The invention relates to the technical field of photovoltaic glass, in particular to an antireflection film layer for photovoltaic glass, a preparation method of the antireflection film layer and a
solar cell module, and the antireflection film layer comprises an antireflection main layer arranged on a glass substrate and an antireflection auxiliary layer arranged on the antireflection main layer; the antireflection main layer comprises
nano silicon dioxide dispersoid, hollow
silicon dioxide particles, a pore-forming agent and a
solvent; the antireflection auxiliary layer comprises
fluorine-containing resin, a curing agent, nanoscale
inorganic particles and an
organic solvent; according to the invention, the antireflection auxiliary layer contains resin with a
fluorine-containing structure, and due to the existence of
fluorine atoms, the surface of the antireflection film layer has excellent
water resistance and
moisture resistance, so that pollutants or greasy
dirt and the like in the environment are prevented from entering the antireflection film layer or directly adhering to the surface of the film layer due to an open pore type structure on the surface in a traditional antireflection film layer
system with a single-layer structure, and the solar
ray transmittance is not reduced.