding rod comprises a welding core and a coating and is characterized in that the coating comprises the following component in percentage by weight: 35-40% of marble, 2-5% of barium carbonate, 17-22% of fluorite, 0.5-2.0% of lithium fluoride, 2-5% of silica micro-powder, 4-6% of rutile, 3-5% of ferrosilicon, 2-4% of ferromanganese, 2-4% of ferromolybdenum, 1-2% of rare-earth ferrosilicon, 0.5-1% of sodium carbonate, 1-2% of magnesium powder, 2-4% of ferrotitanium, 8-10% of nickel powder, and the balance being iron powder. The preheat-free welding rod disclosed by the invention is specially used for welding a low-alloy high-strength steel in matched application, saves a preheat treatment in use, can remarkably reduce the content of diffusible hydrogen and the hardening capability of a welding material, reduces the number of welding cold cracks, and is of very important significance to simplification of a welding process, improvement of performances of a weld joint, reduction of production cost and improvement of working environment.

The invention discloses a seamless submerged arc flux-cored wire for steel with the yield strength being 550 MPa. The seamless submerged arc flux-cored wire is composed of a casing and flux core powder. The casing is a low-carbon steel strip. The flux core powder is prepared from, by weight, 8%-10% of nickel powder, 3%-6% of ferro-molybdenum, 10%-14% of manganese metal, 6%-8% of rare earth ferrosilicon, 3%-5% of ferrotitanium, 1%-2% of ferrozirconium, 1%-3% of ferro-boron, 1%-2% of potassium titanate, 1%-3% of sodium fluoride, and the balance iron powder. The seamless submerged arc flux-cored wire is extremely high in moisture absorption resistance and is matched with fluoride-basic type sintered flux SR-SJ613, the technical properties are excellent, diffusible hydrogen is smaller than or equal to 5 ml every 100 g (based on a gas chromatographic method), the Charpy impact energy at minus 40 DEG C reaches 100 J or over, and the seamless submerged arc flux-cored wire can be applied to welding of steels plates with the yield strength being 550 MPa in high-end technical fields such as ocean engineering and naval construction.

The invention provides an ultralow-hydrogen and high-tenacity metal powder core type seamless flux-cored welding wire for all-position welding. The seamless flux-cored welding wire comprises outer skin and flux core powder, wherein the inner part of the outer skin is filled with the flux core powder, and the outer skin is a low-carbon steel band. The seamless flux-cored welding wire is characterized in that the flux core powder comprises the following components in a percent by weight: 10-15% of low-carbon ferromanganese, 15-20% of atomized ferrosilicon, 2-5% of rutile, 1-5% of cryolite, 1-3% of atomized nickel powder, 1-2% of quartz, 0.5-2% of feldspar and the balance of iron powder. The seamless flux-cored welding wire is suitable for the all-position welding of carbon steel and low-alloy steel which are welded under the protection of mixed gas containing 75-85% of Ar and 15-25% of CO2. The seamless flux-cored welding wire is great in welding machinability, stable in mechanical properties, great in crack resistance, low in hydrogen dispersion and high in moisture absorbability and can be used for all-position welding.

The invention discloses an ultralow hydrogen seamless submerged arc flux-cored wire for steel with yield strength being the 690 MPa level. The submerged arc flux-cored wire is composed of a sheath and flux core powder. The sheath is made of a low-carbon steel strip. The flux core powder is prepared from, by mass percent, 8%-12% of marble, 4%-8% of fluorite, 25%-30% of metal nickel, 2%-4% of metal chromium, 7%-9% of ferromolybdenum, 12%-16% of electrolytic manganese, 1%-3% of ferrosilicon, 3%-5% of ferrotitanium, 2%-4% of ferro-boron, 2%-3% of potassium titanate, 1%-3% of potassium fluoride, 1%-3% of sodium fluoride and the balance ferrous powder. The ultralow hydrogen seamless submerged arc flux-cored wire for the steel with the yield strength being the 690 MPa level is high in moisture absorption resisting property, and excellent in processing property of being matched with fluorine and alkali sintered flux SR-SJ613, diffusible hydrogen is extremely low (smaller than or equal to 4 mL / 100 g), minus 40 DEG C charpy impact energy reaches over 100 J, and the wire can be applied to welding of a steel plate with the yield strength being the 690 MPa level in the ocean engineering field.

The invention provides an acidic high-strength and high-toughness flux-cored welding wire, which includes a flux core and a sheath coated on the outside of the flux core; the flux core includes the following components in parts by weight: 300-430 parts of rutile; 20-430 parts of feldspar 40 parts; 13-25 parts of quartz; 8-20 parts of zircon sand; 4-14 parts of magnesia; 3-10 parts of sodium fluoride; 5-13 parts of iron; 5-15 parts of magnesium powder; 2-9 parts of silicon-calcium alloy; 3-11 parts of aluminum-magnesium alloy; 22-40 parts of ferrosilicon; 14-25 parts of rare earth ferrosilicon; 110-150 parts of nickel powder; 45-70 parts of ferromolybdenum; 3-12 parts of graphite, iron powder balance; the sum of the parts by weight of each powder component is 1000 parts. The acidic flux-cored welding wire of the present invention still has relatively high low-temperature impact toughness and good cold cracking resistance at relatively high strength.

