Preparation method for polyester fiber with efficient performance of light absorption and heat emission
A light-absorbing and heat-generating polyester fiber technology, which is applied in the fields of fiber chemical characteristics, single-component polyester rayon, melt spinning, etc., can solve the problems of poor light-absorbing and heat-generating properties of heat-retaining fibers, and achieve enhanced heat-retaining effect and radiation intensity Enhanced, synergistic effect
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Embodiment 1
[0048] a CuFe 2 o 4 @SiO 2 The preparation method of powder, at first under agitation condition, Cu(NO 3 ) 2 ·3H 2 O solution (concentration is 10wt%) and Fe(NO 3 ) 3 9H 2 After the mixed solution of O solution (concentration is 10wt%) is added dropwise in the citric acid monohydrate solution (concentration is 10wt%) in 1h, adopts ammonia water to adjust the pH value of the system to 7.0 to obtain precursor solution, the mole of citric acid monohydrate The amount is Fe(NO 3 ) 3 9H 2 O and Cu(NO 3 ) 2 ·3H 2 O 10% of the sum of the molar weights, then after adding dropwise the mixed solution of tetraethyl orthosilicate and absolute ethanol in the precursor solution, adjust the pH value of the system to 7.0 with ammonia water, and vacuum-dry under the temperature condition of 80 ℃ 12h to obtain xerogel, Fe(NO 3 ) 3 9H 2 O, Cu(NO 3 ) 2 ·3H 2 The molar ratio of O and ethyl orthosilicate is 2:1:1, and the quality of ethyl orthosilicate is 20% of the mass of the mi...
Embodiment 2
[0050] a CuFe 2 o 4 @SiO 2 The preparation method of powder, at first under agitation condition, Cu(NO 3 ) 2 ·3H 2 O solution (concentration is 25wt%) and Fe(NO 3 ) 3 9H 2 After the mixed solution of O solution (concentration is 25wt%) is added dropwise in the monohydrate citric acid solution (concentration is 25wt%) in 2h, adopts ammonia water to adjust the system pH value to 8.0 to obtain precursor solution, the mole of monohydrate citric acid The amount is Fe(NO 3 ) 3 9H 2 O and Cu(NO 3 ) 2 ·3H 2 O 25% of the sum of the molar weights, then dropwise add a mixed solution of tetraethyl orthosilicate and absolute ethanol to the precursor solution, adjust the pH value of the system to 8.0 with ammonia water, and vacuum dry at a temperature of 100°C 30h to obtain xerogel, Fe(NO 3 ) 3 9H 2 O, Cu(NO 3 ) 2 ·3H 2 The molar ratio of O and ethyl orthosilicate is 2:1:2, and the quality of ethyl orthosilicate is 35% of the mass of the mixed solution of ethyl orthosilic...
Embodiment 3
[0052] a CuFe 2 o 4 @SiO 2 The preparation method of powder, at first under agitation condition, Cu(NO 3 ) 2 ·3H 2 O solution (concentration is 40wt%) and Fe(NO 3 ) 3 9H 2 After the mixed solution of O solution (concentration is 40wt%) is added dropwise in the citric acid monohydrate solution (concentration is 40wt%) in 3h, adopts ammonia water to adjust the pH value of the system to 9.0 to obtain precursor solution, the mole of citric acid monohydrate The amount is Fe(NO 3 ) 3 9H 2 O and Cu(NO 3 ) 2 ·3H 2 O 40% of the sum of the molar weights, then dropwise add a mixed solution of tetraethyl orthosilicate and absolute ethanol to the precursor solution, adjust the pH value of the system to 9.0 with ammonia water, and vacuum-dry at 120°C 48h to obtain xerogel, Fe(NO 3 ) 3 9H 2 O, Cu(NO 3 ) 2 ·3H 2 The molar ratio of O and ethyl orthosilicate is 2:1:3, and the quality of ethyl orthosilicate is 50% of the mass of the mixed solution of ethyl orthosilicate and ab...
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