The invention relates to a high reflection gain type photovoltaic packaging glue film and applications; the packaging glue film comprises a package layer and a reflection layer; the package layer is 200-500 micron in thickness, and comprises a first body resin, a modified auxiliary agent, a UV auxiliary agent, an anti-heat and oxygen aging agent and an initiator, wherein said materials are mixed and fused at 60-200 DEG C, thus forming the film through the film casting technology; the reflection layer is 5-200 micron in thickness, and comprises a second body resin, an auxiliary resin, a first filling, a second filling, a modified auxiliary agent, a diluents, a UV auxiliary agent, an anti-heat and oxygen aging agent and an initiator, wherein said materials are mixed and coated on the surface of the package layer, and solidified at the temperature of 30-150 DEG C so as to form the reflection layer. The preparation technology is simple and low in cost, and the product is excellent in performance, thus providing effective gain effect for a double-face crystal silicon cell assembly, providing basis for cost optimization of one side crystal silicon cell assembly gain type packaging material, and simultaneously providing stability and reliability of the crystal silicon photovoltaic assembly in outdoor long time applications.