Disclosed is an ultra-low hydrogen high-tenacity seamless flux-cored wire for 550 MPa high-strength steel. The flux-cored wire is composed of flux core powder and low-carbon steel band wrapping the flux core powder. The flux core powder is composed of rutile powder, rare earth fluoride, atomized ferrosilicon powder, low-carbon ferromanganese powder, aluminum-magnesium alloy powder, metal titanium powder, metal nickel powder, metal chromium powder, metal molybdenum powder, alumina powder, quartz powder, and the balance iron powder and unavoidable impurities. Re in the rare earth fluoride and a trace of calcium in the atomized ferrosilicon powder of the flux core powder form a combined effect, the size of weld metal inclusion is reduced, the combined effect of Al-Mg-Ti enables the components of the inclusion to facilitate nucleation of acicular ferrite, the content of the acicular ferrite is increased, the structure is refined, and therefore good low-temperature impact toughness is achieved, and the -40 DEG C impact energy average value can reach 80 J or above.

The invention belongs to the technical field of welding materials and discloses a submerged-arc welding flux matched with 850MPa-grade weather-proof high-strength steel and a production and use methodthereof. The welding flux is formed by mixing various ore raw materials and a small amount of alloy powder. The welding flux comprises the following main components: 17-33% of fluorite; 0.1-0.5% of lanthanide series rare earth; 16-21% of zircon sand; 2.5-4% of manganese-iron alloy; 20-37% of fused magnesia; 2-9% of natural wollastonite; 12 to 26% of bauxite; and 2-4% of solid water glass. The welding flux comprises a binder. The main components are uniformly mixed according to the proportions; 20-21.5% of the binder is added into the uniformly mixed main components; an obtained mixture is granulated; an obtained substance is subjected to low-temperature baking at 200-230 DEG C, high-temperature sintering at 680-730 DEG C, and screening sequentially, so that a flux product of which the alkalinity ranges from 2.8 to 3.0 and of which the mesh number ranges from 20 to 50 is obtained. When the welding flux and a special welding wire are matched with each other to weld the 850MPa-grade weather-proof high-strength steel, a deposited metal is obtained. The chemical component C of the deposited metal is smaller than or equal to 0.10%; the chemical component Mn of the deposited metal rangesfrom 1.0 to 2.2%; the chemical component Si of the deposited metal is smaller than or equal to 0.60%; the chemical component P of the deposited metal is smaller than or equal to 0.020%; the chemicalcomponent Cr of the deposited metal is smaller than or equal to 0.60%; the chemical component Mo of the deposited metal ranges from 0.20 to 0.60%; the chemical component Ni of the deposited metal ranges from 2.00 to 3.30%; the chemical component Cu of the deposited metal is smaller than or equal to 0.25%; and the balance of the deposited metal is Fe.

The invention discloses a high-toughness titanium alkaline type seamless flux-cored wire suitable for all-position welding. The flux-cored wire is composed of a low-carbon steel strip at the peripheryand flux core powder inside; and the flux core powder comprises the following components, by weight percentage: 30-40% of rutile, 1-2% of aluminum oxide, 2-4% of dehydrated feldspar, 1-3% of quartz,1-3% of zircon sand, 1-2% of rare earth oxide, 1-2% of silicon powder, 0.2-0.4% of ferroboron, 6-8% of nickel powder, 8-15% of metal manganese, 4-9% of magnesium powder and the balance iron powder andinevitable impurities. According to the flux-cored wire, a titanium alkaline slag system is adopted, the proportion of alloy elements is optimized, the content of mineral powder is adjusted, and under the protection of CO2 gas, horizontal, transverse and vertical position welding can be realized; the mechanical property is stable, the impact power at 40 DEG C below zero reaches 100J, the crack resistance is good, diffusible hydrogen is low, the moisture resistance is strong, the seawater corrosion resistance is good, and the anti-cracking ability is good.

A rutile-type flux-cored welding wire with a yield strength exceeding 890 MPa is composed of a steel strip wrapping the flux-core and a flux-core filled therein, and the flux-core includes C: 0.03-0.09%, Si: 0.3-0.8% by weight percentage , Mn: 1.2‑2.2%, Ni: 0.5‑1.5%, Co: 1.0‑3.5%, Ta: 0.020–0.045%, Rare Earth Alloy: 0.2‑0.5%, TiO 2 : 2.0–4.0%, SiO 2 : 0.2‑0.5%, ZrO 2 : 1.0–3.0%, K 2 O: 0.2-0.4%; the remainder is Fe and other inevitable impurities. Welding wire adopts 80%Ar+20%CO 2 Mixed gas shielded welding has the characteristics of weld metal yield strength exceeding 890MPa, low temperature impact toughness-40℃ impact greater than 47J, diffusible hydrogen less than 2ml / 100g, stable welding arc, and excellent all-position welding processability.

