The invention relates to a method for preparing a polyether polycarboxylic acid type high-efficiency water
reducing agent from polyethylbenzene
tower bottom high-boiling residues. The polyether polycarboxylic acid type high-efficiency water
reducing agent is prepared by free
radical polymerization of arone olefin, a double-bond-containing
macromonomer and a micromolecular
monomer, and the arone olefin is prepared by catalytic
acylation of poly-
ethylbenzene sulfonic acid and unsaturated acylate by using a
bifunctional molecular sieve encapsulated catalyst. The
bifunctional molecular sieve encapsulated catalyst is prepared by one-step
hydrothermal reaction of
sodium metaaluminate,
sodium hydroxide, modified
silicon dioxide, N, N, N-trimethyl-1-
amantadine, carbon nanotubes and (2, 2 '-
bipyridine)
nickel diiodide, and the polyethylbenzene
sulfonic acid is prepared by sulfonating high-boiling residues at the bottom of a polyethylbenzene
tower. According to the method, the polyethylbenzene
tower bottom high-boiling residues serve as raw materials, polyether polycarboxylic acid type high-efficiency water
reducing agent molecules are prepared through the steps of sulfonation,
acylation, free
radical polymerization and the like, and the polyether polycarboxylic acid type high-efficiency water reducing agent molecules are practically applied to the building field and have important significance in resourceful treatment of the
ethylbenzene tower bottom high-boiling residues.