The invention relates to a high toughness seamless submerged-arc flux-cored wire for 460MPa steel. The high toughness seamless submerged-arc flux-cored wire for 460MPa steel is composed of a peripheral mild-carbon steel strip and flux-cored wire powder inside. The flux-cored wire powder comprises the following components in percentages by mass: 8-13% of nickel powder, 0.5-1.5% of ferromolybdenum, 12-20% of manganese metal, 3-7% of rare earth silicon iron, 2-5% of ferrotitanium, 1-3% of ferroboron, 0.5-1% of sodium fluoroaluminate, 1-2% of fluorite and the balance of iron powder and inevitable impurities. The seamless submerged-arc flux-cored wire provided by the invention is matched with fluoride-basic type sintered flux SR-SJ613, the Charpy impact energy reaches 110J or above at 40 DEG C below zero, diffusible hydrogen is smaller than or equal to 5ml / 100g, and the high toughness seamless submerged-arc flux-cored wire can be used for welding 460MPa steel.

The invention provides a flux-cored welding wire for repairing a hot forging die and a method for using the same. The flux-cored welding wire includes an alloy steel strip sheath and a flux-cored powder, wherein the components in the alloy steel strip sheath and their proportion in the total mass of the steel strip sheath are provided. The percentages are: C0.20~0.29%, Si0.60~0.70%, Mn0.5~0.8%, S≤0.01%, P≤0.015%, Cr12~13%, Ni2~3%, Mo4.0~4.9 %, V0.3~0.5%, the balance is Fe; the components in the core powder and their percentages in the total mass of the core powder are: rutile 55-60%, sodium fluoride 3-5%, magnetite 1-2%, potassium cryolite 3-5%, zircon sand 5-8%, potassium titanate 4-7%, cerium oxide 2-3%, the balance is Fe; the flux-cored welding wire of the present invention passes through the alloy The main alloying elements are transferred to the outer skin of the steel strip, which improves the transition rate of the alloying elements, so that the surfacing metal has better wear resistance hardness and impact toughness, and improves the service life of the hot forging die.

Disclosed is a method for fabricating a seamless tube welding wire containing rutile cored powders by a mild-carbon steel strip. The method includes that by weight, 30%-50% of rutile, 2%-5% of dehydrated feldspar, 5%-10% of silicon iron, 1%-8% of ferrotitanium, 5%-15% of manganese metal, 2%-5% of zircon sand, 3%-8% of mineral magnesia, 2%-6% of quartz, 0.5%-2% of zirconium metal and the balance iron powders are fully and uniformly stirred to form the rutile cored powders, and the rutile cored powders are stored in a feeding device for stand-by, the mild-carbon steel strip is rolled to form a U-shaped steel strip, the cored powders are filled in the U-shaped steel strip at a rolling speed of 2-10m / s, the filling rate is controlled within 14%-18%, then a seamed tube in the diameter of D is formed by rolling, a seamless tube welding wire tube blank is formed by on-line welding of a laser-beam welding machine or a high-frequency welding machine, the seamless tube welding wire tube blank is subjected to high frequency annealing at 500-1200 DEG C, then the diameter of the seamless tube welding wire tube blank is reduced by a cold-drawn machine to form a D1 seamless tube welding wire, and then the D1 seamless tube welding wire is copperized so as to form the seamless tube welding wire containing the rutile cored powders.

A flux cored, gas shielded arc welding electrode for depositing a weld metal with low diffusible hydrogen and having tensile strength greater than 620 N / mm 2 (90 Kpsi) and a yield strength greater than 550 N / mm 2 (80 Kpsi). The electrode includes a nickel free steel sheath with a carbon content of less than 0.05% of the sheath and a core in the range of 13-17% of the electrode wherein the core includes primary alloy particles of iron, manganese, magnesium and nickel with a minor amount of secondary alloy particles of a silicon alloy and a boron alloy in a rutile based slag system. The nickel has a controlled amount in the general range of 1.0-2.0% by weight of the electrode and the rutile is 40-60% by weight of the core.

A flux-cored wire for gas shielded arc welding according to the present invention is formed by filling a steel casing with flux, wherein: the flux contains, by mass percentage to the total mass of the wire, titanium dioxide: 4.0 to 8.0%, alkali metal fluoride (fluorine equivalence): 0.02 to 0.40%, and PTFE (fluorine equivalence): 0.02 to 0.40%; the fluorine equivalence of alkali-earth metal fluoride is regulated to 0.01% or less by mass; and the fluorine equivalence of alkali metal fluoride and the fluorine equivalence of PTFE satisfy the following expressions; (fluorine equivalence of alkali metal fluoride) / (fluorine equivalence of polytetrafluoroethylene) 1, and (fluorine equivalence of alkali metal fluoride + 0.35) / (fluorine equivalence of polytetrafluoroethylene) >=1. By the configuration, diffusible hydrogen is prevented from intruding into a weld during arc welding and the wire is excellent in resistance to hygroscopicity and further shows good welding operability.